Correspondence (2) • JUNr2S-B3 10^2B FROM. H.B. FULLER Co. 1D`'7x47395E9B PAGE 1
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08/25/93 v � -'
DENNIS 8IGHAM
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SUBJECT: Material Safety Data Sheet
'~ N�DUCT
REFERENCE: %F-3600
ear Customer: ^
Enclosed are Material Safety Data Sheets (M8OS) for H. 8 Fuller Coman
products. We have reviewed our products, conducted a hazard Uetermina
tipn and prepared an MSDS in compliance with the renuirements of th
Occupational Safety and Health Administration (OSHA) Hazard Cummunica
tiun Standard, 29 CFR 191Q. 1200 and Canada's Workplace Hazardous Materi-
als Information System (WHMI8). Our MSOS also provide information on any -
toxic chemical subject to the reporting requirements of section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986
(SARA).
If this product, or any component of it, is considered to be hazardous
or carcinuoenic under the OSHA Hazard Communication Standard or the
UHMIS regulations, information is provided in Section 2: COMPOSITION/IN-
FORMATION ON IN8REO1ENT3 or in Section 3: HAZARDS IDENTIFICATION.
if you have any questions, please contact your Sales Representative.
Sincerely yours,
H. Q. Fuller Company
industrial Hygiene Section •
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JUN-25=93 20:29 FROM: H.B. FULLER CO. ,1D: 7147395599 PAGE 2
-• Date Printed:. 06/25/93 Page 1. of 6
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MATERIAL SAFETY DATA SHEET
SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
COMPANY INFORMATION MSUS INFORMATION
Industrial Coatings Division Preparation Date: 06/09/93
H.0. Fuller ComPanY Supersedes: 02/22/93
3200 Lahore Road Prepared By; Industrial Hygiene
Vadnal.s Heights, MN 55110 Phone Number: 612-481-3300
Phone: 612-481-9558
Fax: 612
Medical Emergency Phone Number: 1-800-228-5635 ext 018
Transport Emergency Phone Number (CHEMTREC) 1-800-424-9300
PRODUCT INFORMATION
Product Namo/Number: IF-2600, Coal TGIC
Product Description (product use) Powder coating
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
This Material Safety Data Sheet is prepared to comply with the United
States Occupational Safety and Health Administration (OSHA) Hazard •
Communication Stan dard (29 CFR 1910.1200) and the Canadian Workplace
Hazardous Materials Information System (WHMIS). Unlisted ingredients
are not 'hazardous' per the OSHA standard and/or are not found on the
WHMIS ingredient disclosure list.
Chemical/CAS Number Percent OSHA PEL ACGIH TLV
Epoxy resin 1-5% Nut estab. Not estab.
Carbon black (1333-86-4) 1-5% 3.5 mg/M3 3,5 mg/M3
L050; No data found LC50: No data found
Calcium silicate (1344-95-2) 10-30%
Total dust 15 mg/M3 10 mg/H3
Respirable fraction 5 mg/M3 Not estab.
L050: No data found LC50: No data found
1,3,5-triglycidyi 1-5% Not estab. Not estab.
• isocyanurate (TGIC) (2451-62-9)
• L050: 100-225 mg/kg (oral, rat) LC50: No data found
*Supplier recommen ds a STEL of 0.025 mg/M3 for TOIC,
See Section 16 for additional information.
SECTION 31 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
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Oust clouds in air can be ignited by electric sparks, hot surfaces
and open flame.
Potential skin sensitizer
Possible cancer hazard. Contains a material which may cause cancer.
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JUN -25 - 93 10:29 FROM: H.B. FULLER CO. ID: 7147395599 PAGE 3
IF-2600
Date Printed: 06/25/93 Page 2 of 6
POTENTIAL HEALTH EFFECTS
Eyes: Eye contact may cause irritation.
Skin: Epoxy resins are potential skin sensitizers.
Inhalation: Powder coatings may irritate the nose, throat, and :lungs.
TGIC is a potential lung sensitizer,
Ingestion: Not an anticipated route of exposure. Small amounts are
not anticipated to be harmful..
Chronic: TGIC has been found to cause genetic /reproductive changes
in severml animal and bacterial test systems. There is no
evidence that it has caused similar changes in humans.
However, overexposure to TGIC may increase the risk of genetic
effects.
REGULATED CARCINOGEN STATUS:
Carbon black contains. trace amounts of strongly adsorbed
polynuclear aromatic compounds (PNA's). Some PNA's in the
non — adsorbed form are listed as potential carcinogens by l:ARC,
See Section :I.6 Additional Information — for exposure
guidelines.
Existing Health Conditions Affected by Exposure: Inhalation of dust
may <'agdravate lung conditions such as asthma, emphysema or
chronic:: bronchitis.
Existing 5I<i.T1 allergies may be aggravated by contact with this
product.
SECTION 4: FIRST AID MEASURES
If in eye: Flush immediately with water for 15 minutes. Consult a
physician if irritation persists.
If on sk :iu: LJash material. from skin with £OaP and water.
If vapors inhaled: Remove subject to fresh air. Call a physician if
symptoms persist,
If ingested: If person can swallow, give one glass of water or milk.
Do hot induce vomiting, Get immediate medical. attention.
Never give anything by mouth to an unconscious person.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point /Method: Not applicable
Upper Explosive Limit /Lower Explosive Limit: Normal LEL for powder
coatings 0,04 to 0.07 ounces /cubic foot. Strong explosions
are not expected below 0.4 to 0.7.
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Autoignition Temperature: Not applicable
JUN-25 10^30 FROM. N.B. FULLER CO. ID. 7147395599 PAGE 4
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1F-2800 :
Date Printed: 06/25/93 Page 3 of 6
Appropriate Extinguishers: Use dry chemical, sand or ground
limestone,
Special Fire Fighting Procedures: Persons exposed to products of
combustion should wear self-contained breathing apparatus and
full protective equipment.
Unusual Fire and Explosion Hazards: Oust clouds in air can be
ignited by electric sparks, hot surfaces and open flame.
Hazardous Combustion Product; incomplete combustion can yield low
molecular weight hydrocarbons, carbon monoxide, nitrogen
compounds
SECTION 6: ACCIDENTAL RELEASE MEASURES
Spill or Leak Procedures: Remove all sources of ignitiwn. Avoid
creating dusty con6itions. Vacuum or sweep up spilled
material.
SECTION 7: HANDLING AND STORAGE
STORAGE INFORMATION
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Consult the Technical Data Sheet for specific storage instructions.
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SECTION B| EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection: Safety glasses.
Skin Protection: Gloves, long-sleeved shirt and other clothing as
needed to prevent skin contact.
Respiratory Protection: NIOSH approved particulate respirator.
Ventilation: Ventilation must be sufficient to control dust and
fumes produces by processing method. Local exhaust
recommended.
SECTION 9: PHYSICAL ANO CHEMICAL PROPERTIES
Physical State: Solid
• Color; DARK
Odor:
none
Odor Threshold: Not established
Weight per Gallon; 12.049 lbs.
Specific Gravity: 1,446
X Solids by Weight: 100
pH: Not applicable
Boiling Ramse: Not applicable
Freezing/Melting Point: Not applicable
Vapor Pressure: Not established
Vapor Density: Not established •
Evaporation Rate: Not applicable
Water/Oil Partition Coefficient: Not established
jmH725 10,30 FROM: H.B. FULLER Co. ID: 7147395599 PAGE s
IF-2600
Date Printed: 06/25/93 Page 4 of �
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VOC: Negligible levels of volatile organic
compound emissions are expected at ambient
temperature and pressure. Low molecular
weight hydrocarbons may be emitted at
application temperature. Emissions data is
best developed by monitoring actual plant
conditions.
SECTION 10: STABILITY AND REACTIVITY DATA
Stability: Stable
Incompatibility: Not established
Hazardous Decomposition:
Nitrogen compounds
Hazardous Polymerization: Will not occur
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SECTION 111 TOXICOLOGICAL INFORMATION
Testing on generic powder cmat1ngs containing 10% TGIC yielded a
single exposure inhalation LCGO of greater than 11 m9/M3. The
LC50 for a 5 day, 6 hour/day repeated exposurewas greater than 1700 •
mg/M3. Mvtagenicity screening using a 9% TGIC coating in a mouse
spermataeoniol cell study showed an increased rate of chromosomal
changes (damage) at an oral dose of BOO mg/M. Lower dose levels
did not demonstrate a statistically significant response. This
study also demonstrated a statistically significant dose-response
trend. The No-Effect Level (NOEL-nu damage to animals or
• chromosomes at this exposure level) for the study was 100 mg/M3.
Since the previously published studies on powder coatings containing
TGIC were designed as worst-case scenarios, a more realistic study
was conducted using a pigmented powder coating containing 4.6% TGIC,
for nose-only inhalation, at a particle size greater than 10
micrometers. This study showed a NOEL of 1000 mg/M3.
SECTION 12: ECOLOGICAL INFORMATION
No data available
SECTION 13: DISPOSAL CONSIDERATIONS
To the best of our knowledge, this product does not meet the
definition of hazardous waste under the U.S. EPA Hazardous Waste
Regulations 40 CFR 261. Dispose of in an approved landfill.
Consult state, local or provincial authorities for more restrictive
requirements.
SECTION 141 TRANSPORTATION INFORMATION
UNITED STATES DEPARTMENT OF TRANSPORTATION (DOT)
DOT Proper Shipping Name: Not regulated
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zUm-25 10^30 FROM. H.B. FULLER CO. ID. 7147395599 PAGE 6
IF-2600
Date Printed: 06/25/93 Page 5 of 6
SECT/ON 15: REGULATORY INFORMATION
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FEDERAL
Toxic Substances Control Act (TSCA)
Section 8(b) - Inventory Status
All components of this product are registered under the
regulations of the Tonic Substances Control Act.
SARA TITLE III
Section 313: This product does not contain regulated levels of
any toxic chemical subject to the reporting
requirements of section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986
(SARA) and 40 CFR part 372.
STATE REGULATIONS
California Proposition 851 Proposition 65, The Safe Drinking Water
and Toxic Enforcement Act of 1986:
This product does not contain known levels of any chemical known
to the State of California to cause cancer or cause reproductive
damage.
WHMIS IDENTIFICATION/OTHER INTERNATIONAL REGULATIONS
D1B 02A, 028
SECTION 16: ADDITIONAL INFORMATION
After handling product, wash thoroughly before eating or smoking.
Use adequate ventilation or NIOSH approved organic vapor respirator
when welding, cutting or brazing coated parts.
Based on the most recent animal studies, our TGIC supplier has
recommended an exposure limit of 10 m3/M3 TWA for powder coatings
containing less than approximately 5X TGIC.
Based on the information gained from all the toxicological studies
conducted at this time, our TGIC supplier recommended an exposure
limit of 1 mg/M3 TWA for powder coatings containing TGIC at levels
greater than apnrwmimatelr 5 X
See Section 11: Toxicological Information for more imfwrmetiwn.
An exposure guideline of 3.5 mg/M3 is set to prevent overexposure to
PNA's in carbon black. Maintaining employee exposures below 10
ms/M3 will maintain the carbon black exposure levels below this
guidelinw. Therefore, maintain exposure levels below 10 mg/M3 for
this product.
JUN-25 10,31 FROM. H.B. FULLER co. ID: 71473e5588 PAGE 7
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IF-2600
• Date Printed: 06/25/93 Page 6 of 8
HMIS RATING
Health-1 Flammability-1 Reactivity-0
See SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for personal
protective enuipment recvmmendatinns.
The information and recommendations set forth herein are believed to be
accurate. Because some of the information is derived from information
Provided to the H.B. Fuller Company from its suppliers, and because the
H.B. Fuller Company has no control over the conditions of handling and
use, the H.8. Fuller Company makes no warranty, express or implied^
regarding the accuracy of the data or the results to be obtained from
the use thereof. The information is supplied solely for your
information and consideration, and the H.B. Fuller Company assumes no
resrousib1lity from use or reliance tbereon. It is the responsibility
of the user of H.B. Fuller Company products to comply with all
applicable federal, state and local laws and regulations,
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