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Report ��7✓ btAp o1i- 0000, 7atk.( S ;A/2__, -* , M )2 D DON PATTY CODE CONSULTING RECEIVED FEB 1 5 "'I 15533 SE 232 DRIVE CITY OFTIGARD BUILDING DIVISION DAMASCUS OR 97089 503- 658 -3990 FAX 503- 658 -2383 CELL 503- 705 -9096 7 FEBRUARY 2011 RSD REFRIGERATION SUPPLIES DISTRIBUTOR PACTRUST BUSINESS CENTER 7244 SW DURHAM RD SUITE 500 PORTLAND OR 97224 SUBJECT: HIGH PILED STORAGE FOR WHOLESALE. THE NAICS CODE IS 423740, REFRIDGE, EQ, AND SUPPLIES WHOLESALE. THE FOLLOWING LIST SHOWS THE HAZARDOUS ITEMS TO BE STORED AT THIS WAREHOUSE. 1. ACETYLENE 10 -19 CUBIC FT 2. PENTAFLOUROETHANE (R507) REFRIG 750 LBS 3.1,1,1- TRIFLUOROETHANE (R404A) REFRIG 1000 LBS 4.CHLORODIFLUOROMETHANE (R408A) REFRIG 750 LBS 5.CHLORODIFLUOROMETHANE (R409A) REFRIG. 300 LBS 6.CHLORODIFLUOROMETHANE (R401B) REFRIG 300 LBS 7.CHLORODIFLUOROMETHANE (R401 A) REFRIG. 300 LBS 8. DIFLUOROMETHANE (R410A) REFRIG 750 LBS 9. PENTAFLUOETHANE (R402A) REFRIG 240 LBS 10.1,1,1,2- 'l'ETRAFLUOROTHANE (R134A) REFRIG 600 LBS 11.CHLORODIFLUOROMETHANE(R407A) REFRIG 2400 LBS 12.1,1,1,2- TETRAFLUOROTHANE (R407A) REFRIG 480 LBS 13 .TY ION B20, SOLIUM NITRATE, SODIUM '1'ETRABORATE PENTA -5 GALLONS 14.CALCLEAN, SODIUM METASILICATE 20 GAL 15.CALGON, REFINED MINERAL OIL 50 GAL 16.CALGON, ALKYL BENZENE OIL 100 GAL 17.CALGON, PROPYLENE GLYCOL 50 GAL 18.CALGON, HYDROCHLORIC ACID 11 GAL 19.CALGON, SODIUM HYDROXIDE 88 GAL 20. OXYGEN 200 CUBIC FEET RSD WOULD LIKE TO STORE THE ITEMS ON THE LIST ABOVE TO 6' HIGH TOP OF PRODUCT EXCEPT FOR THE REFRIGERANT THEY WOULD LIKE TO STORE TO 12' TOP OF PRODUCT, ADDITIONAL MATERIALS SUCH AS REFRIGERATION UNITS, COMPRESSORS, AND MOTORS TO 20'. THEY WILL BE STORING AIR FILTERS TO APPROXIMATELY 15' ON RACKS WITH OPEN WIRE SHELVING THE AISLES WILL BE GREATER THAN 8' ALL OF THE RACKS WILL HAVE OPEN WIRE DECKING THE PRODUCT IS ON WOOD PALLETS AND IT IS NON ENCAPSULATED. THE SPRINKLER SYSTEM IS AT .58/2000. THERE ARE SIX SMOKE VENTS (SEE ATTACHED PLANS). THE ATTACHED FLOOR PLAN SHOWS FLOOR LAY OUT, RACKS, EXITING AND DIMENSIONS. THE ABOVE LIST OF HAZARDOUS MATERIALS DOES NOT EXCEED THE MAXIMUM ALLOWABLE QUANTITY PER CONTROL AREA PER OREGON FIRE CODE CHAPTER 27 AND CHAPTER 37. ALSO THE METHOD THAT RSD REQUESTED FOR THERE STORAGE WILL ALSO MEET OREGON FIRE CODE (SEE LIST ABOVE) THE EXISTING SPRINKLER SYSTEM AND THE SMOKE VENTS ALSO MEET CURRENT OREGON FIRE CODE NOTE: THERE WILL BE A FULL SET OF MATERIAL SAFETY DATA SHEETS SUBMITTED WITH YOUR APPLICATION TO THE BUILDING AND FIRE DEPARTMENT. THANK YOU DON PATTY 125-0' 40 -0 R 40-0' ......__.._._.. _ _ ... {ufl ■ i ! I Ito ar t n t IIIIII . 1=19=== MI 1 1 1 I II 8 Y 1 j I l Iiiiitri I _ II • I l l l l A -� � ` 2. NI ` ®I 1 I I I I ®' I et I - ®®.0eN•6ii66 ' i 11;11 I o 1 111 a® ® ®o l gP a e 6 SPACBPOR: MARTIN W. HANSON, ARCHITECT o l i y z RSD Refrigeration Supplies Distributor 1° a . ° #300 N N c PACrnUSTBDSN®SC WTER TiMSWDURHAMRD. k500 BUB - DP1°M (PI'Rp pbc186j 11071 11 Poanwrro,oavnu A F4 PROPERTY I I 125-0` 1 40-0 ` 1 6 -0 ` 40' -0' l v I . .. I i i ; 6 h3 1 1 1 1 1 1 ''! "I I 11. r� I I II I l l l l T t I 1 c ®I { - *1 E. I t l 1 1 � ' XI ice. �.� 1 _ 1 .._... ...... I I I I I ...I �� ` a it p. A. IIM 111 131 \ 1 ! ® ®•Q®® •6i.Z I fl ; 5 IJ ijI l i l! iiiJI j,,ii ;Ii P 3 i 1 VIM iii 111P ill :: ! o 1 NACE MARTIN W. HANSON, ARCHITECT i � N F. x RS Refrigeration Supplies Distributor �.„°° F. o PACIRUrrsUSN sC TER ) N 7244RW DURHAM RD. HUHffiIOY myPwMRa I i T PORTLAND, A Pl MILIET PROPERTY BIA J ' DO) J - vovG RE po -r R ECEIV ED 7 � 1'1 F�E 11 R17 � � � algon MATERIAL SAFETY DATA SHEET CITY OF TIGARD SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION BuLLllIIVU DIVISION Company Name Phone Number CI EMTREC Nu- Calgon Wholesaler, Inc. (314) 469 -7000 / (800) 554 -5499 (800) 424 -9300 Street Address City State Postal Code Last Update 2008 Altom Court St. Louis MO 63146 -4151 1/11/10 Product Name Product Number Product Use EPA Registration # Freez- Kontr'l 4188 Closed system anti - freezing agent. N/A SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients % By Wt. CAS Number l I.\ PEL Propylene Glycol 70 - 80 57 -55 -6 NE NE SECTION 3 - HAZARD IDENTIFICATION Emergency Overview: Material is a clear, colorless solution. Potential Health Effects Eves: May cause transitory stinging and tearing. Skin: Mild irritant and defatting agent, especially on prolonged contact. Ingestion: Relatively non - toxic. Ingestion of sizable amount (over 100 mL) may cause some gastrointestinal upset and temporary central nervous system depression. Effects appear more severe in individuals with kidney problems. Inhalation: No adverse effects via Inhalation. Chronic Exposure: Lactic acidosis, stupor, and seizures have been reported following chronic ingestion. Carcinogenicity: This product has NOT been identified as a carcinogen by NTP, IARC, ACGIH, OSHA, or CA Prop 65. Medical Conditions Aggravated be Exposure: Kidney disorders. SECTION 4 - FIRST AID MEASURES EYCS: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Skin: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists. Ingestion: Not expected to require first aid measures. Give several glasses of water to drink and dilute. If large amounts are swallowed, seek medical advice. Note to physician: In case of ingestion, monitor for acidosis and central nervous system changes. Exposed persons with previous kidney dysfunction may require special treatment. Inhalation: Remove to fresh air. Not expected to require first aid measures. SECTION 5 - FIREFIGHTING MEASURES Flash Point: 99 °C /211 °F Autoignition Temp: 371 °C /700 °F Hazardous Products of Combustion: No Data. Flammable Limits in Air: ( %vol. in air) -17.4 Extinguishing Media: Use extinguishing agent suitable for type of surrounding fire. Water Spray: OK Carbon Dioxide: OK Foam: OK Dry Chemical: OK Other: Any "ABC" Class Fire and Explosion Hazards: Containers may explode in the heat of the fire. Explosion Sensitivity to Mechanical Impact: Not sensitive. Explosion Sensitivity to Static Discharge: Not sensitive. Special Firefighting Procedures: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by the DOT Emergency Response Guidebook, a self - contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area and keep unauthorized personnel out. Contain spill if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Cool equipment exposed to fire with water, if it can be done with minimal risk. SECTION 6 — ACCIDENTAL RELEASE MEASURES Spill or Leak: For small releases of this product, wear latex or nitrile gloves and safety glasses. Absorb spilled liquid and rinse area thoroughly with soap and water. For large or uncontrolled releases, ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal equipment and specified in section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Collect liquid in an appropriate container or absorb with an inert material (e.g. vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. SECTION 7 — HANDLING AND STORAGE handling Procedures and Equipment: Work and Hygiene Practices: As with all chemicals, avoid getting this product ON YOU or IN YOU. Do not eat, drink, smoke or apply cosmetics while handling the product. Wash hands thoroughly after handling. Protective Practices During Maintenance of Contaminated Equipment: When cleaning non - disposable equipment, wear latex or nitrile gloves (double gloving is recommended), goggles, and lab coat. Wash equipment with soap and water. All needles, syringes, vials and other disposable items contaminated with this product should be disposed of properly. Storage Requirements: Store only in approved containers. Keep away from any incompatible materials or conditions (see Section 10). Store in a dry ventilated area at a temperature of 15 °C to 30 °C (59 °F to 86 °F). Protect from light. SECTION 8 — EXPOSURE CONTROLS /PERSONAL PROTECTION Respiratory Protection: Not normally required for routine, administration of this product. A NIOSH certified air- purifying respirator may be used under conditions where airborne concentrations are expected to be excessive. Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a positive pressure air supplied respirator if there is potential for uncontrolled release, exposure levels are not known or any other circumstances where air - purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Eye Protection: The use of chemical goggles to safeguard against potential eye contact, irritation, or injury is recommended. Protective Clothing: Use protective gloves. Wash hands before and after using gloves. Use clean body covering. Exposure Guidelines: No Data. Specific Engineering Controls (such as ventilation, enclosed process): Use with adequate ventilation. Follow standard medical product handling procedures. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Liquid Freezing Point: - 60 °C / -76 °F 0 /O Volatile by Weight: No Data.% Color: Light blue Vapor Density lair =1 I: 60 -90° F: 2.6 Evaporation Rate: (ether -1): N/A Odor: near odorless Vapor Pressure: mm Hg: 0.1 Specific Gravity: 1.04 Boiling Point: 182 °C /360 °F Solubility in Water: Complete plI (concentrate): SECTION 10 — STABILITY AND REACTIVITY Chemical Stability: Stable under labeled storage conditions. Hazardous Polymerization: Will not occur. Incompatibilities: Strong oxidizing agents. Reactive Conditions to avoid: Heat, ignition sources, and incompatibles Decomposition Products: CO2, CO, aldehydes SECTION 11 — TOXICOLOGICAL INFORMATION Hazardous Ingredients CAS # EI\ECS # L,D 50 of Ingredient I:CSO of Ingredient (Specify Species) (Specify Species) Propylene Glycol No Data. No Data. Oral LD50 (rat) = 20 g/kg Irritation eye (rabbit) = 500 Skin LD50 (rabbit) = 20.8 g/kg mg/24H mild Mutagenicity: DNA inhibition: When propylene glycol was given Subcutaneous mouse = at 30% in the diet, it affected 8000mg/kg, reproduction rates in rats. Cytogenic Analysis: Subcutaneous It has generally not affected mouse = 8000 mg/kg, Cytogenic fertility or reproduction, except at analysis: Hamster, Fibroblast = 32 very high dosed where effects gm /L. could be attributed to nutritional deficiency. SECTION 12 - ECOLOGICAL INFORMATION Hazardous Ingredients Aquatic Toxicity Data When released into the soil, this material is expected to readily biodegrade. When released into the soil, the material is expected to leach into ground water. When released into water this material is expected to readily degrade. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half -life between 1 and 10 days. SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal: Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of unused contents according to federal, state, and local regulations. SECTION 14 - TRANSPORTATION INFORMATION Special Shipping Information: No Hazardous Purview Proper Shipping Name UN Number Packing., Group Hazard Class DOT Not Regulated. (Land) IMO No Data. (Water) ICAO No Data. (Air) SECTION 15 - REGULATORY INFORMATION WHMIS Classification: (Workplace No Data. Hazardous Material Information System) SARA Title III: ( Superfund Amendments & The components of this product are not subject to the reporting requirements of Sections 302, 304 and Reauthorization Act) 313 of Title II of the Superfund Amendments and Reauthorization Act. OSHA: (Occupational Safety & Health No Data. Administration) TSCA: (Toxic Substance Control Act) Propylene glycol is a "drug" as defined by the Federal Food, Drug and Cosmetic Act and is therefore not a chemical substance under TSCA. VOC: (volatile Organic Compounds) slightly volatile CPR: (Canadian Controlled Products This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations) Regulations. EINECS: (European Inventory of Existing No Data. Commercial Chemical Substances) DSL / NDSL: (Canadian Domestic Substance No Data. ListXNon- Domestic Substance List) CERCLA: (Comprehensive Response Not applicable Compensation & Liability Act) IDL: (Canadian Ingredient Disclosure List) No Data. NFPA (HMIS) Rating: (Hazardous Materials Health: 0 Identification System) Flammability: 1 Reactivity: 1 SECTION 16 - OTHER INFORMATION California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does NOT contain a chemical known to the State of California to cause developmental and reproductive effects. Other U.S. Federal Regulations: Based on this product's use, the requirements of the OSHA Bloodborne pathogen Standard (29 CFR 1910.1030) are not applicable. ANSI Labeling (Based on 129.1. Provided to Summarize Occupational Exposure Hazards): The information contained herein is based on the data available to us and is believed to be correct. However, Nu -Calgon Wholesaler Inc. makes no warranty, expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu- Calgon Wholesaler Inc. assumes no liability for injury from the use of the product described herin. N ►�. RECEIVE' l Wholesaler, Inc. MATERIAL SAFETY DATA SHEET _ 1 , , SECTION 1— CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ITY OF TIOARD Company Name Phone Number CHEMTREC� Nu- Calgon Wholesaler, Inc. (314) 469 -7000 / (800) 554 -5499 (800) 424- 434ILDING DIVISION Street Address C State Postal Code I.,ast Update 2008 Altorn Court St. Louis MO 63146 -4151 1 /11 /10 Product Name Product Number Product Use EPA Registration # Freez-Kontr'l 4188 Closed system anti - freezing agent. N/A SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients % By Wt. CAS Number I� V PAL Propylene Glycol 70 - 80 57 -55 -6 NE NE SECTION 3 — HAZARD IDENTIFICATION Emergency Overview: Material is a clear, colorless solution. Potential Health Effects Eves: May cause transitory stinging and tearing. Skin: Mild irritant and defatting agent, especially on prolonged contact. Ingestion: Relatively non - toxic. Ingestion of sizable amount (over 100 mL) may cause some gastrointestinal upset and temporary central nervous system depression. Effects appear more severe in individuals with kidney problems. Inhalation: No adverse effects via Inhalation. Chronic Exposure: Lactic acidosis, stupor, and seizures have been reported following chronic ingestion. Carcinogenicity: This product has NOT been identified as a carcinogen by NTP, IARC, ACGIH, OSHA, or CA Prop 65. Medical Conditions Aggravated be Exposure: Kidney disorders. SECTION 4 — FIRST AID MEASURES Eves: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Skin: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists. Ingestion: Not expected to require fast aid measures. Give several glasses of water to drink and dilute. If large amounts are swallowed, seek medical advice. Note to physician: In case of ingestion, monitor for acidosis and central nervous system changes. Exposed persons with previous kidney dysfunction may require special treatment. Inhalation: Remove to fresh air. Not expected to require first aid measures. SECTION 5 — FIREFIGHTING MEASURES Flash Point: 99 °C /211 °F Autoienition Temp: 371 °C /700 °F Hazardous Products of Combustion: No Data. Flammable I..imits in Air: ( %vol. in air) -17.4 Extinguishing Media: Use extinguishing agent suitable for type of surrounding fire. Water Spray: OK Carbon Dioxide: OK Foam: OK Dry Chemical: OK Other: Any "ABC" Class Fire and Explosion Hazards: Containers may explode in the heat of the fire. Explosion Sensitivity to Mechanical Impact: Not sensitive. Explosion Sensitivity to Static Discharge: Not sensitive. Special Firefighting Procedures: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by the DOT Emergency Response Guidebook, a self - contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area and keep unauthorized personnel out. Contain spill if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Cool equipment exposed to fire with water, if it can be done with minimal risk. SECTION 6 — ACCIDENTAL RELEASE MEASURES Spill or Leak: For small releases of this product, wear latex or nitrile gloves and safety glasses. Absorb spilled liquid and rinse area thoroughly with soap and water. For large or uncontrolled releases, ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal equipment and specified in section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Collect liquid in an appropriate container or absorb with an inert material (e.g. vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. SECTION 7 — HANDLING AND STORAGE Handling Procedures and Equipment: Work and Hygiene Practices: As with all chemicals, avoid getting this product ON YOU or IN YOU. Do not eat, drink, smoke or apply cosmetics while handling the product. Wash hands thoroughly after handling. Protective Practices During Maintenance of Contaminated Equipment: When cleaning non - disposable equipment, wear latex or nitrile gloves (double gloving is recommended), goggles, and lab coat. Wash equipment with soap and water. All needles, syringes, vials and other disposable items contaminated with this product should be disposed of properly. Storage Requirements: Store only in approved containers. Keep away from any incompatible materials or conditions (see Section 10). Store in a dry ventilated area at a temperature of 15 °C to 30 °C (59 °F to 86 °F). Protect from light. SECTION 8 EXPOSURE CONTROLS /PERSONAL PROTECTION Respiratory Protection: Not normally required for routine, administration of this product. A NIOSH certified air - purifying respirator may be used under conditions where airborne concentrations are expected to be excessive. Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a positive pressure air supplied respirator if there is potential for uncontrolled release, exposure levels are not known or any other circumstances where air - purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Eye Protection: The use of chemical goggles to safeguard against potential eye contact, irritation, or injury is recommended. Protective Clothing: Use protective gloves. Wash hands before and after using gloves. Use clean body covering. Exposure Guidelines: No Data. Specific Engineering Controls (such as ventilation, enclosed process): Use with adequate ventilation. Follow standard medical product handling procedures. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Liquid Freezing Point: - 60 °C / -76 °F % Volatile by Weight: No Data.% Color: Light blue Vapor Density lair =1 1: 60 -90° F: 2.6 Evaporation Rate: (ether =l): N/A Odor: near odorless Vapor Pressure: mm Hg: 0.1 Specific Gravity: 1.04 Boiling Point: 182 °C /360 °F Solubility in Water: Complete p11 (concentrate): SECTION 10 — STABILITY AND REACTIVITY Chemical Stability: Stable under labeled storage conditions. Ilazardous Polymerization: Will not occur. Incompatibilities: Strong oxidizing agents. Reactive Conditions to avoid: Heat, ignition sources, and incompatibles Decomposition Products: CO2, CO, aldehydes SECTION 11 — TOXICOLOGICAL INFORMATION Hazardous Ingredients CAS # EFNF,CS # L,D 50 of Ingredient L,C50 of Ingredient (Specify Species) (Specify Species) Propylene Glycol No Data. No Data. Oral LD50 (rat) = 20 g/kg Irritation eye (rabbit) = 500 Skin LD50 (rabbit) = 20.8 g/kg mg/24H mild Mutagenicity: DNA inhibition: When propylene glycol was given Subcutaneous mouse = at 30% in the diet, it affected 8000mg/kg, reproduction rates in rats. Cytogenic Analysis: Subcutaneous It has generally not affected mouse = 8000 mg/kg, Cytogenic fertility or reproduction, except at analysis: Hamster, Fibroblast = 32 very high dosed where effects gm /L. could be attributed to nutritional deficiency. • • SECTION 12 — ECOLOGICAL INFORMATION Hazardous Ingredients Aquatic Toxicity Data When released into the soil, this material is expected to readily biodegrade. When released into the soil, the material is expected to leach into ground water. When released into water this material is expected to readily degrade. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half -life between 1 and 10 days. SECTION 13 — DISPOSAL CONSIDERATIONS Waste Disposal: Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of unused contents according to federal, state, and local regulations. SECTION 14 — TRANSPORTATION INFORMATION Special Shipping Information: No Hazardous Purview Proper Shipping Name UN Number Packing Group Hazard Class DOT Not Regulated. (Land) IMO No Data. (Water) ICAO No Data. (Air) SECTION 15 — REGULATORY INFORMATION WHMIS Classification: (Workplace No Data. Hazardous Material Information System) SARA Title HI: (Superhind Amendments & The components of this product are not subject to the reporting requirements of Sections 302, 304 and Reauthorization Act) 313 of Title II of the Superfund Amendments and Reauthorization Act. OSHA: (Occupational Safety & Health No Data. Administration) TSCA: (Toxic Substance Control Act) Propylene glycol is a "drug" as defined by the Federal Food, Drug and Cosmetic Act and is therefore not a chemical substance under TSCA. VW:: (volatile Organic Compounds) slightly volatile CPR: (Canadian Controlled Products This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations) Regulations. EINECS: (European Inventory of Existing No Data. Commercial Chemical Substances) DSL / NDSL: (Canadian Domestic Substance No Data. I,ist)(Non- Domestic Substance list) CERCL.A: (Comprehensive Response Not applicable Compensation & l.,iability Act) IDL: (Canadian Ingredient Disclosure List) No Data. NFPA (IIMIS) Rating: (Hazardous Materials Health: 0 Identification System) Flammability: 1 _ Reactivity: 1 SECTION 16 — OTHER INFORMATION California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does NOT contain a chemical known to the State of California to cause developmental and reproductive effects. Other U.S. Federal Regulations: Based on this product's use, the requirements of the OSHA Bloodborne pathogen Standard (29 CFR 1910.1030) are not applicable. ANSI Labeling (Based on 129.1. Provided to Summarize Occupational Exposure Hazards): The information contained herein is based on the data available to us and is believed to be correct. However, Nu- Calgon Wholesaler Inc. makes no warranty, expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu- Calgon Wholesaler Inc. assumes no liability for injury from the use of the product described herin. ��!'��' RECEIVED w h olesa l er, inc. J n ler �L3 MATERIAL SAFETY DATA SHEET FEB 15 2011 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION jTy Or TI(}ARD Company Name Phone Number CIIEMT DING DIVISION Nu- Calgon Wholesaler, Inc. (314) 469 -7000 / (800) 554 -5499 (800) 42 Street Address C State Postal Code Last Update 2008 Altom Court St. Louis MO 63146 -4151 6/5/09 Product Name Product Number Product Use EPA Registration # Liquid Scale Dissolver 4330 Acidic scale dissolving solution. N/A SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients % By Wt. CAS Number TLV PEL Hydrochloric Acid > 21 7647 -01-0 5 ppm 5 ppm SECTION 3 - HAZARD IDENTIFICATION Emereencv Overview: Overexposure to product has the following effects: Inhalation of vapors may cause pulmonary edema, collapse of circulatory system and damage to the upper respiratory system. Inhalation may cause coughing, throat burning, choking, bronchitis and difficult breathing. Ingestion is harmful and may be fatal. Ingestion may cause burns. Potential Health Effects Eves: Corrosive. Causes eye damage. Wear splash proof goggles. Provide convenient eyewash stations. Flush immediately with water for 15 minutes. Get prompt medical attention. Skin: Corrosive. Causes irritation and burns. Wear acid- resistant protective gloves, boots, and clothing. Provide convenient safety showers. Remove contaminated clothing. Flush skin thoroughly with water for 15 minutes. Get medical attention if burns persist. Ingestion: Corrosive. Causes irritation and burning in mouth, esophagus, throat and stomach. Avoid swallowing. Drink lots of water or, preferably, milk. Get medical attention if effects persist. Do not induce vomiting. Inhalation: Breathing of vapor can cause respiratory irritation and inflammation. Breathing of mist or liquid can cause burns. Wear approved HCl vapor /mist respirator if exposure is likely. Remove to fresh air. Give artificial respiration or oxygen if needed. Get prompt medical attention. Chronic Exposure: EYES & SKIN: Corrosive to tissues. Causes burns to eyes and skin. INGESTION: Harmful if swallowed. Burns to mouth, throat and stomach are likely. INHALATION: Mists may cause coughing and irritation to respiratory tract. Carcinogenicity: N/A Medical Conditions Aggravated be Exposure: No Data. SECTION 4 - FIRST AID MEASURES Eyes: Flush immediately with water for 15 minutes. Get prompt medical attention. Skin: Wear acid - resistant protective gloves, boots, and clothing. Provide convenient safety showers. Remove contaminated clothing. Flush skin thoroughly with water for 15 minutes. Get medical attention if burns persist. Ingestion: Drink lots of water or, preferably, milk. Get medical attention if effects persist. Do not induce vomiting. Inhalation: Wear approved HCl vapor /mist respirator if exposure is likely. Remove to fresh air. Give artificial respiration or oxygen if needed. Get prompt medical attention. SECTION 5 - FIREFIGHTING MEASURES Flash Point: N /A °F Autoienition Tema: No Data. °C /No Data. °F Hazardous Products of Combustion: N/A Flammable Limits in Air: N/A Extintuishine Media: Product is nonflammable. Use water spray to cool fire. Fire and Explosion Hazards: This product can react with metals to release hydrogen gas. Firemen may need to protect against this. Special Firefighting Procedures: Avoid skin and eye contact, and breathing of acid vapors. Wear head and body protection and HCl respirator if exposure to liquid is likely. SECTION 6 - ACCIDENTAL RELEASE MEASURES Spill or Leak: Small spills can be flushed into normal drainage or into ground with copious amounts of water, or taken up with absorbent material. Larger spills should be contained by dike or other methods and held for collection and/or reuse, or for neutralization with alkali before collection & disposal. People should use eye and skin protection & respirator. SECTION 7 - HANDLING AND STORAGE Handling I'rocedures and Equipment: Check daily for any leaks from containers, vessels, pumps, and piping. Have water hoses and alkali (caustic soda, lime, etc.) convenient. Only use containers and equipment designed for acid service. Storage Requirements: Areas of use and storage should be ventilated adequately to reduce vapors below odor level. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection: A NIOSH - approved respirator for acids is recommended. Eve Protection: Full face shield or goggles. Protective Clothing: Protective clothing and gloves. Exposure Guidelines: No Data. Specific Engineering Controls (such as ventilation, enclosed process): Do not get in eyes, on skin or clothing. Avoid breathing vapor or mist. Keep container closed. Wash thoroughly after handling. Keep from contact with chlorine bleaches. Wash clothing after exposure/use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Orange Liquid Freezing Point: No Data. °C /No Data. °F % Volatile by Weight: No Data.% Color: Orange Vapor Density lair =11: No Data. Evaporation Rate: No Data. Odor: Sharp or Pungent - Acid Vapor Pressure: No Data. Specific Gravity: 1.10 Boiling Point: >100°C/ >212°F Solubility in Water: Complete pH (concentrate): <1.0 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at normal temperatures and storage conditions. Hazardous Polymerization: Does not occur Incompatibilities: strong alkalis, materials not resistant to strong acids, active metals (zinc, aluminum, magnesium, etc.). Reactive Conditions to avoid: Alkaline materials, chlorine bleach or other chlorine containing materials. Strong oxidizers and metals.. Decomposition Products: Contact with metals may generate Hydrogen, which can be explosive. SECTION 11 - TOXICOLOGICAL INFORMATION Ilazardous Ingredients CAS # EINECS # LD 50 of Ingredient LC50 of Ingredient (Specify Species) (Specify Species) Hydrochloric Acid 7647 -01 -0 No Data. 40 MG/KG (Mouse) 3124 PPM (Rat) SECTION 12 - ECOLOGICAL INFORMATION Hazardous Ingredients Aquatic Toxicity Data Hydrochloric Acid This material is expected to be toxic to aquatic life. ' . SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal: Dispose of in accordance with local, state and federal regulations. I SECTION 14 - TRANSPORTATION INFORMATION Special Shipping Information: No Data. Purview Proper Shipping Name UN Number Packint; Group Hazard Class DOT HYDROCHLORIC ACID SOLUTION UNI789 II 8 (Land) IMO No Data. No Data. No Data. No Data. (Water) ICAO No Data. No Data. No Data. No Data. (Air) SECTION 15 - REGULATORY INFORMATION WIIMIS Classification: (Workplace Class E - Corrosive Material. Hazardous Material Information System) SARA Title III: (Superfund Amendments & Hydrochloric Acid Reauthorization Act) OSHA: (Occupational Safety & Health No Data. Administration) TSCA: (Toxic Substance Control Act) No Data. VOC: (volatile Organic Compounds) 0.45% CPR: (Canadian Controlled Products This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations) Regulations. EINECS: (European Inventory of Existing No Data. Commercial Chemical Substances) DSL I NDSL: (Canadian Domestic Substance No Data. List)(Non- Domestic Substance List) CERCLA: (Comprehensive Response No Data. Compensation & Liability Act) IDL: (Canadian Ingredient Disclosure List) No Data. NFPA (HMIS) Rating: (Hazardous Materials Health Hazard • 3 Identification System) Fire Hazard • 0 Reactivity • I Personal Protection...: X SECTION 16 - OT ER INFORMATION I No Data. The information contained herein is based on the data available to us and is believed to be correct. However, Nu -Calgon Wholesaler Inc. makes no warranty, expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu- Calgon Wholesaler Inc. assumes no liability for injury from the use of the product described herin. :$ Nu Calgon RECEIVED MATERIAL SAFETY DATA SHEET 1. Product and Company Identification CITY OF TICARD Product Name NU -BRITE (4291) BUILDING DIVISION CAS # Mixture Product use Coil Cleaner / Degreaser Manufacturer Nu- Calgon 2008 Altom Court St. Louis, MO 63146 US Phone: 314 - 469 -7000 / 800 -554 -5499 Emergency Phone: 1- 800 - 424 -9300 (CHEMTREC) LEGEND Health HMIS /NFPA Q Severe 4 Flammability 0 Serious 3 Moderate 2 Slight 1 Personal Protection El Minimal 0 2. Hazards Identification Emergency overview DANGER -- CORROSIVE Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation, Ingestion. Eyes Causes chemical burns. May cause blindness. Skin Causes chemical burns. Harmful contact may not cause immediate pain. Inhalation May cause respiratory tract irritation or chemical burns. Ingestion Harmful if swallowed. Causes chemical burns to mouth, throat and stomach. Target organs Eyes. Respiratory system. Skin. Chronic effects Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis. Signs and symptoms The product causes burns of eyes, skin and mucous membranes. 3. Composition / Information on Ingredients Ingredient(s) CAS # Percent Sodium hydroxide 1310 -73 -2 10 - 30 Alkyl polyglycoside 110615 -47 -9 1 - 5 4. First Aid Measures First aid procedures Eye contact Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Skin contact Immediately flush with water. Wash with soap and water. Obtain medical attention if irritation persists. Inhalation If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Ingestion Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Use of an impervious apron is recommended. Keep out of reach of children. #18522 Page 1 of 6 Issue date 21- Aug -2008 4291 5. Fire Fighting Measures Flammable properties Not flammable by WHMIS /OSHA criteria. Extinguishing media Suitable extinguishing media Dry chemical. Water spray. Carbon dioxide. Foam. Unsuitable extinguishing media None Protection of firefighters Specific hazards arising from None the chemical Protective equipment for Firefighters should wear full protective clothing including self contained breathing firefighters apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Explosion data Sensitivity to mechanical No impact Sensitivity to static discharge No 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill /leak. Methods for containment Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non - reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re -use. 7. Handling and Storage Handling Use good industrial hygiene practices in handling this material. Do not get this material in your eyes, on your skin, or on your clothing. Storage Keep out of the reach of children.Store in a closed container away from incompatible materials. 8. Exposure Controls / Personal Protection Exposure limits Ingredient(s) Exposure Limits Alkyl polyglycoside ACGIH -TLV None OSHA -PEL None Sodium hydroxide ACGIH -TLV Ceiling: 2 mg /m3 OSHA -PEL TWA: 2 mg /m3 Engineering controls General ventilation normally adequate. Personal protective equipment Eye / face protection Wear chemical goggles. Hand protection Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Rubber apron recommended. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Avoid breathing mists or vapors. General hygiene considerations Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. #18522 Page 2 of 6 Issue date 21- Aug -2008 4291 9. Physical & Chemical Properties Appearance liquid. Color Blue Form Liquid Odor Characteristic, Mild Odor threshold None Physical state Liquid pH 14 (Concentrate) Melting point None Freezing point 0 °C (32.00 °F) Boiling point 100 °C (212.00 °F) Flash point None to boiling Evaporation rate As water Flammability limits in air, lower, % None by volume - Flammability limits in air, upper, % None by volume Vapor pressure Not available Vapor density Not available Specific gravity 1.242 ± 0.005 Octanol /water coefficient Not available Solubility (H20) Complete Auto - ignition temperature None VOC (Weight %) None Viscosity Less than 5cps Percent volatile 76 10. Chemical Stability & Reactivity Information Chemical stability Stable under recommended storage conditions. Conditions to avoid Reacts violently with acids. This product may react with oxidizing agents. Do not mix with other chemicals. Hazardous vapours may be produced when mixed with chlorinated detergents or sanitizers. Incompatible materials Acids. Oxidizing agents. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Possibility of hazardous reactions Hazardous polymerization does not occur. 11. Toxicological information Component analysis - LC50 Ingredient(s) LC50 Alkyl polyglycoside Not available Sodium hydroxide Not available Component analysis - Oral LD50 Ingredient(s) LD50 Alkyl polyglycoside 5000 mg /kg rat Sodium hydroxide 140 mg /kg rat Effects of acute exposure Eye Causes chemical burns. May cause blindness. Skin Causes chemical burns. Harmful contact may not cause immediate pain. Inhalation May cause respiratory tract irritation or chemical burns. Ingestion Harmful if swallowed. Causes chemical burns to mouth, throat and stomach. Sensitization Non - hazardous by WHMIS /OSHA criteria. #18522 Page 3 of 6 Issue date 21- Aug -2008 4291 Chronic effects Non - hazardous by WHMIS /OSHA criteria. Carcinogenicity Non - hazardous by WHMIS /OSHA criteria. Mutagenicity Non - hazardous by WHMIS /OSHA criteria. Reproductive effects Non - hazardous by WHMIS /OSHA criteria. Teratogenicity Non - hazardous by WHMIS /OSHA criteria. 12. Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns. Ecotoxicity - Freshwater Fish Species Data Sodium hydroxide 1310 -73 -2 96 Hr LC50 Oncorhynchus mykiss: 45.4 mg/L [static] Environmental effects Not available Aquatic toxicity Not available Persistence / degradability Not available Bioaccumulation / accumulation Not available Partition coefficient Not available Mobility in environmental media Not available Chemical fate information Not available 13. Disposal Considerations Waste codes Not available Disposal instructions Dispose in accordance with all applicable regulations. Waste from residues / unused Not available products Contaminated packaging Not available 14. Transport Information U.S. Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Corrosive liquid, basic, inorganic, n.o.s. (SODIUM HYDROXIDE) Hazard class 8 UN number UN3266 6 1� �1 Packing group II �+ �� Additional information: GQRRQS�YE Special provisions B2, 1B2, T11, TP2, TP27 8 Packaging exceptions <0.3 Gallon - Limited Quantity ERG number 154 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (SODIUM HYDROXIDE) Hazard class 8 UN number UN3266 e Packing group Additional information: Special provisions 16 8 Packaging exceptions <1L - Limited Quantity #18522 Page 4 of 6 Issue date 21- Aug -2008 4291 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada - WHMIS - Ingredient Disclosure List Sodium hydroxide 1310 -73 -2 1 % US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. U.S. - CERCLA /SARA - Hazardous Substances and their Reportable Quantities Sodium hydroxide 1310 -73 -2 1000 Lb final RQ; 454 kg final RQ Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous Yes chemical CERCLA (Superfund) reportable quantity Sodium hydroxide: 1000.0000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Not available Clean Water Act (CWA) Hazardous substance Safe Drinking Water Act (SDWA) Not available Drug Enforcement Agency (DEA) Not applicable Food and Drug Administration Not applicable (FDA) WHMIS status Controlled WHMIS classification Class E - Corrosive Material WHMIS labeling 5v) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances Sodium hydroxide 1310 -73 -2 Present U.S. - Louisiana - Reportable Quantity List for Pollutants Sodium hydroxide 1310 -73 -2 1000 Lb final RQ; 454 kg final RQ U.S. - Massachusetts - Right To Know List Sodium hydroxide 1310 -73 -2 Present U.S. - Minnesota - Hazardous Substance List Sodium hydroxide 1310 -73 -2 Present U.S. - New Jersey - Right to Know Hazardous Substance List Sodium hydroxide 1310 -73 -2 sn 1706 U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances Sodium hydroxide 1310 -73 -2 1000 Lb RQ (air); 100 lb RQ (land/water) U.S. - Pennsylvania - RTK (Right to Know) List Sodium hydroxide 1310 -73-2 Environmental hazard U.S. - Rhode Island - Hazardous Substance List Sodium hydroxide 1310 -73-2 Toxic; Flammable #18522 Page 5 of 6 Issue date 21- Aug -2008 4291 Inventory name Country(s) or region Inventory name On inventory (yes /no)* Canada Domestic Substances List (DSL) No Canada Non - Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 21- Aug -2008 Effective date 15- Aug -2008 Expiry date 15- Aug -2011 Prepared by Nu- Calgon Technical Service (314) 469 -7000 #16522 Page 6 of 6 Issue date 21- Aug -2008 4291 Material Safety Data Sheet Honeywell RECEIVED Genetron® 22 FEB 152011 Version 2 Revision Date 10/01/2010 Printalt' %1! IP BUILDING iIVISI3N SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Genetron® 22 MSDS Number : 000000009890 Product Use Description Refrigerant Company : Honeywell International, Inc. 101 Columbia Road Morristown, NJ 07962 -1057 For more information call : 800 - 522 -8001 (Monday- Friday, 9:OOam- 5:OOpm) In case of emergency call : Medical: 1- 800 - 498 -5701 or +1-651-523-0309 : Transportation: 1- 800 - 424 -9300 or +1- 703 - 527 -3887 : (24 hours /day, 7 days /week) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : Liquefied gas Color : colourless Odor : slight Hazard Summary : Warning! Container under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. Gas reduces oxygen available for breathing. Causes asphyxiation in high concentrations. The victim will not realize that he /she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. May cause drowsiness and dizziness. Do not breathe vapour. Irritating to eyes and skin. Avoid contact with skin, eyes and clothing. At higher temperatures, ( >250 °C), decomposition products may include hydrochloric acid (HCI), hydrofluoric acid (HF) and carbonyl halides. The ACGIH Threshold Limit Values (2007) for Hydrogen Fluoride are TLV- TWA 0.5 ppm and Ceiling Exposure Limit 2 ppm. Potential Health Effects Skin : Avoid skin contact with leaking liquid (danger of frostbite). Page 1 / 11 • Material Safety Data Sheet Honeywell Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 May cause frostbite. Irritating to skin. Eyes : Causes serious eye irritation. May cause frostbite. Ingestion : Unlikely route of exposure. Effects due to ingestion may include: Gastrointestinal discomfort Inhalation : Gas reduces oxygen available for breathing. Causes asphyxiation in high concentrations. The victim will not realize that he /she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. Vapours may cause drowsiness and dizziness. Chronic Exposure : None known. Carcinogenicity No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA. SECTION 3. COMPOSITION /INFORMATION ON INGREDIENTS Formula : CHCIF2 Chemical Name CAS -No. Concentration Chlorodifluoromethane 75 -45 -6 100.00% SECTION 4. FIRST AID MEASURES Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline- ephedrine group. Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician. Page 2 / 11 Material Safety Data Sheet Honeywell Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician. Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately. Notes to physician Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of symptoms and the clinical conditions. Treat frost- bitten areas as needed. SECTION 5. FIRE - FIGHTING MEASURES Flash point : not applicable Lower explosion limit : None Upper explosion limit : None Suitable extinguishing : The product is not flammable. media ASHRAE 34 Use water spray, alcohol- resistant foam, dry chemical or carbon dioxide. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards during fire : Contents under pressure. fighting This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run -off from fire fighting to enter drains or water courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen chloride (HCI). Page 3 / 11 Material Safety Data Sheet H oneywe ll Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 Hydrogen fluoride Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Special protective : In the event of fire and /or explosion do not breathe fumes. equipment for fire- fighters Wear self- contained breathing apparatus and protective suit. No unprotected exposed skin areas. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill /leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite). Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been tested and determined safe. Ensure that the oxygen content is >= 19.5 %. Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evaporates readily. Methods for cleaning up : Ventilate the area. SECTION 7. HANDLING AND STORAGE Handling Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame Page 4 / 11 Material Safety Data Sheet Honeywell Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use. Advice on protection : The product is not flammable. against fire and explosion Can form a combustible mixture with air at pressures above atmospheric pressure. Storage Requirements for storage : Pressurized container: Protect from sunlight and do not expose areas and containers to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Keep containers tightly closed in a dry, cool and well - ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage. SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Engineering measures : General room ventilation is adequate for storage and handling. Perform filling operations only at stations with exhaust ventilation facilities. Eye protection : Wear as appropriate: Safety glasses with side - shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Polyvinyl alcohol or nitrile- butyl- rubber gloves Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves /face shield /eye protection. Page 5 / 11 Material Safety Data Sheet Honeywell Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Wear a positive - pressure supplied -air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. For rescue and maintenance work in storage tanks use self - contained breathing apparatus. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re -use. Keep working clothes separately. Exposure Guidelines Chlorodifluoromethane 75 -45 -6 ACGIH TWA 1,000 ppm NIOSH STEL 1,250 ppm 4,375 mg /m3 NIOSH REL 1,000 ppm 3,500 mg /m3 OSHA Z1A TWA 1,000 ppm 3,500 mg /m3 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquefied gas Color : colourless Odor : slight Molecular Weight : 86.46 g /mol pH : neutral Melting point /range : -160 °C ( -256 °F) Boiling point/boiling range : -40.8 °C ( -41.4 °F) Vapor pressure : 9,384 hPa at 21.1 °C (70.0 °F) Page 6 / 11 Material Safety Data Sheet Honeywell Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 Vapor pressure : 21,470 hPa at 54.4 °C (129.9 °F) Relative vapour density : 3 (Air = 1.0) Density : 1.21 g /cm3 at 21.1 °C (70.0 °F) Water solubility : 3.0 g/I Partition coefficient: n- : log Pow: 1.08 - 1.13 octanol /water The product is more soluble in octanol. SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Decomposes under high temperature. Some risk may be expected of corrosive and toxic decomposition products. Can form a combustible mixture with air at pressures above atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure. Materials to avoid : Finely divided aluminium Potassium Calcium Powdered metals Aluminium Magnesium Zinc Hazardous decomposition : In case of fire hazardous decomposition products may be products produced such as: Gaseous hydrogen chloride (HCI). Gaseous hydrogen fluoride (HF). Carbonyl halides Carbon monoxide Carbon dioxide (CO2) Thermal decomposition : >250 °C Hazardous reactions : Hazardous polymerisation does not occur. Stable under normal conditions. Page 7 / 11 Material Safety Data Sheet H oneywe ll Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 SECTION 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity : LC50: > 300000 ppm Exposure time: 4 h Species: rat Repeated dose toxicity : Species: rat Application Route: Inhalation Exposure time: Lifetime Exposure NOEL: 10000 ppm Note: Lifetime exposure of male rats was associated with a small increase in salivary gland fibrosarcomas. Further information : Acute toxicity Chlorodifluoromethane (HCFC -22): Cardiac sensitisation threshold (dog): 50000 ppm. Rapid evaporation of the liquid may cause frostbite. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. May cause cardiac arrhythmia. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish : static test LC50: 777 mg /I Exposure time: 96 h Species: Danio rerio (zebra fish) Toxicity to daphnia and other : static test aquatic invertebrates. EC50: 433 mg /I Exposure time: 48 h Species: Daphnia magna (Water flea) Further information on ecology Additional ecological : Accumulation in aquatic organisms is unlikely. information This product contains greenhouse gases which may contribute to global warming. Do NOT vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any Page 8/11 Material Safety Data Sheet H oneywe ll Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 residual must be recovered. This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations at 40 CFR Part 82. Section 611 requires the following label text on all shipments of this product: Warning: Contains Chlorodifluoromethane (HCFC -22), a substance which harms public health and environment by destroying ozone in the upper atmosphere. Refer to sections 610 and 612 for list of acceptable and unacceptable uses for this product. SECTION 13. DISPOSAL CONSIDERATIONS Waste Information: Observe all Federal, State, and Local Environmental regulations. Additional advice : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling. SECTION 14. TRANSPORT INFORMATION DOT UN /ID No. : UN 1018 Proper shipping name : CHLORODIFLUOROMETHANE Class 2.2 Packing group Hazard Labels 2.2 IATA UN /ID No. : UN 1018 Description of the goods : CHLORODIFLUOROMETHANE Class : 2.2 Hazard Labels : 2.2 Packing instruction (cargo : 200 aircraft) Packing instruction : 200 (passenger aircraft) IMDG UN /ID No. : UN 1018 Description of the goods : CHLORODIFLUOROMETHANE Class : 2.2 Hazard Labels : 2.2 EmS Number : F -C Marine pollutant : no Page 9 / 11 Material Safety Data Sheet Honeywell Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 SECTION 15. REGULATORY INFORMATION Inventories 1907/2006 (EU) : This mixture contains only ingredients which have been subject to a pre- registration according to Regulation (EC) No. 1907/2006 (REACH). US. Toxic Substances : On TSCA Inventory Control Act Australia. Industrial : On the inventory, or in compliance with the inventory Chemical (Notification and Assessment) Act Canada. Canadian : All components of this product are on the Canadian DSL list. Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) Japan. Kashin -Hou Law : On the inventory, or in compliance with the inventory List Korea. Toxic Chemical : On the inventory, or in compliance with the inventory Control Law (TCCL) List Philippines. The Toxic : On the inventory, or in compliance with the inventory Substances and Hazardous and Nuclear Waste Control Act China. Inventory of Existing : On the inventory, or in compliance with the inventory Chemical Substances NZIOC - New Zealand : On the inventory, or in compliance with the inventory National regulatory information SARA 313 Components : Chlorodifluoromethane 75 -45 -6 SARA 311/312 Hazards : Acute Health Hazard Sudden Release of Pressure Hazard Page 10 / 11 Material Safety Data Sheet H oneywe ll Genetron® 22 Version 2 Revision Date 10/01/2010 Print Date 11/15/2010 California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Massachusetts RTK : Chlorodifluoromethane 75 -45 -6 New Jersey RTK : Chlorodifluoromethane 75 -45 -6 Pennsylvania RTK : Chlorodifluoromethane 75 -45 -6 WHMIS Classification : A This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Global warming potential : 1,500 Ozone depletion potential : 0.06 (ODP) SECTION 16. OTHER INFORMATION HMIS III NFPA Health hazard : 1 2 Flammability : 1 1 Physical Hazard : 0 Instability : 0 Page 11 / 11 Material Safety Data Sheet H oneywe ll J RECEIVED FEB 15 Genetron® AZ -50 (R -507) CITY OFTIGARD BUILDING DIVISION Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Genetron® AZ -50 (R -507) MSDS Number : 000000009882 Product Use Description : Refrigerant Company : Honeywell International, Inc. 101 Columbia Road Morristown, NJ 07962 -1057 For more information call : 800 - 522 -8001 (Monday- Friday, 9:OOam- 5:OOpm) In case of emergency call : Medical: 1- 800 - 498 -5701 or +1- 651 - 523 -0309 : Transportation: 1- 800 - 424 -9300 or +1-703-527-3887 : (24 hours /day, 7 days /week) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : Liquefied gas Color : colourless Odor : very faint sweet Hazard Summary : Warning! Container under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. Gas reduces oxygen available for breathing. Causes asphyxiation in high concentrations. The victim will not realize that he /she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. May cause drowsiness and dizziness. Do not breathe vapour. Irritating to eyes and skin. Avoid contact with skin, eyes and clothing. At higher temperatures, ( >250 C), decomposition products may include hydrofluoric acid (HF) and carbonyl halides. The ACGIH Threshold Limit Values (2007) for Hydrogen Fluoride are TLV -TWA 0.5 ppm and Ceiling Exposure Limit 2 ppm. Potential Health Effects Skin : Avoid skin contact with leaking liquid (danger of frostbite). Page 1 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 May cause frostbite. Irritating to skin. Eyes : Causes serious eye irritation. May cause frostbite. Ingestion : Unlikely route of exposure. Effects due to ingestion may include: Gastrointestinal discomfort Inhalation : Gas reduces oxygen available for breathing. Causes asphyxiation in high concentrations. The victim will not realize that he /she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. Vapours may cause drowsiness and dizziness. Chronic Exposure : None known. Carcinogenicity No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA. SECTION 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Concentration Pentafluoroethane 354 -33 -6 50.00% 1,1,1- Trifluoroethane 420 -46 -2 50.00% SECTION 4. FIRST AID MEASURES Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline- ephedrine group. Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician. Page 2 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician. Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately. Notes to physician Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of symptoms and the clinical conditions. Treat frost- bitten areas as needed. SECTION 5. FIRE - FIGHTING MEASURES Flash point : not applicable Ignition temperature : >750 °C (1,382 °F) Lower explosion limit : ASTM E -681 None Upper explosion limit : ASTM E -681 None Suitable extinguishing : The product is not flammable. media Use water spray, alcohol- resistant foam, dry chemical or carbon dioxide. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards during fire : Contents under pressure. fighting This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run -off from fire fighting to enter drains or water courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Page 3 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 Rapid evaporation of the liquid may cause frostbite. In case of fire hazardous decomposition products may be produced such as: Hydrogen halides Hydrogen fluoride Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Special protective : In the event of fire and /or explosion do not breathe fumes. equipment for fire- fighters Wear self- contained breathing apparatus and protective suit. No unprotected exposed skin areas. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill /leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite). Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been tested and determined safe. Ensure that the oxygen content is >= 19.5 %. Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evaporates readily. Methods for cleaning up : Ventilate the area. SECTION 7. HANDLING AND STORAGE Handling Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Use only in well - ventilated areas. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Page 4 / 12 Material Safety Data Sheet H oneywe ll Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use. Advice on protection : The product is not flammable. against fire and explosion Can form a combustible mixture with air at pressures above atmospheric pressure. Storage Requirements for storage : Pressurized container: Protect from sunlight and do not expose areas and containers to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Keep containers tightly closed in a dry, cool and well - ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage. SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Engineering measures : General room ventilation is adequate for storage and handling. Perform filling operations only at stations with exhaust ventilation facilities. Eye protection : Wear as appropriate: Safety glasses with side - shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Page 5 / 12 Material Safety Data Sheet H oneywe ll Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 Polyvinyl alcohol or nitrile- butyl- rubber gloves Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves /face shield /eye protection. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Wear a positive - pressure supplied -air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. For rescue and maintenance work in storage tanks use self - contained breathing apparatus. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re -use. Keep working clothes separately. Exposure Guidelines Contains no substances with occupational exposure limit values. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquefied gas Color : colourless Odor : very faint sweet pH : neutral Freezing point : not determined Boiling point/boiling range : -46.7 °C ( -52.1 °F) Vapor pressure : 10,611 hPa at 21.1 °C (70.0 °F) Vapor pressure : 25,289 hPa at 54.4 °C (129.9 °F) Relative vapour density : 3.43 (Air = 1.0) Page 6 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 Density : 1.07 g /cm3 at 21.1 °C (70.0 °F) Water solubility : 1.5 g/I Partition coefficient: n- : log Pow: 1.48 octanol /water SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Decomposes under high temperature. Some risk may be expected of corrosive and toxic decomposition products. Can form a combustible mixture with air at pressures above atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure. Materials to avoid : Finely divided aluminium Potassium Calcium Powdered metals Aluminium Magnesium Zinc Hazardous decomposition : Halogenated compounds products Hydrogen fluoride Carbonyl halides Carbon oxides Thermal decomposition : >250 °C To avoid thermal decomposition, do not overheat. Hazardous reactions : Hazardous polymerisation does not occur. Stable under normal conditions. SECTION 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity : LC50: > 800000 ppm Exposure time: 4 h Species: rat Test substance: Ethane, pentafluoro- (HFC -125) Page 7 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 : LC50: > 250000 ppm Exposure time: 4 h Species: rat Test substance: 1,1,1- trifluoroethane (HFC -143a) Sensitisation Pentafluoroethane : Cardiac sensitization Species: dogs Note: No- observed -effect level 75,000 ppm Lowest observable effect level 100,000 ppm 1,1,1- Trifluoroethane : Cardiac sensitization Species: dogs Note: 1,1,1,2- tetrafluoroethane (HFC- 134a): Cardiac sensitisation threshold (dog): 80000 ppm. Repeated dose toxicity : Species: rat Note: NOEL 20,000 ppm Genotoxicity in vitro Pentafluoroethane : Test Method: Ames test Result: negative 1,1,1- Trifluoroethane : Test Method: Ames test Result: negative : Cell type: Human lymphocytes Result: negative : Cell type: Chinese Hamster Ovary Cells Result: negative : Cell type: Human lymphocytes Result: negative Genotoxicity in vivo 1,1,1 - Trifluoroethane : Species: mouse Cell type: Bone marrow Application Route: Inhalation Result: negative Teratogenicity Page 8 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 Pentafluoroethane : Species: rabbit Application Route: Inhalation exposure NOAEL,Teratog: 50,000 ppm NOAEL,Maternal: 50,000 ppm Note: Did not show teratogenic effects in animal experiments. Species: rat Application Route: Inhalation exposure NOAEL,Teratog: 50,000 ppm NOAEL,Maternal: 50,000 ppm Note: Did not show teratogenic effects in animal experiments. 1,1,1 - Trifluoroethane : Species: rat Application Route: Inhalation exposure NOAEL,Teratog: 40,000 ppm NOAEL,Maternal: 40,000 ppm Note: Did not show teratogenic effects in animal experiments. Species: rabbit Application Route: Inhalation exposure NOAEL,Teratog: 40,000 ppm NOAEL,Maternal: 40,000 ppm Note: Did not show teratogenic effects in animal experiments. • Further information SECTION 12. ECOLOGICAL INFORMATION Biodegradability Pentafluoroethane : Result: Not readily biodegradable. Value: 5 % Method: OECD 301 D Further information on ecology Additional ecological : Accumulation in aquatic organisms is unlikely. information This product contains greenhouse gases which may contribute to global warming. Do NOT vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any residual must be recovered. Page 9 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 SECTION 13. DISPOSAL CONSIDERATIONS Waste Information: Observe all Federal, State, and Local Environmental regulations. Additional advice : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling. SECTION 14. TRANSPORT INFORMATION DOT UN /ID No. : UN 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. (Pentafluoroethane, 1,1,1 - Trifluoroethane) Class 2.2 Packing group Hazard Labels 2.2 IATA UN /ID No. : UN 3163 Description of the goods : LIQUEFIED GAS, N.O.S. (Pentafluoroethane, 1,1,1 - Trifluoroethane) Class : 2.2 Hazard Labels : 2.2 Packing instruction (cargo : 200 aircraft) Packing instruction : 200 (passenger aircraft) IMDG UN /ID No. : UN 3163 Description of the goods : LIQUEFIED GAS, N.O.S. (PENTAFLUOROETHANE, 1,1,1 - TRIFLUOROETHANE) Class : 2.2 Hazard Labels : 2.2 EmS Number : F -C Marine pollutant : no SECTION 15. REGULATORY INFORMATION Inventories 1907/2006 (EU) : This mixture contains only ingredients which have been subject to a pre- registration according to Regulation (EC) No. 1907/2006 (REACH). Page 10 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 US. Toxic Substances : On TSCA Inventory Control Act Australia. Industrial : On the inventory, or in compliance with the inventory Chemical (Notification and Assessment) Act Canada. Canadian : All components of this product are on the Canadian DSL list. Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) Japan. Kashin -Hou Law : On the inventory, or in compliance with the inventory List Korea. Toxic Chemical : On the inventory, or in compliance with the inventory Control Law (TCCL) List Philippines. The Toxic : On the inventory, or in compliance with the inventory Substances and Hazardous and Nuclear Waste Control Act China. Inventory of Existing : On the inventory, or in compliance with the inventory Chemical Substances NZIOC - New Zealand : On the inventory, or in compliance with the inventory National regulatory information SARA 311/312 Hazards : Acute Health Hazard Sudden Release of Pressure Hazard California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Page 11 / 12 Material Safety Data Sheet Honeywell Genetron® AZ -50 (R -507) Version 2 Revision Date 10/04/2010 Print Date 11/15/2010 WHMIS Classification : A This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Global warming potential : 3,850 Ozone depletion potential : 0 (ODP) SECTION 16. OTHER INFORMATION HMIS III NFPA Health hazard : 1 2 Flammability : 1 1 Physical Hazard : 0 Instability : 0 Page 12 / 12 3a i -C on °� MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product Name Ty -Ion B -20 (7537) RECEIVED CAS # Mixture Product use Dispersant and pH indicator Manufacturer Nu- Calgon FEB 1 5 2011 2008 Altom Court St. Louis, MO 63146 US CITY OF TIGARD Phone: 314 - 469 -7000 / 800 - 554 -5499 BUILDING DIVISION Emergency Phone: 1- 800 - 424 -9300 (CHEMTREC) LEGEND Health ®© HMIS /NFPA (} Severe 4 Flammability 0 Serious 3 r� 2 \ 1 Moderate 1 OX Slight Personal Protection II Minimal 0 2. Hazards Identification Emergency overview DANGER Oxidizing material. May cause severe irritation or burns to the eyes, skin, gastrointestinal tract, and respiratory system. CONTAINS MATERIAL WHICH MAY CAUSE CANCER. Contains a potential reproductive toxin. Potential short term health effects Routes of exposure Eye, Skin contact, Skin absorption, Inhalation, Ingestion. Eyes May cause chemical burns. May cause blindness. Skin As per Policy Issue Sheet Number 60, strongly acidic or alkaline substances with a demonstrated pH of 2 or less or 11.5 or greater, need not be tested for primary dermal irritation, owing to their predictable corrosive properties. In lieu of skin corrosivity test data on animals, this product is considered corrosive in Canada based on the pH of the product as a whole. May cause severe irritation or chemical burns. May be absorbed through the skin. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Ingestion Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Target organs Eyes. Respiratory system. Skin. Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis. Signs and symptoms Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms can include irritation, redness, scratching of the cornea, and tearing. 3. Composition / Information on Ingredients Ingredient(s) CAS # Percent Sodium metasilicate pentahydrate 10213 -79 -3 7 - 13 Sodium tetraborate pentahydrate 12179 -04 -3 5 - 10 Sodium nitrite 7632 -00 -0 10 - 30 Phenolphthalein 77 -09 -8 0 - 0.1 #19415 Page 1 of 6 Issue date 28 -Oct -2009 7537 • 4. First Aid Measures First aid procedures Eye contact Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Skin contact Immediately flush with water. Wash with soap and water. Obtain medical attention if irritation persists. Inhalation If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. Ingestion Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Notes to physician Symptoms may be delayed. General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Not flammable by WHMIS /OSHA criteria. Containers may explode when heated. Extinguishing media Suitable extinguishing media Treat for surrounding material. Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from Container may explode in heat of fire. the chemical Protective equipment for Firefighters should wear full protective clothing including self contained breathing firefighters apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Explosion data Sensitivity to mechanical Not available impact Sensitivity to static discharge Not available 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill /leak. Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non - reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re -use. 7. Handling and Storage Handling Use good industrial hygiene practices in handling this material. Do not get this material in your eyes, on your skin, or on your clothing. Storage Keep out of reach of children. Store in a closed container away from incompatible materials. Keep away from heat, open flames or other sources of ignition. #19415 Page 2 of 6 Issue date 28 -Oct -2009 7537 8. Exposure Controls / Personal Protection Exposure limits Ingredient(s) Exposure Limits Phenolphthalein ACGIH -TLV Not established OSHA -PEL Not established Sodium metasilicate pentahydrate ACGIH -TLV Not established OSHA -PEL Not established Sodium nitrite ACGIH -TLV Not established OSHA -PEL Not established Sodium tetraborate pentahydrate ACGIH -TLV TWA: 2 mg /m3 STEL: 6 mg /m3 OSHA -PEL Not established Engineering controls General ventilation normally adequate. Personal protective equipment Eye / face protection Chemical splash goggles. Wear chemical goggles. Hand protection Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. 9. Physical and Chemical Properties Appearance aqueous solution Color Clear Red Form Liquid Odor Odorless Odor threshold Not available Physical state Liquid pH 11.8 - 12.4 Melting point Not available Freezing point Not available Boiling point Not available Flash point Not available Pour point Not available Evaporation rate Not available Flammability limits in air, lower, % Not available by volume Flammability limits in air, upper, % Not available by volume Vapor pressure Not available Vapor density Not available Specific gravity 1.20 - 1.26 g /mL #19415 Page 3 of 6 Issue date 28 -Oct -2009 7537 Octanol /water coefficient Not available Solubility (H20) Complete Auto - ignition temperature Not available VOC (Weight %) Not available Viscosity Not available Percent volatile Not available 10. Stability and Reactivity Chemical stability Stable under recommended storage conditions. Conditions to avoid Reacts violently with acids. This product may react with oxidizing agents. Do not mix with other chemicals. Incompatible materials Acids. Oxidizing agents. Amines. Ammonium salts. Cyanides. Reducing agents. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Possibility of hazardous reactions Hazardous polymerization does not occur. 11. Toxicological Information Component analysis - LC50 Ingredient(s) LC50 Phenolphthalein Not available Sodium metasilicate pentahydrate Not available Sodium nitrite 175 mg /kg mouse; 5.5 mg /I /4h rat Sodium tetraborate pentahydrate Not available Component analysis - Oral LD50 Ingredient(s) LD50 Phenolphthalein 1000 mg /kg rat Sodium metasilicate pentahydrate Not available Sodium nitrite 88 mg /kg rat Sodium tetraborate pentahydrate 3400 mg /kg rat Effects of acute exposure Eye May cause chemical burns. May cause blindness. Skin As per Policy Issue Sheet Number 60, strongly acidic or alkaline substances with a demonstrated pH of 2 or less or 11.5 or greater, need not be tested for primary dermal irritation, owing to their predictable corrosive properties. In lieu of skin corrosivity test data on animals, this product is considered corrosive in Canada based on the pH of the product as a whole. May cause severe irritation or chemical burns. May be absorbed through the skin. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Ingestion Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Sensitization Non - hazardous by WHMIS /OSHA criteria. Chronic effects Non - hazardous by WHMIS /OSHA criteria. Carcinogenicity See below. ACGIH - Threshold Limit Values - Carcinogens Sodium tetraborate pentahydrate 12179 -04 -3 A4 - Not Classifiable as a Human Carcinogen (listed under Borate compounds, inorganic) IARC - Group 2B (Possibly Carcinogenic to Humans) Phenolphthalein 77 -09 -8 Monograph 76 [2000] NTP (National Toxicology Program) - Report on Carcinogens - Reasonably Anticipated to be Human Carcinogens Phenolphthalein 77 -09 -8 Reasonably Anticipated To Be A Human Carcinogen U.S. - California - Proposition 65 - Carcinogens List Phenolphthalein 77 -09 -8 carcinogen, initial date 5/15/98 Mutagenicity Non - hazardous by WHMIS /OSHA criteria. Reproductive effects Contains a potential reproductive toxin. Borates may cause harmful reproductive effects based on animal data. #19415 Page 4 of 6 Issue date 28 -Oct -2009 7537 Teratogenicity Non - hazardous by WHMIS /OSHA criteria. Synergistic Materials Not available 12. Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns. Ecotoxicity - Freshwater Fish Species Data Sodium nitrite 7632 -00 -0 96 Hr LC50 Oncorhynchus mykiss: 0.19 mg /L [flow - through] (juvenile); 96 Hr LC50 Oncorhynchus mykiss:0.092 -0.13 mg /L [flow- through]; 96 Hr LC50 Oncorhynchus mykiss:0.4 -0.6 mg /L [semi- static]; 96 Hr LC50 Oncorhynchus mykiss:0.65 -1 mg /L [static]; 96 Hr LC50 Pimephales promelas:2.3 mg /L [flow- through]; 96 Hr LC50 Pimephales promelas:20 mg /L [static] Environmental effects Not available Aquatic toxicity Not available Persistence / degradability Not available Bioaccumulation / accumulation Not available Partition coefficient Not available Mobility in environmental media Not available Chemical fate information Not available Other adverse effects Not available 13. Disposal Considerations Waste codes Not available Disposal instructions Dispose in accordance with all applicable regulations. Waste from residues / unused Not available products Contaminated packaging Not available 14. Transport Information U.S. Department of Transportation (DOT) Limited Quantity Transportation of Dangerous Goods (TDG - Canada) Limited Quantity 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada - WHMIS - Ingredient Disclosure List Sodium nitrite 7632 -00 -0 1 % US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Sodium nitrite 7632 -00 -0 100 Lb final RQ; 45.4 kg final RQ U.S. - CERCLA/SARA - Section 313 - Emission Reporting Sodium nitrite 7632 -00 -0 1.0 % de minimis concentration U.S. - CWA (Clean Water Act) - Hazardous Substances Sodium nitrite 7632 -00 -0 Present Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous Yes chemical CERCLA (Superfund) reportable quantity Sodium hydroxide: 1000.0000 Sodium nitrite: 100.0000 #19415 Page 5 of 6 Issue date 28- Oct -2009 7537 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Section 302 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Not available Clean Water Act (CWA) Not available WHMIS status Controlled WHMIS classification Class C - Oxidizing Material, Class D - Division 2A, Class E - Corrosive Material WHMIS labeling State regulations WARNING: This product contains a chemical known to the State of California to cause cancer. U.S. California - CCR Section 339 - Director's List of Hazardous Substances Sodium nitrite 7632 -00 -0 Present Sodium tetraborate pentahydrate 12179 -04 -3 Present (exempt except when present as free crystal /powder, listed under Borates, tetra, sodium salts) U.S. - California - Proposition 65 - Carcinogens List Phenolphthalein 77 -09 -8 carcinogen, initial date 5/15/98 U.S. - Louisiana - Reportable Quantity List for Pollutants Sodium nitrite 7632 -00 -0 100 Lb final RQ; 45.4 kg final RQ U.S. - Massachusetts - Right To Know List Sodium nitrite 7632 -00 -0 Present Sodium tetraborate pentahydrate 12179 -04 -3 Present U.S. - New Jersey - Right to Know Hazardous Substance List Phenolphthalein 77 -09 -8 sn 4110 Sodium nitrite 7632 -00 -0 sn 2258 U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances Sodium nitrite 7632 -00 -0 100 Lb RQ (air); 100 lb RQ (land /water) U.S. - Pennsylvania - RTK (Right to Know) List Sodium nitrite 7632 -00 -0 Environmental hazard Inventory name Country(s) or region Inventory name On inventory (yes /no)* Canada Domestic Substances List (DSL) Yes Canada Non - Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 28 -Oct -2009 Effective date 31- Oct -2009 Expiry date 31- Oct -2012 Prepared by Nu- Calgon Technical Service (314) 469 -7000 Other information For an updated MSDS, please contact the supplier /manufacturer listed on the first page of the document. #19415 Page 6 of 6 Issue date 28- Oct -2009 7537 if RECEIVED •Cto. Caton MATERIAL SAFETY DATA SHEET FEB 15 2011 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION CITY OFTIGARD Company Name Phone Number CiiEN ING DIVISION Nu- Calgon Wholesaler, Inc. (314) 469 -7000 / (800) 554 -5499 (800) 4 4 -9300 Street Address .ity State Postal Code Last Update 2008 Altom Court St. Louis MO 63146 -4151 6/11/09 Product Name Product Number Product Use EPA Registration # Calclean 4135 Cleaner/Degreaser N/A SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients % By Wt. CAS Number TLV PEL Sodium Metasilicate 1 -5% 6834 -92 -0 None Established None Established Nonionic Surfactant 1 -5% Proprietary None Established None Established Sodium Tripolyphosphate 1 -5% 7758 -29 -4 None Established None Established • SECTION 3 - HAZARD IDENTIFICATION Emergency Overview: Alkaline detergent. Do not get in eyes, on skin or clothing. Avoid breathing spray or mist. Use only with adequate personal protection equipment. Potential Health Effects Eves: Prolonged contact with eyes will cause severe irritation, possibly burns and permanent damage.. Skin: Prolonged or repeated contact with skin can cause moderate to severe irritation with pain; irritation may be delayed. Ingestion: Harmful if swallowed - may cause bums of the mouth, throat and stomach if ingested. Inhalation: Inhalation of generated mists or spray may cause respiratory irritation or chemical burn of mouth, throat, and stomach. Chronic Exposure: None currently known. Carcinogenicity: None Medical Conditions Aggravated be Exposure: An existing dermatitis. -- SECTION 4 - FIRST AID MEASURES Eves: .Flush eyes with water for at least 30 minutes and call a physician immediately. Speed of action is essential. Skin: Remove contaminated clothing. Wash with large amounts of soap and water. If skin still feels slippery or if irritation persists, continue washing. Consult a physician in the case of any prolonged irritation Ingestion: Do not induce vomiting. Immediately give large quantities of water or (preferably) milk and call a physician. Speed of action is essential. Inhalation: Remove to fresh air. Start artificial respiration if necessary. Oxygen may be administered. Call a physician. SECTION 5 - FIREFIGHTING MEASURES Flash Point: None to Boiling °F Autoignition Temp: N /A °C/N /A °F Hazardous Products of Combustion: Burning may produce oxides of carbon and other substances. Flammable Limits in Air: N/A Extinguishing Media: Product is non - combustible. Water Spray (Fog), Dry Chemical; CO2; or Foam may be used where product is stored. Fire and Explosion Hazards: None Special Firefighting Procedures: Do not enter confined fire - spaces without protective clothing and self-contained air supply. r SECTION 6 - ACCIDENTAL RELEASE MEASURES Spill or I.,eak: Before attempting clean up, refer to personal protection information. Do not touch or walk through spilled material. Stop leak if you can without risk. Dike ahead of large spills to prevent run -off. Mop, pump or take up with sand or other inert absorbent and reclaim into containers for reuse, recycle or proper disposal. SECTION 7 - HANDLING AND STORAGE Handling Procedures and Equipment: Avoid contact with corrosion sensitive metals, leather and wood. Do not get in eyes, on skin or clothing. Sprays and generated mists can be irritating. Use only according to dilution instructions and with adequate protective clothing. Storage Requirements: Keep container closed when not in use. Wash thoroughly after handling. D.O.T. Classification: Not Regulated SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection: Specific use conditions (spraying/confined spaces) may require local exhaust ventilation to prevent release of mist & /or vapors into work environment. If ventilation in not adequate, use NIOSH/MSHA approved respirator with alkaline mist/gas cartridge & full face piece. Eye Protection: Close fitting safety glasses/goggles/ face shield depending upon conditions of use. Protective Clothing: Impervious protective clothing appropriate to minimize contact (ie: rubber boots, apron, faceshield) especially where sprayback/misting conditions exist. Rubber protective gloves. Exposure Guidelines: No ingredients have an established exposure limit (TLV). Eye wash station and safety shower in handling area. Specific Engineering Controls (such as ventilation, enclosed process): Insure adequate ventilation to control any misting conditions. Eye wash station and safety shower in handling area. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Liquid Freezing Point: 0 °C /32 °F % Volatile by Weight: -87% Color: Opal Vapor Density lair =11: Not Determined Evaporation Rate: (vs. H20):About the same. Odor: Mild, Pleasant Odor Vapor Pressure: Not Determinded Specific Gravity: (H2O =1): 1.08 ( +1- 0.005) Boiling Point: 100 °C /212 °F Solubility in Water: Complete pH (concentrate): 13.0 (=/ -0.5) SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable Hazardous Polymerization: None Incompatibilities: Strong acids/oxidizers. Do not mix with chlorinated detergents (bleach). Reactive Conditions to avoid: Do not mix with chlorinated detergents (bleach) or any other chemicals. Decomposition Products: Burning may produce oxides of carbon and other substances. SECTION 11 - TOXICOLOGICAL INFORMATION hazardous Ingredients CAS # EINECS # LD 50 of Ingredient LC :50 of Ingredient (Specify Species) (Specify Species) Sodium Tripolyphosphate 7758 -29 -4 231 -838 -7 3120 mg/kg (oral; Rat) Not Determined Nonionic Surfactant Proprietary No Data. >5.0 g / kg (Oral ; Rat) Not Determined Sodium Metasilicate 6834 -92 -0 No Data. 1280 mg/kg (Oral; Rat) Not Determined SECTION 12 - ECOLOGICAL INFORMATION Hazardous Ingredients Aquatic Toxicity Data Sodium Tripolyphosphate EC50 (48 hr) = >1,000 mg/I (Daphnia Magna) Nonionic Surfactant Not Determined Sodium Metasilicate LC50 (96 hr) = 247 mg/1 (Daphnia Magna) SECTION 13 - DISPOSAL CONSIDERATIONS I Waste Disposal: Dispose of in an approved waste facility according to Federal, State and local regulations. SECTION 14 - TRANSPORTATION INFORMATION Special Shipping Information: No Data. Purview Proper Shipping Name UN Number Packing Group Hazard Class DOT Not Regulated (Land) MO O No Data. (Water) ICAO No Data. (Air) SECTION 15 - REGULATIORY INFORMATION WIIAl1S Classification: (Workplace Class E - Corrosive Material Hazardous Material Information System) SARA Title III: (Superfund Amendments & Contains no Section 313 listed substances subject to reporting requirement. Reauthorization Act) OSHA: (Occupational Safety & l lealth OSHA Hazardous - Acute hazard Administration) TSCA: (Toxic Substance Control Act) All ingredients are TSCA registered. VOC: (volatile Organic Compounds) Less than 1% CPR: (Canadian Controlled Products This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations) Regulations. EINECS: (European Inventory of Existing No Data. Commercial Chemical Substances) 951. / NDSL: (Canadian Domestic Substance All ingredients are listed on the Canadian DSL. List )(Non - Domestic Substance List) CERCL.A: (Comprehensive Response N/A Compensation & Liability Act) LDL: (Canadian Ingredient Disclosure List) Sodium metasilicate is listed. NFPA (HMIS) Rating: (Hazardous Materials Health= I Flammability = 0 Reactivity = 0 Identification System) SECTION 16 - OTHER INFORMATION No Data. The information contained herein is based on the data available to us and is believed to be correct. However, Nu- Calgon Wholesaler Inc. makes no warranty, expressed, or implied, regarding the accuracy of this data or the results to be obtained from the use thereof. Nu- Calgon Wholesaler Inc. assumes no liability for injury from the use of the product described herin. 1 RECEIVED P*Nu. -Con MATERIAL SAFETY DATA SHEET FEB 1 5 2011 1. Product and Company Identification CITY OFTIGARD 3U1LDINu Div MON Product Name C -3s Refrigeration Oil (4303) CAS # Mixture Product use Oil Manufacturer Nu- Calgon 2008 Altom Court St. Louis, MO 63146 US Phone: 314-469-7000 / 800-554-5499 Emergency Phone: 1- 800 - 424 -9300 (CHEMTREC) LEGEND Health 00 HMIS /NFPA 1 Severe 4 Flammability Q S 0 erious 3 Moderate 2 0 Slight 1 Personal Protection Minimal 0 2. Hazards Identification Emergency overview Contact may cause eye and skin irritation. Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation, Ingestion. Eyes May cause irritation. Skin May cause irritation. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Ingestion May cause stomach distress, nausea or vomiting. Target organs Skin. Eyes. Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and symptoms Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. 3. Composition / Information on Ingredients Composition comments None by WHMIS /OSHA criteria. 4. First Aid Measures First aid procedures Eye contact Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. Inhalation If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Ingestion Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. Notes to physician Symptoms may be delayed. General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. #18496 Page 1 of 5 Issue date 12- Aug -2008 4303 5. Fire Fighting Measures Flammable properties Not flammable by WHMIS /OSHA criteria. Extinguishing media Suitable extinguishing media Foam. Water spray. Dry chemical. Carbon dioxide. Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from Not available the chemical Protective equipment for Firefighters should wear full protective clothing including self contained breathing firefighters apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Explosion data Sensitivity to mechanical Not available impact Sensitivity to static discharge Not available 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill /leak. Methods for containment Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non - reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re -use. 7. Handling and Storage Handling Use good industrial hygiene practices in handling this material. Storage Keep out of reach of children. Store in a closed container away from incompatible materials. 8. Exposure Controls / Personal Protection Engineering controls General ventilation normally adequate. Personal protective equipment Eye / face protection Wear safety glasses with side shields. Hand protection Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Avoid breathing mists or vapors. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. 9. Physical & Chemical Properties Appearance Clear. Color Straw colored Form Liquid Odor Mild petroleum Odor threshold Not available Physical state Liquid pH Not available Melting point -42.77 °C ( -45 °F) Freezing point Not available Boiling point > 260 °C (> 500.00 °F) #18496 Page 2 of 5 Issue date 12- Aug -2008 4303 Flash point 165.55 °C (330 °F) Evaporation rate Not available Flammability limits in air, lower, % Not available by volume Flammability limits in air, upper, % Not available by volume Vapor pressure < 0.001 mmHg @ 20 °C Vapor density > 5 Specific gravity 0.9129 Octanol /water coefficient Not available Solubility (H20) Negligible Auto - ignition temperature 343 °C (649.40 °F) VOC (Weight %) Not available Viscosity 157.2 SUS @ 100 °F Percent volatile Not available 10. Chemical Stability & Reactivity Information Chemical stability Stable under recommended storage conditions. Conditions to avoid Do not mix with other chemicals. Incompatible materials Oxidizers. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Possibility of hazardous reactions Hazardous polymerization does not occur. 11. Toxicological Information Effects of acute exposure Eye May cause irritation. Skin May cause irritation. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Ingestion May cause stomach distress, nausea or vomiting. Sensitization Non- hazardous by WHMIS /OSHA criteria. Chronic effects Non - hazardous by WHMIS /OSHA criteria. Carcinogenicity Non - hazardous by WHMIS /OSHA criteria. Mutagenicity Non - hazardous by WHMIS /OSHA criteria. Reproductive effects Non - hazardous by WHMIS /OSHA criteria. Teratogenicity Non- hazardous by WHMIS /OSHA criteria. 12. Ecological Information Ecotoxicity Components of this product are hazardous to aquatic life. Environmental effects Not available Aquatic toxicity Not available Persistence / degradability Not available Bioaccumulation / accumulation Not available Partition coefficient Not available Mobility in environmental media Not available Chemical fate information Not available 13. Disposal Considerations Waste codes Not available Disposal instructions Dispose in accordance with all applicable regulations. Waste from residues / unused Not available products #18496 Page 3 of 5 Issue date 12- Aug -2008 4303 Contaminated packaging Not available 14. Transport Information U.S. Department of Transportation (DOT) Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. US Federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. CERCLA/SARA Hazardous Substances - Not applicable. Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous No chemical CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical No Clean Air Act (CAA) Not available Clean Water Act (CWA) Not available Safe Drinking Water Act (SDWA) Not available Drug Enforcement Agency (DEA) Not available Food and Drug Administration Not available (FDA) WHMIS status Not Controlled State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Inventory name Country(s) or region Inventory name On inventory (yes /no)* Canada Domestic Substances List (DSL) Yes Canada Non - Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 12- Aug -2008 Effective date 15- Aug -2008 #18496 Page 4 of 5 Issue date 12- Aug -2008 4303 Expiry date 15- Aug -2011 Prepared by Nu- Calgon Technical Service (314) 469 -7000 #18496 Page 5 of 5 Issue date 12- Aug -2008 4303 4 0" Nu-Cakon RECEIVED MATERIAL SAFETY DATA SHEET [TB 15 1 1. Product and Company Identification CITY OFTIGARD Product Name Zero! 150 (4310) BUILDING DLV151UN CAS # Mixture Product use Oil Manufacturer Nu- Calgon 2008 Altom Court St. Louis, MO 63146 US Phone: 314 -469 -7000 / 800 -554 -5499 Emergency Phone: 1- 800 - 424 -9300 (CHEMTREC) LEGEND Health MIMI HMIS/NFPA Severe 4 Flammability 0 Serious 3 I 0 Moderate 2 � 0 � g SlI ht 1 Personal Protection Minimal 0 X 2. Hazards Identification Emergency overview Contact may cause eye and skin irritation. Potential short term health effects Routes of exposure Eye, Skin contact, Inhalation, Ingestion. Eyes May cause minor irritation. Skin Based on test data, not expected to be a primary skin irritant. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Ingestion May cause stomach distress, nausea or vomiting. Target organs Skin. Eyes. Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. Signs and symptoms Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. 3. Composition / Information on Ingredients Composition comments This product is considered non hazardous by WHMIS /OSHA criteria. 4. First Aid Measures First aid procedures Eye contact Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. Inhalation If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Ingestion Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. Notes to physician Symptoms may be delayed. General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. #18455 Page 1 of 5 Issue date 06-Aug -2008 4310 5. Fire Fighting Measures Flammable properties Not flammable by WHMIS /OSHA criteria. Extinguishing media Suitable extinguishing media Carbon dioxide. Dry chemical. Fog. Foam. Unsuitable extinguishing media Not available Protection of firefighters Specific hazards arising from Not available the chemical Protective equipment for Firefighters should wear full protective clothing including self contained breathing firefighters apparatus. Hazardous combustion products May include and are not limited to: Oxides of carbon. Explosion data Sensitivity to mechanical Not available impact Sensitivity to static discharge Not available 6. Accidental Release Measures Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill /leak. Methods for containment Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non - reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re -use. 7. Handling and Storage Handling Use good industrial hygiene practices in handling this material. Storage Keep out of reach of children. Store in a closed container away from incompatible materials. 8. Exposure Controls / Personal Protection Engineering controls General ventilation normally adequate. Personal protective equipment Eye / face protection Safety glasses if eye contact is possible. Hand protection Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Avoid breathing mists or vapors. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. 9. Physical & Chemical Properties Appearance Clear. Color Yellow Form Liquid Odor Odorless Odor threshold Not available Physical state Liquid pH Not available Melting point Not available Freezing point Not available Boiling point > 300 °C (> 572.00 °F) #18455 Page 2 of 5 Issue date 06- Aug -2008 4310 Flash point > 150 °C (> 302.00 °F) Cleveland Open Cup Evaporation rate Not available Flammability limits in air, lower, To Not available by volume Flammability limits in air, upper, To Not available by volume Vapor pressure Not available Vapor density Not available Specific gravity 0.86 - 0.88 Octanol /water coefficient Not available Solubility (H20) Negligible Auto - ignition temperature > 340 °C (> 644.00 °F) Viscosity 26 - 31 cSt @ 40 °C Percent volatile Not available 10. Chemical Stability & Reactivity Information Chemical stability Stable under recommended storage conditions. Conditions to avoid Do not mix with other chemicals. Incompatible materials Oxidizers. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Possibility of hazardous reactions Hazardous polymerization does not occur. 11. Toxicological Information Effects of acute exposure Eye May cause minor irritation. Skin Based on test data, not expected to be a primary skin irritant. Inhalation Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Ingestion May cause stomach distress, nausea or vomiting. Sensitization Non - hazardous by WHMIS /OSHA criteria. Chronic effects Non - hazardous by WHMIS /OSHA criteria. Carcinogenicity Non - hazardous by WHMIS /OSHA criteria. Mutagenicity Non - hazardous by WHMIS /OSHA criteria. Reproductive effects Non - hazardous by WHMIS /OSHA criteria. Teratogenicity Non - hazardous by WHMIS /OSHA criteria. 12. Ecological Information Ecotoxicity Not available Environmental effects Not available Aquatic toxicity Not available Persistence I degradability Not available Bioaccumulation / accumulation Not available Partition coefficient Not available Mobility in environmental media Not available Chemical fate information Not available 13. Disposal Considerations Waste codes Not available Disposal instructions Dispose in accordance with all applicable regulations. Waste from residues / unused Not available products Contaminated packaging Not available #18455 Page 3 of 5 Issue date 06-Aug -2008 4310 14. Transport Information U.S. Department of Transportation (DOT) Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. US Federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. CERCLA/SARA Hazardous Substances - Not applicable. Occupational Safety and Health Administration (OSHA) 29 CFR 1910.1200 hazardous No chemical CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous chemical No Clean Air Act (CAA) Not available Clean Water Act (CWA) Not available Safe Drinking Water Act (SDWA) Not available Drug Enforcement Agency (DEA) Not available Food and Drug Administration Not available (FDA) WHMIS status Not Controlled State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. Inventory name Country(s) or region Inventory name On inventory (yes /no)* Canada Domestic Substances List (DSL) Yes Canada Non - Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. Issue date 06- Aug -2008 Effective date 01- Aug -2008 Expiry date 01- Aug -2011 #18455 Page 4 of 5 Issue date 06-Aug -2008 4310 Prepared by Nu- Calgon Technical Service (314) 469 -7000 #18455 Page 5 of 5 Issue date 06-Aug -2008 4310 Material Safety Data Shee Acetylene Section 1. Chemical product and company identification Product name : Acetylene Supplier : AIRGAS INC., on behalf of its subsidiaries RECEIVED 259 North Radnor - Chester Road Suite 100 Radnor, PA 19087 -5283 FEB 15 2011 1- 610 - 687 -5253 Product use : Synthetic /Analytical chemistry. CITY OFTIGARD Synonym : acetylen; acetylene ; ethine; ethyne; narcylen BUILDING DIVISION MSDS # : 001001 Date of : 4/22/2010. Preparation /Revision In case of emergency : 1- 866 - 734 -3438 Section 2. Hazards identification Physical state : Gas. Emergency overview : WARNING! FLAMMABLE GAS. MAY CAUSE FLASH FIRE. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CONTENTS UNDER PRESSURE. Keep away from heat, sparks and flame. Do not puncture or incinerate container. May cause target organ damage, based on animal data. Use only with adequate ventilation. Keep container closed. Contact with rapidly expanding gases can cause frostbite. Target organs : May cause damage to the following organs: upper respiratory tract, central nervous system (CNS). Routes of entry : Inhalation Potential acute health effects Eyes : Contact with rapidly expanding gas may cause burns or frostbite. Skin : Contact with rapidly expanding gas may cause burns or frostbite. Inhalation : Acts as a simple asphyxiant. Ingestion : Ingestion is not a normal route of exposure for gases Potential chronic health : CARCINOGENIC EFFECTS: Not available. effects MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditions : Pre - existing disorders involving any target organs mentioned in this MSDS as being at aggravated by over- risk may be aggravated by over - exposure to this product. exposure See toxicological information (section 11) Section 3. Composition, Information on Ingredients Name CAS number % Volume Exposure limits Acetylene 74 -86 -2 100 NIOSH REL (United States, 6/2009). CEIL: 2662 mg /m' CEIL: 2500 ppm 1 id : Page: 1/6 Acetylene Section 4. First aid measures No action shall be taken involving any personal risk or without suitable training.lf it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self- contained breathing apparatus.lt may be dangerous to the person providing aid to give mouth -to -mouth resuscitation. Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Frostbite : Try to warm up the frozen tissues and seek medical attention. Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Ingestion : As this product is a gas, refer to the inhalation section. Section 5. Fire - fighting measures Flammability of the product : Flammable. Auto - ignition temperature : 304.85 °C (580.7 °F) Flash point : Closed cup: - 18.15 °C (- 0.7 °F). Flammable limits : Lower: 2.5% Upper: 82% Products of combustion : Decomposition products may include the following materials: carbon dioxide carbon monoxide Fire hazards in the presence : Extremely flammable in the presence of the following materials or conditions: open of various substances flames, sparks and static discharge, heat and oxidizing materials. Fire - fighting media and : In case of fire, use water spray (fog), foam or dry chemical. instructions In case of fire, allow gas to burn if flow cannot be shut off immediately. Apply water from a safe distance to cool container and protect surrounding area. If involved in fire, shut off flow immediately if it can be done without risk. Contains gas under pressure. Flammable gas. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective : Fire - fighters should wear appropriate protective equipment and self- contained breathing equipment for fire - fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (section 8). Shut off gas supply if this can be done safely. Isolate area until gas has dispersed. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up : Immediately contact emergency personnel. Stop leak if without risk. Use spark -proof tools and explosion -proof equipment. Note: see section 1 for emergency contact information and section 13 for waste disposal. <u; Page: 2/6 Acetylene Section 7. Handling and storage Handling : Use only with adequate ventilation. Use explosion -proof electrical (ventilating, lighting and material handling) equipment. High pressure gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Keep container closed. Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Storage : Keep container in a cool, well - ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Segregate from oxidizing materials. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Section 8. Exposure controls /personal protection Engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion -proof ventilation equipment. Personal protection Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Skin : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory : Use a properly fitted, air - purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4 -93 Hands : Chemical- resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Personal protection in case : Self- contained breathing apparatus (SCBA) should be used to avoid inhalation of the of a large spill product. Product name acetylene NIOSH REL (United States, 6/2009). CEIL: 2662 mg /m CEIL: 2500 ppm Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Molecular weight : 26.04 g /mole Molecular formula : C2 -H2 Melting /freezing point : Sublimation temperature: - 81.8 °C (- 115.2 °F) Critical temperature : 35.3 °C (95.5 °F) Vapor pressure : 635 (psig) Vapor density : 0.9 (Air = 1) Specific Volume (ft 3 /Ib) : 14.7058 Gas Density (lb /ft 3 ) : 0.613 3a (;i Page: 3/6 Acetylene Section 10. Stability and reactivity Stability and reactivity : The product may undergo hazardous decomposition, condensation or polymerization, react violently with water to emit toxic gases or become self- reactive under conditions of shock or increase in temperature or pressure. Incompatibility with various : Extremely reactive or incompatible with oxidizing agents substances Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Toxicity data Chronic effects on humans : May cause damage to the following organs: upper respiratory tract, central nervous system (CNS). Other toxic effects on : No specific information is available in our database regarding the other toxic effects of humans this material to humans. Specific effects Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known significant effects or critical hazards. Reproduction toxicity : No known significant effects or critical hazards. Section 12. Ecological information Aquatic ecotoxicitt Not available. Products of degradation : Products of degradation: carbon oxides (CO, 002) and water. Environmental fate : Not available. Environmental hazards : No known significant effects or critical hazards. Toxicity to the environment : Not available. Section 13. Disposal considerations Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name information DOT Classification UN1001 ACETYLENE, 2.1 Not applicable (gas). Limitecil DISSOLVED quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: Forbidden. Cargo aircraft Quantity limitation: 15 kg Page: 4/6 Acetylene TDG Classification UN1001 ACETYLENE, 2.1 Not applicable (gas). Explosive DISSOLVED Limit and Limited Quantity Index 0 Passenger Carrying Ship Index 75 Passenger Carrying Road or Rail Index Forbidden Special provisions 38, 42 Mexico UN1001 ACETYLENE, 2.1 Not applicable (gas). - Classification DISSOLVED "Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product." Section 15. Regulatory information United States U.S. Federal regulations : United States inventory (TSCA 8b): This material is listed or exempted. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: acetylene SARA 311/312 MSDS distribution - chemical inventory - hazard identification: acetylene: Fire hazard, reactive, Sudden release of pressure, Immediate (acute) health hazard Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 accidental release prevention: acetylene Clean Air Act (CAA) 112 regulated flammable substances: acetylene Clean Air Act (CAA) 112 regulated toxic substances: No products were found. State regulations : Connecticut Carcinogen Reporting: This material is not listed. Connecticut Hazardous Material Survey: This material is not listed. Florida substances: This material is not listed. Illinois Chemical Safety Act: This material is not listed. Illinois Toxic Substances Disclosure to Employee Act: This material is not listed. Louisiana Reporting: This material is not listed. Louisiana Spill: This material is not listed. Massachusetts Spill: This material is not listed. Massachusetts Substances: This material is listed. Michigan Critical Material: This material is not listed. Minnesota Hazardous Substances: This material is not listed. New Jersey Hazardous Substances: This material is listed. New Jersey Spill: This material is not listed. New Jersey Toxic Catastrophe Prevention Act: This material is not listed. New York Acutely Hazardous Substances: This material is not listed. New York Toxic Chemical Release Reporting: This material is not listed. Pennsylvania RTK Hazardous Substances: This material is listed. Bold 1.1 Page: 5/6 Acetylene Rhode Island Hazardous Substances: This material is not listed. Canada WHMIS (Canada) : Class A: Compressed gas. Class B -1: Flammable gas. Class F: Dangerously reactive material. CEPA Toxic substances: This material is not listed. Canadian ARET: This material is not listed. Canadian NPRI: This material is listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances: This material is not listed. Quebec Designated Substances: This material is not listed. Section 16. Other information United States Label requirements : FLAMMABLE GAS. MAY CAUSE FLASH FIRE. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CONTENTS UNDER PRESSURE. Canada Label requirements : Class A: Compressed gas. Class B -1: Flammable gas. Class F: Dangerously reactive material. Hazardous Material ead 1 Information System (U.S.A.) Flammability 4 Phyaleal hazards 2 National Fire Protection Flammability Association (U.S.A.) Health =`' ♦ 0 Instability Special Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above -named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. : ; Page: 6/6 1 Material Safety Data Sheet A irgas. Oxygen Section 1. Chemical product and company identification Product name : Oxygen RECEIVED Supplier : AIRGAS INC., on behalf of its subsidiaries RECEIVED LL 259 North Radnor - Chester Road Suite 100 FEB 15 2011 Radnor, PA 19087 -5283 1- 610- 687 -5253 CITY OF TIGARD Product use : Synthetic /Analytical chemistry. BUILDING DIVISION Synonym : Molecular oxygen; Oxygen molecule; Pure oxygen; 02; Liquid- oxygen -; UN 1072; UN 1073; Dioxygen MSDS # : 001043 Date of : 4/22/2010. Preparation /Revision In case of emergency : 1- 866 - 734 -3438 Section 2. Hazards identification Physical state : Gas. Emergency overview : DANGER! GAS: OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. CONTENTS UNDER PRESURE. Do not puncture or incinerate container. May cause severe frostbite. • LIQUID: OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. Extremely cold liquid and gas under pressure. May cause severe frostbite. Do not puncture or incinerate container. Store in tightly - closed container. Avoid contact with combustible materials. Contact with rapidly expanding gases or liquids can cause frostbite. Routes of entry : Inhalation Potential acute health effects Eyes : May cause eye irritation. Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenic liquid can cause frostbite and cryogenic burns. Skin : May cause skin irritation. Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenic liquid can cause frostbite and cryogenic burns. Inhalation : Acts as a simple asphyxiant. Ingestion : Ingestion is not a normal route of exposure for gases. Contact with cryogenic liquid can cause frostbite and cryogenic burns. Potential chronic health : CARCINOGENIC EFFECTS: Not available. effects MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditions : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. aggravated by over- exposure See toxicological information (section 11) ��,.�, Page: 1/7 Oxygen Section 3. Composition, Information on Ingredients Name CAS number % Volume Exposure limits Oxygen 7782 -44 -7 100 Section 4. First aid measures No action shall be taken involving any personal risk or without suitable training.lf it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self- contained breathing apparatus.lt may be dangerous to the person providing aid to give mouth -to -mouth resuscitation. Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Frostbite : Try to warm up the frozen tissues and seek medical attention. Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention. Ingestion : As this product is a gas, refer to the inhalation section. Section 5. Fire - fighting measures Flammability of the product : Non - flammable. Products of combustion : No specific data. Fire hazards in the presence : Extremely flammable in the presence of the following materials or conditions: reducing of various substances materials, combustible materials and organic materials. Fire - fighting media and : Use an extinguishing agent suitable for the surrounding fire. instructions Apply water from a safe distance to cool container and protect surrounding area. If involved in fire, shut off flow immediately if it can be done without risk. Contains gas under pressure. Contact with combustible material may cause fire. This material increases the risk of fire and may aid combustion. In a fire or if heated, a pressure increase will occur and the container may burst or explode. Special protective : Fire - fighters should wear appropriate protective equipment and self- contained breathing equipment for fire - fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (section 8). Eliminate all ignition sources if safe to do so. Do not touch or walk through spilled material. Shut off gas supply if this can be done safely. Isolate area until gas has dispersed. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up : Immediately contact emergency personnel. Stop leak if without risk. Use spark -proof tools and explosion -proof equipment. Note: see section 1 for emergency contact information and section 13 for waste disposal. Section 7. Handling and storage Handling : High pressure gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Store in tightly - closed container. Avoid contact with combustible materials. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Never allow any unprotected part of the body to touch uninsulated pipes or vessels that contain cryogenic liquids. Prevent entrapment of liquid in closed systems or piping without pressure relief devices. Some materials may become brittle at low temperatures and will easily fracture. Page: 2/7 Oxygen Storage : Keep container tightly closed. Keep container in a cool, well - ventilated area. Separate from acids, alkalies, reducing agents and combustibles. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). For additional information concerning storage and handling refer to Compressed Gas Association pamphlets P -1 Safe Handling of Compressed Gases in Containers and P- 12 Safe Handling of Cryogenic Liquids available from the Compressed Gas Association, Inc. Section 8. Exposure controls /personal protection Engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Personal protection Eyes : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. When working with cryogenic liquids, wear a full face shield. Skin : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory : Use a properly fitted, air - purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4 -93 Hands : Chemical- resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Insulated gloves suitable for low temperatures Personal protection in case : Self- contained breathing apparatus (SCBA) should be used to avoid inhalation of the of a large spill product. Product name oxygen Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Molecular weight : 32 g /mole Molecular formula : 02 Boiling /condensation point . - 183.1 °C (- 297.6 °F) Melting /freezing point : - 218.6 °C (- 361.5 °F) Critical temperature : - 118.6 °C (- 181.5 °F) Vapor density : 1.105 (Air = 1) Liquid Density @BP: 71.23 lb/ft3 (1141 kg /m3) Specific Volume (ft 3 /Ib) : 12.0482 Gas Density (Ib /ft 3 ) : 0.083 Section 10. Stability and reactivity Stability and reactivity : The product is stable. Incompatibility with various : Extremely reactive or incompatible with the following materials: oxidizing materials, substances reducing materials and combustible materials. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Page: 3/7 Oxygen Section 11. Toxicological information Toxicity data Other toxic effects on : No specific information is available in our database regarding the other toxic effects of humans this material to humans. Specific effects Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known significant effects or critical hazards. Reproduction toxicity : No known significant effects or critical hazards. Section 12. Ecological information Aquatic ecotoxicity Not available. Environmental fate : Not available. Environmental hazards : No known significant effects or critical hazards. Toxicity to the environment : Not available. Section 13. Disposal considerations Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name information DOT Classification UN1072 OXYGEN, 2.2 Not applicable (gas). Limited COMPRESSED auantity Yes. UN1073 Oxygen, refrigerated Packaainq liquid ® instruction Passenger aircraft Quantity limitation: 75 kg Cargo aircraft Quantity limitation: 150 kg Special provisions A52 TDG Classification UN1072 OXYGEN, 2.2 Not applicable (gas). Explosive COMPRESSED Limit and Limited Quantity UN1073 Oxygen, refrigerated Index liquid ® 0.125 ERAP Index 3000 Passenger Carrying Shia 33,1 r Page: 4/7 Oxygen Index 50 Passenger Carrying Road or Rail Index 75 Special provisions 42 Mexico UN1072 OXYGEN, 2.2 Not applicable (gas). - Classification COMPRESSED UN1073 Oxygen, refrigerated liquid "Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product." Section 15. Regulatory information United States U.S. Federal regulations : TSCA 8(a) IUR: oxygen United States inventory (TSCA 8b): This material is listed or exempted. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: oxygen SARA 311/312 MSDS distribution - chemical inventory - hazard identification: oxygen: Fire hazard, Sudden release of pressure, Delayed (chronic) health hazard Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 accidental release prevention: No products were found. Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. State regulations : Connecticut Carcinogen Reporting: This material is not listed. Connecticut Hazardous Material Survey: This material is not listed. Florida substances: This material is not listed. Illinois Chemical Safety Act: This material is not listed. Illinois Toxic Substances Disclosure to Employee Act: This material is not listed. Louisiana Reporting: This material is not listed. Louisiana Spill: This material is not listed. Massachusetts Spill: This material is not listed. Massachusetts Substances: This material is listed. Michigan Critical Material: This material is not listed. Minnesota Hazardous Substances: This material is not listed. New Jersey Hazardous Substances: This material is listed. New Jersey Spill: This material is not listed. New Jersey Toxic Catastrophe Prevention Act: This material is not listed. New York Acutely Hazardous Substances: This material is not listed. New York Toxic Chemical Release Reporting: This material is not listed. Pennsylvania RTK Hazardous Substances: This material is listed. Rhode Island Hazardous Substances: This material is not listed. Canada WHMIS (Canada) : Class A: Compressed gas. Class C: Oxidizing material. ,. Page: 5/7 Oxygen CEPA Toxic substances: This material is not listed. Canadian ARET: This material is not listed. Canadian NPRI: This material is not listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances: This material is not listed. Quebec Designated Substances: This material is not listed. Section 16. Other information United States Label requirements : GAS: OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. CONTENTS UNDER PRESURE. Do not puncture or incinerate container. May cause severe frostbite. LIQUID: OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. Extremely cold liquid and gas under pressure. May cause severe frostbite. Canada Label requirements : Class A: Compressed gas. Class C: Oxidizing material. Hazardous Material Health 0 Information System (U.S.A.) Flammability 0 s 0 liquid: Head Fire hazard 0 Reactivity 0 Personal protection National Fire Protection • Flammability Association (U.S.A.) Health 4 Instability Special liquid: Flammability Health Instability Special Notice to reader �_v 1 Page: 6/7 Oxygen To the best of our knowledge, the information contained herein is accurate. However, neither the above -named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. ? Page: 7/7 I Honeywell Mater Safety Data Sheet Genetron AZ -20 (R -410A) 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Genetron AZ -20 (R -410A) R ECEIVED OTHER/GENERIC NAMES: R -410A PRODUCT USE: Refrigerant FEB 15 n MANUFACTURER: Honeywell 101 Columbia Road CITY OF TIGARD Box 1053 BUILDING DIVISION Morristown, New Jersey 07962 -1053 FOR MORE INFORMATION CALL: IN CASE OF EMERGENCY CALL: (Monday- Friday, 9:OOam- 5:OOpm) (24 Hours/Day, 7 Days /Week) 1- 800 - 522 -8001 1- 800 - 707 -4555 or Chemtrec- 1- 800 - 424 -9300 2. COMPOSITION /INFORMATION ON INGREDIENTS INGREDIENT NAME CAS NUMBER WEIGHT % Difluoromethane 75 -10 -5 50 Pentafluoroethane 354 -33 -6 50 Trace impurities and additional material names not listed above may also appear in Section 15 toward the end of the MSDS. These materials may be listed for local "Right -To- Know" compliance and for other reasons. 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Colorless, volatile liquid with ethereal and faint sweetish odor. Non - flammable material. Overexposure may cause dizziness and loss of concentration. At higher levels, CNS depression and cardiac arrhythmia may result from exposure. Vapors displace air and can cause asphyxiation in confined spaces. At higher temperatures, ( >250 C), decomposition products may include Hydrofluoric Acid (HF) and carbonyl halides POTENTIAL HEALTH HAZARDS SKIN: Irritation would result from a defatting action on tissue. Liquid contact could cause frostbite. EYES: Liquid contact can cause severe irritation and frostbite. Mist may irritate. INHALATION: Genetron AZ -20 (R -410A) is low in acute toxicity in animals. When oxygen levels in air are reduced to 12 -14% by displacement, symptoms of asphyxiation, loss of coordination, increased pulse rate and deeper respiration will occur. At high levels, cardiac arrhythmia may occur. MSDS Number: GTRN -0004 Page 1 of 7 Current Issue Date: February, 2003 Honeywell MATERIAL SAFETY DATA SHEET Genetron AZ -20 (R -410A) INGESTION: Ingestion is unlikely because of the low boiling point of the material. Should it occur, discomfort in the gastrointestinal tract from rapid evaporation of the material and consequent evolution of gas would result. Some effects of inhalation and skin exposure would be expected. DELAYED EFFECTS: None known Ingredients found on one of the OSHA designated carcinogen lists are listed below. INGREDIENT NAME NTP STATUS IARC STATUS OSHA LIST No ingredients listed in this section 4. FIRST AID MEASURES SKIN: Promptly flush skin with water until all chemical is removed. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. Get medical attention if symptoms persist. EYES: Immediately flush eyes with large amounts of water for at least 15 minutes (in case of frostbite water should be lukewarm, not hot) lifting eyelids occasionally to facilitate irrigation. Get medical attention if symptoms persist. INHALATION: Immediately remove to fresh air. If breathing has stopped, give artificial respiration. Use oxygen as required, provided a qualified operator is available. Get medical attention. Do not give epinephrine (adrenaline). INGESTION: Ingestion is unlikely because of the physical properties and is not expected to be hazardous. Do not induce vomiting unless instructed to do so by a physician. ADVICE TO PHYSICIAN: Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of symptoms and the clinical conditions. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES FLASH POINT: Gas, not applicable per DOT regulations FLASH POINT METHOD: Not applicable AUTOIGNITION TEMPERATURE: >750° C UPPER FLAME LIMIT (volume % in air): None by ASTM D - - LOWER FLAME LIMIT (volume % in air): None by ASTM E - 681 FLAME PROPAGATION RATE (solids): Not applicable OSHA FLAMMABILITY CLASS: Not applicable EXTINGUISHING MEDIA: Use any standard agent — choose the one most appropriate for type of surrounding fire (material itself is not flammable) MSDS Number: GTRN -0004 Page 2 of 7 Current Issue Date: February, 2003 Honeywell MATERIAL SAFETY DATA SHEET Genetron AZ -20 (R -410A) UNUSUAL FIRE AND EXPLOSION HAZARDS: Genetron AZ -20 (R -410A) is not flammable at ambient temperatures and atmospheric pressure. However, this material will become combustible when mixed with air under pressure and exposed to strong ignition sources. Contact with certain reactive metals may result in formation of explosive or exothermic reactions under specific conditions (e.g. very high temperatures and/or appropriate pressures). SPECIAL FIRE FIGHTING PRECAUTIONS/INSTRUCTIONS: Firefighters should wear self - contained, NIOSH- approved breathing apparatus for protection against possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire- exposed containers cool. 6. ACCIDENTAL RELEASE MEASURES IN CASE OF SPILL OR OTHER RELEASE: (Always wear recommended personal protective equipment.) Evacuate unprotected personnel. Protected personnel should remove ignition sources and shut off leak, if without risk, and provide ventilation. Unprotected personnel should not return until air has been tested and determined safe, including low - lying areas. Spills and releases may have to be reported to Federal and/or local authorities. See Section 15 regarding reporting requirements. 7. HANDLING AND STORAGE NORMAL HANDLING: (Always wear recommended personal protective equipment.) Avoid breathing vapors and liquid contact with eyes, skin or clothing. Do not puncture or drop cylinders, expose them to open flame or excessive heat. Use authorized cylinders only. Follow standard safety precautions for handling and use of compressed gas cylinders. Genetron AZ -20 (R -410A) should not be mixed with air above atmospheric pressure for leak testing or any other purpose. STORAGE RECOMMENDATIONS: Store in a cool, well - ventilated area of low fire risk and out of direct sunlight. Protect cylinder and its fittings from physical damage. Storage in subsurface locations should be avoided. Close valve tightly after use and when empty. 8. EXPOSURE CONTROLS /PERSONAL PROTECTION ENGINEERING CONTROLS: Provide local ventilation at filling zones and areas where leakage is probable. Mechanical (general) ventilation may be adequate for other operating and storage areas. PERSONAL PROTECTIVE EQUIPMENT SKIN PROTECTION: Skin contact with refrigerant may cause frostbite. General work clothing and gloves (leather) should provide adequate protection. If prolonged contact with the liquid or gas is anticipated, insulated gloves constructed of PVA, neoprene or butyl rubber should be used. Any contaminated clothing should be promptly removed and washed before reuse. MSDS Number: GTRN -0004 Page 3 of 7 Current Issue Date: February, 2003 Honeywell MATERIAL SAFETY DATA SHEET Genetron AZ -20 (R -410A) EYE PROTECTION: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear chemical safety goggles. RESPIRATORY PROTECTION: None generally required for adequately ventilated work situations. For accidental release or non - ventilated situations, or release into confined space, where the concentration may be above the PEL of 1,000 ppm, use a self - contained, NIOSH - approved breathing apparatus or supplied air respirator. For escape: use the former or a NIOSH- approved gas mask with organic vapor canister. ADDITIONAL RECOMMENDATIONS: Where contact with liquid is likely, such as in a spill or leak, impervious boots and clothing should be worn. High dose - level warning signs are recommended for areas of principle exposure. Provide eyewash stations and quick- drench shower facilities at convenient locations. For tank cleaning operations, see OSHA regulations, 29 CFR 1910.132 and 29 CFR 1910.133. EXPOSURE GUIDELINES INGREDIENT NAME ACGIH TLV OSHA PEL OTHER LIMIT Difluoromethane None None *1000 ppm TWA Pentafluoroethane None None (8hr) *9000 ppm TWA (8hr) * = Limit established by Honeywell. ** = Workplace Environmental Exposure Level (AIHA). * ** = Biological Exposure Index (ACGIH). OTHER EXPOSURE LIMITS FOR POTENTIAL DECOMPOSITION PRODUCTS: Hydrogen Fluoride: ACGIH TLV: 3 ppm ceiling 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, colorless liquid and vapor PHYSICAL STATE: Gas at ambient temperatures MOLECULAR WEIGHT: 72.6 CHEMICAL FORMULA: CH CHF ODOR: Faint ethereal odor SPECIFIC GRAVITY (water = 1.0): 1.08 @ 21.1° C (70° F) SOLUBILITY IN WATER (weight %): Unknown pH: Neutral BOILING POINT: -48.5° C ( -55.4° F) FREEZING POINT: Not Determined VAPOR PRESSURE: 215.3 psia @ 70° F 490.2 psia @ 130° F VAPOR DENSITY (air = 1.0): 3.0 MSDS Number: GTRN -0004 Page 4 of 7 Current Issue Date: February, 2003 Honeywell MATERIAL SAFETY DATA SHEET Genetron AZ -20 (R -410A) EVAPORATION RATE: >1 COMPARED TO: CCI = 1 % VOLATILES: 100 FLASH POINT: Not applicable (Flash point method and additional flammability data are found in Section 5.) 10. STABILITY AND REACTIVITY NORMALLY STABLE? (CONDITIONS TO AVOID): The product is stable. Do not mix with oxygen or air above atmospheric pressure. Any source of high temperature, such as lighted cigarettes, flames, hot spots or welding may yield toxic and/or corrosive decomposition products. INCOMPATIBILITIES: (Under specific conditions: e.g. very high temperatures and/or appropriate pressures) — Freshly abraded aluminum surfaces (may cause strong exothermic reaction). Chemically active metals: potassium, calcium, powdered aluminum, magnesium and zinc. HAZARDOUS DECOMPOSITION PRODUCTS: Halogens, halogen acids and possibly carbonyl halides. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL INFORMATION IMMEDIATE (ACUTE) EFFECTS: LC50 : 4 hr. (rat) - a 520,000 ppm ( difluoromethane) Cardiac Sensitization threshold (dog) a 100,000 ppm (pentafluoroethane) DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS: Teratology - negative Subchronic inhalation (rat) NOEL - 50,000 ppm OTHER DATA: Not active in four genetic studies 12. ECOLOGICAL INFORMATION Degradability (BOD): Genetron AZ -20 (R -410A) is a gas at room temperature; therefore, it is unlikely to remain in water. Octanol Water Partition Coefficient: Log P = 1.48 (pentafluoroethane), 0.21 (difluoromethane) 13. DISPOSAL CONSIDERATIONS RCRA Is the unused product a RCRA hazardous waste if discarded? Not a hazardous waste If yes, the RCRA ID number is: Not applicable MSDS Number: GTRN -0004 Page 5 of 7 Current Issue Date: February, 2003 Honeywell MATERIAL SAFETY DATA SHEET Genetron AZ -20 (R -410A) OTHER DISPOSAL CONSIDERATIONS: Disposal must comply with federal, state, and local disposal or discharge laws. Genetron AZ -20 (R -410A) is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling. The information offered here is for the product as shipped. Use and /or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal method. 14. TRANSPORT INFORMATION US DOT HAZARD CLASS: US DOT PROPER SHIPPING NAME: Liquified gas, n.o.s. (Pentafluoroethane, Difluoromethane) US DOT HAZARD CLASS: 2.2 US DOT PACKING GROUP: Not applicable US DOT ID NUMBER: UN3163 For additional information on shipping regulations affecting this material, contact the information number found in Section 1. 15. REGULATORY INFORMATION TOXIC SUBSTANCES CONTROL ACT (TSCA) TSCA INVENTORY STATUS: Components listed on the TSCA inventory OTHER TSCA ISSUES: None SARA TITLE III /CERCLA "Reportable Quantities" (RQs) and /or "Threshold Planning Quantities" (TPQs) exist for the following ingredients. INGREDIENT NAME SARA/CERCLA RO (lb.) SARA EHS TPQ (lb.) No ingredients listed in this section Spills or releases resulting in the loss of any ingredient at or above its RQ requires immediate notification to the National Response Center 1(800) 424 -88021 and to your Local Emergency Planning Committee. SECTION 311 HAZARD CLASS: IMMEDIATE PRESSURE SARA 313 TOXIC CHEMICALS: The following ingredients are SARA 313 "Toxic Chemicals ". CAS numbers and weight percents are found in Section 2. INGREDIENT NAME COMMENT No ingredients listed in this section MSDS Number: GTRN -0004 Page 6 of 7 Current Issue Date: February, 2003 Honeywell MATERIAL SAFETY DATA SHEET Genetron AZ -20 (R -410A) STATE RIGHT -TO -KNOW In addition to the ingredients found in Section 2, the following are listed for state right - to - know purposes. INGREDIENT NAME WEIGHT % COMMENT No ingredients listed in this section ADDITIONAL REGULATORY INFORMATION: Genetron AZ -20 (R -410A) is subject to U.S. Environmental Protection Agency Clean Air Act Regulations at 40 CFR Part 82. WARNING: Contains pentafluoroethane (HFC -125) and difluoromethane (HFC -32), greenhouse gases which may contribute to global warming Do Not vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any residual must be recovered. WHMIS CLASSIFICATION (CANADA): This product has been evaluated in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. FOREIGN INVENTORY STATUS: EU — EINECS # 2065578 (HFC - 125) 16. OTHER INFORMATION CURRENT ISSUE DATE: February, 2003 PREVIOUS ISSUE DATE: January, 2000 CHANGES TO MSDS FROM PREVIOUS ISSUE DATE ARE DUE TO THE FOLLOWING: Section 1: Updated contact information OTHER INFORMATION: HMIS Classification: Health — 1, Flammability — 1, Reactivity — 0 NFPA Classification: Health — 2, Flammability —1, Reactivity — 0 ANSI /ASHRAE 34 Safety Group — A 1 Regulatory Standards: 1. OSHA regulations for compressed gases: 29 CFR 1910.101 2. DOT classification per 49 CFR 172.101 Toxicity information per PAFT Testing MSDS Number: GTRN -0004 Page 7 of 7 Current Issue Date: February, 2003 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Genetron® HP80 (R -402A) RECEIVED MSDS Number : 000000009892 Product Use Description : Refrigerant FEB 15201' Company : Honeywell International, Inc. CITY OFTIGARD 101 Columbia Road BUILDING DIVISION Morristown, NJ 07962 -1057 For more information call : 800 - 522 -8001 (Monday- Friday, 9:OOam- 5:OOpm) In case of emergency call : Medical: 1- 800 -498 -5701 : Transportation: 1- 800 -424 -9300 or 703- 527 -3887 : (24 hours /day, 7 days /week) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : Liquefied gas Color : colourless Odor : weak Hazard Summary : Warning! Container under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. Gas reduces oxygen available for breathing. Causes asphyxiation in high concentrations. The victim will not realize that he /she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. May cause drowsiness and dizziness. Do not breathe vapour. Irritating to eyes and skin. Avoid contact with skin, eyes and clothing. At higher temperatures, ( >250 °C), decomposition products may include hydrochloric acid (HCI), hydrofluoric acid (HF) and carbonyl halides. The ACGIH Threshold Limit Values (2007) for Hydrogen Fluoride are TLV -TWA 0.5 ppm and Ceiling Exposure Limit 2 ppm. Potential Health Effects Skin : Avoid skin contact with leaking liquid (danger of frostbite). May cause frostbite. Irritating to skin. Eyes : Causes severe eye irritation. May cause frostbite. Ingestion : Unlikely route of exposure. Pagel /10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 Effects due to ingestion may include: Gastrointestinal discomfort Inhalation : Gas reduces oxygen available for breathing. Causes asphyxiation in high concentrations. The victim will not realize that he /she is suffocating. Inhalation may cause central nervous system effects. Vapours may cause drowsiness and dizziness. Chronic Exposure : None known. Carcinogenicity No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA. SECTION 3. COMPOSITION /INFORMATION ON INGREDIENTS Component CAS -No. Weight Pentafluoroethane 354 -33 -6 58.00 - 62.00 Chlorodifluoromethane 75 -45 -6 36.00 - 40.00 Propane 74 -98 -6 1.00 - 2.00 SECTION 4. FIRST AID MEASURES Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline- ephedrine group. Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician. Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician. Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately. Notes to physician Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of Page 2 / 10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 symptoms and the clinical conditions. Treat frost - bitten areas as needed. SECTION 5. FIRE - FIGHTING MEASURES Flash point : not applicable Lower explosion limit : None Upper explosion limit : None Suitable extinguishing : The product is not flammable. media ASHRAE 34 Use water spray, alcohol- resistant foam, dry chemical or carbon dioxide. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Specific hazards during fire : Contents under pressure. fighting This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run -off from fire fighting to enter drains or water courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen chloride (HCI). Hydrogen fluoride Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Special protective : In the event of fire and /or explosion do not breathe fumes. equipment for fire- fighters Wear self- contained breathing apparatus and protective suit. No unprotected exposed skin areas. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill /leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite). Ventilate the area. After release, disperses into the air. Page 3 / 10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been tested and determined safe. Ensure that the oxygen content is >= 19.5 %. Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evaporates readily. Methods for cleaning up : Ventilate the area. SECTION 7. HANDLING AND STORAGE Handling Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use. Advice on protection against : The product is not flammable. fire and explosion Can form a combustible mixture with air at pressures above atmospheric pressure. Storage Requirements for storage : Pressurized container: Protect from sunlight and do not expose areas and containers to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Keep containers tightly closed in a dry, cool and well - ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Protective measures : Do not breathe vapour. Page 4 / 10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to the workstation location. Engineering measures : General room ventilation is adequate for storage and handling. Perform filling operations only at stations with exhaust ventilation facilities. Eye protection : Wear as appropriate: Safety glasses with side - shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Polyvinyl alcohol or nitrile- butyl- rubber gloves Skin and body protection : Protective suit Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves /face shield /eye protection. Respiratory protection : In case of insufficient ventilation wear suitable respiratory equipment. Wear a positive - pressure supplied -air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. For rescue and maintenance work in storage tanks use self- contained breathing apparatus. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re -use. Keep working clothes separately. Exposure Guidelines Pentafluoroethane 354 -33 -6 WEEL TWA 1,000 ppm 4,900 mg /m3 HONEYWELL TWA 1,000 ppm Chlorodifluoromethane 75 -45 -6 ACGIH TWA 1,000 ppm NIOSH REL 1,000 ppm 3,500 mg /m3 NIOSH STEL 1,250 ppm 4,375 mg /m3 US CA OEL TWA PEL 1,000 ppm 3,500 mg /m3 OSHA Z1A TWA 1,000 ppm 3,500 mg /m3 Propane 74 -98 -6 NIOSH REL 1,000 ppm 1,800 mg /m3 Page 5 / 10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 OSHA Z1 PEL 1,000 ppm 1,800 mg /m3 OSHA Z1A TWA 1,000 ppm 1,800 mg /m3 US CA OEL TWA PEL 1,000 ppm 1,800 mg /m3 ACGIH TWA 1,000 ppm SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquefied gas Color : colourless Odor : weak pH : neutral Freezing point : no data available Boiling point/boiling range : -49.2 °C ( -56.6 °F) Vapor pressure : 11,928 hPa at 21.1 °C (70.0 °F) Vapor pressure : 26,883 hPa at 54.4 °C (129.9 °F) Relative vapour density : 3.5 (Air = 1.0) Density : 1.14 g /cm3 at 21.1 °C (70.0 °F) Water solubility : no data available Partition coefficient: : log Pow: 1.48 n- octanol /water Partition coefficient: : log Pow: 1.08 - 1.13 n- octanol /water Solubility in other solvents : no data available SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Decomposes under high temperature. Some risk may be expected of corrosive and toxic decomposition products. Can form a combustible mixture with air at pressures above atmospheric pressure. Page 6 / 10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 Do not mix with oxygen or air above atmospheric pressure. Materials to avoid : Finely divided aluminium Potassium Calcium Powdered metals Aluminium Magnesium Zinc Hazardous decomposition : In case of fire hazardous decomposition products may be products produced such as: Gaseous hydrogen chloride (NCI). Hydrogen fluoride Carbonyl halides Carbon monoxide Carbon dioxide (CO2) Thermal decomposition : >250 °C SECTION 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity : LC50 rat Dose: > 800000 ppm Exposure time: 4 h Test substance: Ethane, pentafluoro- (HFC -125) Acute inhalation toxicity : LC50 rat Dose: > 300000 ppm Exposure time: 4 h Test substance: Chlorodifluoromethane (HCFC -22) Repeated dose toxicity : rat NOEL: 15000 ppm Additional advice : Acute Health Hazard Chlorodifluoromethane (HCFC -22): Cardiac sensitisation threshold (dog): 50000 ppm. Ethane, pentafluoro- (HFC -125): Cardiac sensitisation threshold (dog): 75000 ppm. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Irritating to eyes and skin. Rapid evaporation of the liquid may cause frostbite. May cause cardiac arrhythmia. SECTION 12. ECOLOGICAL INFORMATION Additional ecological : This product contains greenhouse gases which may contribute information to global warming. Do NOT vent to the atmosphere. To comply Page 7/10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 with provisions of the U.S. Clean Air Act, any residual must be recovered. This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations at 40 CFR Part 82. Section 611 requires the following label text on all shipments of this product: Warning: Contains Chlorodifluoromethane (HCFC -22), a substance which harms public health and environment by destroying ozone in the upper atmosphere. Refer to sections 610 and 612 for list of acceptable and unacceptable uses for this product. SECTION 13. DISPOSAL CONSIDERATIONS Waste Information: Avoid contact of spilled material and runoff with soil and surface waterways. Consult an environmental professional to determine if local, regional or national regulations would classify spilled or contaminated materials as hazardous waste. Use only approved transporters, recyclers, treatment, storage or disposal facilities. Dispose of according to all federal, state and local applicable regulations. Other Disposal Considerations: Observe all Federal, State, and Local Environmental regulations. The information offered here is for the product as shipped. Use and /or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal method. Additional advice : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling. SECTION 14. TRANSPORT INFORMATION DOT Proper shipping name : LIQUEFIED GAS, N.O.S. UN- Number : 3163 Class : 2.2 Packing group IATA UN Number : 3163 Description of the goods : LIQUEFIED GAS, N.O.S. (Pentafluoroethane, Chlorodifluoromethane, Propane) Class : 2.2 Hazard Label : 2.2 Packing instruction (cargo : 200 aircraft) Packing instruction : 200 (passenger aircraft) IMDG Substance No. : UN 3163 Description of the goods : LIQUEFIED GAS, N.O.S. (Pentafluoroethane, Chlorodifluoromethane, Page 8 / 10 Material Safety Data Sheet Honeywell Genetron® HP80 (R -402A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 Propane) Class : 2.2 Hazard Label : 2.2 EmS Number : F -C Marine pollutant : no SECTION 15. REGULATORY INFORMATION Inventories EU. EINECS : On or in compliance with the inventory US. Toxic Substances : On TSCA Inventory Control Act Australia. AICS : On or in compliance with the inventory Canada. Canadian : All components of this product are on the Canadian DSL list. Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) Japan. ENCS : On or in compliance with the inventory Korea. KECI : On or in compliance with the inventory Philippines. PICCS : On or in compliance with the inventory China. IECSC : On or in compliance with the inventory National regulatory information SARA 313 Components : Chlorodifluoromethane 75 -45 -6 SARA 311/312 Hazards : Acute Health Hazard Sudden Release of Pressure Hazard California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects. Massachusetts RTK : Chlorodifluoromethane 75 -45 -6 : Propane 74 -98 -6 New Jersey RTK : Pentafluoroethane 354 -33 -6 Page 9 / 10 • Material Safety Data Sheet Honeywell Genetron® HP8O (R -4O2A) Version 2 Revision Date 11/16/2007 Print Date 11/16/2007 : Chlorodifluoromethane 75 -45 -6 : Propane 74 -98 -6 Pennsylvania RTK : Pentafluoroethane 354 -33 -6 : Chlorodifluoromethane 75 -45 -6 : Propane 74 -98 -6 WHMIS Classification : A Global warming potential : 2,040 Ozone depletion potential : 0.02 (ODP) SECTION 16. OTHER INFORMATION HMIS III NFPA Health Hazard : 1 2 Flammability : 1 1 Physical Hazard : 0 Instability : 0 Page 10 / 10 Material Safety Data Sheet ` R RKEMR FORANE ® 134a Thu world is our inspiration 1. PRODUCT AND COMPANY IDENTIFICATION Company Arkema Inc. RECEIVED 2000 Market Street Philadelphia, Pennsylvania 19103 FEB 15 2011 Fluorochemicals CITY OF TIGARD Customer Service Telephone Number: (800) 245 -5858 BUILDING DIVISION (Monday through Friday, 8:30 AM to 5:30 PM EST) Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: FORANE ® 134a Synonyms: HFC 134a, R 134a Molecular formula: CH2FCF3 Chemical family: Hydrofluorocarbon Molecular weight: 102.03 g /mol Product use: Refrigerant, Foam blowing agent, Aerosol propellants 2. HAZARDS IDENTIFICATION Emergency Overview Color: transparent Physical state: gas Odor: ether -like WARNING! LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. CAUSES EYE AND RESPIRATORY TRACT IRRITATION. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Signs and symptoms of acute exposure: Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 1 / 10 Material Safety Data Sheet RRKEmR FORANE ®134a The world is our inspiration Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Irritating to eyes and respiratory system. Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (extent of injury depends on severity of exposure). Skin: Slightly irritating. (based on animal studies) Inhalation: Practically nontoxic. (based on animal studies) Eyes: Slightly irritating. (based on animal studies) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Wt/Wt OSHA Hazardous Ethane, 1,1,1,2 - tetrafluoro- 811 -97 -2 > 99 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Notes to physician: Do not give drugs from adrenaline- ephedrine group. 5. FIRE - FIGHTING MEASURES Flash point not applicable Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 2 / 10 Material Safety Data Sheet RRhCeMR FORANE ® 134a The world is our insp7rakiart Auto - ignition temperature: 1,369 °F (743 °C) Lower flammable limit (LFL): None. Upper flammable limit (UFL): None. Extinguishing media (suitable): Use extinguishing measures to suit surroundings. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self- contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Further firefighting advice: Stop the flow of gas if possible. Fire fighting equipment should be thoroughly decontaminated after use. Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Keep upwind and operate from safe distance. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Do not smoke or operate internal combustion engines. Remove flames and heating elements. Stop the leak if you can do so without risk. Sources of ignition should be kept well clear. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 3 / 10 Material Safety Data Sheet RRKemla FORANE ® 134a The world is our +nsperation 7. HANDLING AND STORAGE Handling General information on handling: Avoid contact with skin, eyes and clothing. Avoid breathing gas. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Use a backflow preventative device in piping. Wash thoroughly after handling. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Store separate from: Alkaline earth metals Finely divided metals Strong oxidizing agents 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,240 mg /m3) Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below airborne exposure limits (if applicable see above). Provide ventilation if necessary to control exposure levels Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 4 / 10 Material Safety Data Sheet Al F ORANFORANE ®134a The world is our inspiration below airborne exposure limits (see above). If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Monitor carbon monoxide and oxygen levels in tanks and enclosed spaces. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components. Full facepiece equipment is recommended and, if used, replaces need for face shield and /or chemical goggles. Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self- contained breathing apparatus or positive- pressure airline with auxiliary self- contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment immediately available. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: transparent Physical state: gas Odor: ether -like pH: not applicable Density: not determined Specific Gravity (Relative 1.21 (77 °F( 25 °C)) density): Vapor pressure: 4,432.000 mmHg (70.0 °F (21.1 °C)) Relative vapor density: 3.54 Vapor density: not determined Boiling point/boiling -15.5 °F ( -26.4 °C) range: Freezing point: -150 °F ( -101 °C) Melting point/range: no data available Solubility in water: 0.9 g/I 77 °F (25 °C) Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 5 / 10 Material Safety Data Sheet RRI- Cet't"1R FORANE ® 134a The world is our inspiration Molecular weight: 102.03 g /mol Thermal decomposition > 698 °F (> 370 °C) Critical point: Critical pressure: 30,528 mmHg Critical temperature: 214 °F (101 °C) Henry's constant: 5.06E +03 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Alkaline earth metals Finely divided metals (aluminium, magnesium, zinc...) Strong oxidizing agents Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : Halogen acids (HCI and HF) Carbon monoxide Carbon dioxide (CO2) Carbonyl halides 11. TOXICOLOGICAL INFORMATION Data for FORANE ® 134a Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approximately 2,360 mg /I (— 567000 ppm). Practically nontoxic. (rat) 0.5 h LC50 approximately 3,122 mg /I (— 750000 ppm). Signs /effects reported after acute exposure. (mouse, dog, cat, monkey) signs: anesthetic effects Skin Irritation: Slightly irritating. (rabbit) (24 h) Eye Irritation: Slightly irritating. (rabbit) Sensitization: Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 6 / 10 Material Safety Data Sheet ZRKerfl�a FORANE ® 134a The world is our inspiration Causes cardiac sensitization. inhalation. (dog) Stress - induced heart effects. signs: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat / No adverse systemic effects reported. Carcinogenicity Chronic inhalation administration to male rat / affected organ(s): testes / signs: tumors were benign / Increase in tumor incidence was reported. Chronic inhalation administration to female rat / No increase in tumor incidence was reported. 1 year oral gavage administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (delays in development, at doses that produce effects in mothers) Reproductive effects Reproduction Test. inhalation (rat) / No toxicity to reproduction. 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data for FORANE ® 134a Biodegradation: Not readily biodegradable. (28 d) biodegradation 3 % Bioaccumulation: Octanol Water Partition Coefficient: log Pow = 1.06 Photodegradation: Degradation in the atmosphere Half -life direct photolysis: = 9.6 - 16.7 y (in atmosphere) Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 7 / 10 Material Safety Data Sheet AZern FORANE ® 134a The world is our inspiration Global Warming Potential: GWP = 0.3 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0 Ecotoxicoloqy Data for FORANE ® 134a Aquatic toxicity data: Practically nontoxic. Oncorhynchus mykiss (rainbow trout) 96 h LC50 = 450 mg /I Aquatic invertebrates: Practically nontoxic. Daphnia magna (Water flea) 48 h EC50 = 930 mg /I Microorganisms: Practically nontoxic. Bacteria 16 h EC10 > 730 mg /I 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3159 Proper shipping name : 1,1,1,2 - Tetrafluoroethane( REFRIGERANT GAS R 134a) Class : 2.2 Marine pollutant : no International Maritime Dangerous Goods Code (IMDG) UN Number : 3159 Proper shipping name : 1,1,1,2 - TETRAFLUOROETHANE ( REFRIGERANT GAS R 134a) Class : 2.2 Marine pollutant : no Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 8 / 10 Material Safety Data Sheet /07 r<eMR FORANE ®134a The world is our inspiration 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Does not conform Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Does not conform published by ERMA New Zealand United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard SARA Title III — Section 313 Toxic Chemicals: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 9 / 10 Material Safety Data Sheet RRKemR FORANE ® 134a The world is our inspiration IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations Massachusetts Right to Know No components are subject to the Massachusetts Right to Know Act. New Jersey Right to Know No components are subject to the New Jersey Right to Know Act. Pennsylvania Right to Know Chemical Name CAS -No. Ethane, 1,1,1,2 - tetrafluoro- 811 -97 -2 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Miscellaneous: Other information: This MSDS covers the following grades: High Purity. Latest Revision(s): Revised Section(s): revised section 15 - 12b Reference number: 000000033838 Date of Revision: 07/29/2009 Date Printed: 07/29/2009 FORANE ® is a registered trademark of Arkema Inc. Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. Product code: 04134 Version 1.3 Issued on: 07/29/2009 Page: 10 / 10 Material Safety Data Sheet R nkemn Refrigerant 401A 1. PRODUCT AND COMPANY IDENTIFICATION Company RECENED Arkema Inc. 2000 Market Street Philadelphia, Pennsylvania 19103 FEB 1 5 2011 Fluorochemicals CITY OF TIGA;D Customer Service Telephone Number: (800) 245 -5858 BUILDING DIVISION (Monday through Friday, 8:30 AM to 5:30 PM EST) Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: Refrigerant 401A Synonyms: Not available Molecular formula: CHCIF2 /CH3CHF2 /CHCIFCF3 Chemical family: Hydrofluorocarbon, Hydrochlorofluorocarbon Product use: Refrigerant 2. HAZARDS IDENTIFICATION Emergency Overview Color: Clear - colourless Physical state: gaseous Form: Liquefied gas Odor: Ether -like (slightly) WARNING! HIGH PRESSURE GAS. LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. CAUSES EYE AND RESPIRATORY TRACT IRRITATION. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 1 / 13 Material Safety Data Sheet AR Refrigerant 401A Signs and symptoms of acute exposure: Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (extent of injury depends on severity of exposure). Skin: Contact with liquid or refrigerated gas can cause cold burns and frostbite. Inhalation: Practically nontoxic. (based on animal studies) Eyes: Contact with liquid or refrigerated gas can cause cold burns and frostbite. (mist or aerosol) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Wt/Wt OSHA Hazardous Methane, chlorodifluoro- 75 -45 -6 53 % Y Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 34 % Y Ethane, 1,1- difluoro- 75 -37 -6 13 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Notes to physician: Do not give drugs from adrenaline- ephedrine group. Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 2 / 13 Material Safety Data Sheet ARKEmA Refrigerant 401A 5. FIRE - FIGHTING MEASURES Flash point not applicable Auto - ignition temperature: 1,258 °F (681 °C) Lower flammable limit (LFL): None. Upper flammable limit (UFL): None. Extinguishing media (suitable): Use extinguishing media appropriate to surrounding fire conditions. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self- contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Further firefighting advice: Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. When burned, the following hazardous products of combustion can occur: hydrofluoric acid hydrochloric acid Carbon oxides Carbonyl halides 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Eliminate all ignition sources. Evacuate area of all unnecessary personnel. Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Prevent further leakage or spillage if you can do so without risk. Keep upwind. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Avoid dispersal of leaked material. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 3 / 13 Material Safety Data Sheet I ARKemR Refrigerant 401A 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing gas. Avoid contact with eyes. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Use a backflow preventative device in piping. Wash thoroughly after handling. Close valve after each use and when empty. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Store separate from: Alkaline earth metals Finely divided metals (aluminium, magnesium, zinc...) Strong oxidizing agents Alkali metals Strong bases 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Methane, chlorodifluoro- (75 -45 -6) US. ACGIH Threshold Limit Values Time Weighted Average (TWA): 1,000 ppm Ethane, 2- chloro - 1,1,1,2- tetrafluoro- (2837 -89 -0) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 4 / 13 Material Safety Data Sheet ARKemn Refrigerant 401A Remarks: Listed Ethane, 1,1- difluoro- (75 -37 -6) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (2,700 mg /m3) Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below airborne exposure limits (if applicable see above),If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Monitor carbon monoxide and oxygen levels in tanks and enclosed spaces. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components. Full facepiece equipment is recommended and, if used, replaces need for face shield and /or chemical goggles. Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self- contained breathing apparatus or positive - pressure airline with auxiliary self- contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment immediately available. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Clear - colourless Physical state: gaseous Form: Liquefied gas Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 5 / 13 Material Safety Data Sheet ARt -CemA Refrigerant 401A Odor: Ether -like (slightly) pH: Not applicable Density: 1.194 g /cm3 (77 °F (25 °C)) Vapor pressure: 5,797.243 mmHg (77 °F (25 °C)) Vapor density: 3.3 kg /m3 (77 °F (25 °C)) Boiling point/boiling -27 °F ( -33 ° C) range: Solubility in water: 0.1 g/I 77 °F (25 °C) % Volatiles: 100 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Alkaline earth metals Finely divided metals (aluminium, magnesium, zinc...) Strong oxidizing agents Alkali metals Strong bases Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : hydrofluoric acid hydrochloric acid Carbon oxides Carbonyl halides 11. TOXICOLOGICAL INFORMATION Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45-6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approx. 780 mg /I (220000 ppm). Skin Irritation: Moderately irritating. (rabbit) (Rapid evaporation of the liquid may cause frostbite.) Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 6 / 13 Material Safety Data Sheet RRKemA Refrigerant 401A Eye Irritation: Slightly irritating. (rabbit) (30 s) (gas spray) Sensitization: Causes cardiac sensitization. (dog, rat, mouse, rabbit and monkey) irregular heart beat, rapid heart beat, in some cases, sudden death Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat, rabbit, mouse / affected organ(s): liver, lung, central nervous system / (Repeated exposure at high concentrations) Chronic oral administration to rat / No adverse effects reported. Carcinogenicity Chronic inhalation administration to mouse / No increase in tumor incidence was reported. Chronic inhalation administration to female rat / No increase in tumor incidence was reported. Chronic inhalation administration to male rat / affected organ(s): salivary gland / Increased incidence of tumors was reported. (The observed tumors do not appear to be relevant for men.) Genotoxicity Assessment in Vitro: Genetic changes were observed in laboratory tests using: bacteria No genetic changes were observed in laboratory tests using: animal cells, yeast Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals, rodent Developmental toxicity Exposure during pregnancy. inhalation (rat) / Birth defects were observed. (eye) Exposure during pregnancy. inhalation (rabbit) / No birth defects were observed. Reproductive effects Reproduction test. inhalation (rat and mouse) / No toxicity to reproduction / (males) Human experience Inhalation: Lung: Asphyxia, suffocation. Heart: Palpitation. (based on reports of occupational exposure to workers) Human experience Skin contact: Skin: irritation, redness, swelling. (repeated or prolonged exposure) Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 7 / 13 Material Safety Data Sheet ARKemA Refrigerant 401A Data for Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- (2837 -89 -0) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 between 1,280 - 1,670 mg /I (between 230000 - 300000 ppm). Signs /effects reported after acute exposure. (dog, mouse) signs: anesthetic effects Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Inhalation administration to rat and mouse / affected organ(s): central nervous system / signs: blood chemistry changes Carcinogenicity Chronic inhalation administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (at doses that produce effects in mothers) Data for Ethane, 1,1- difluoro- (75 -37 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LCO = 861 mg /I (319000 ppm). Practically nontoxic. (rat) 4 h ALC = 1,034 mg /I (383000 ppm). Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress - induced heart effects. rapid heart beat, irregular heart beat, in some cases, sudden death Repeated dose toxicity Repeated inhalation administration to rat / affected organ(s): respiratory tract / signs: irritation / (Repeated exposure at high concentrations) Carcinogenicity Chronic inhalation administration to rat / No increase in tumor incidence was reported. Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 8 / 13 Material Safety Data Sheet ARI -(emA Refrigerant 401A Genotoxicity Assessment in Vitro: No genetic changes were observed in a laboratory test using: bacteria Genetic changes were observed in a laboratory test using: human cells Genotoxicity Assessment in Vivo: No genetic changes were observed in a laboratory test using: rodent, mouse Developmental toxicity Exposure during pregnancy. inhalation (rat) / No birth defects were observed. Human experience Inhalation: Throat: Frostbite, damage. (effects associated with substance abuse) Heart: Cardiac arrhythmias, death. (effects associated with substance abuse) 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Biodegradation: Not readily biodegradable. Octanol Water Partition Coefficient: log Pow = 1.08 (Practically no potential to bioaccumulate.) Photodegradation: Half -life direct photolysis: = 8.4 y Mobility and Distribution in the Environment: Moderate adsorption / Log Koc = 1.8 Global Warming Potential: GWP = 0.33 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0.055 Data for Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- (2837 -89 -0) Biodegradation: Not readily biodegradable. (28 d) biodegradation 2 - 5 Slight potential to bioaccumulate. Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 9 / 13 Material Safety Data Sheet ARKemn Refrigerant 401A Octanol Water Partition Coefficient: log Pow = 1.9 -2.0 Global Warming Potential: GWP 470 (Global warming potential with respect to CO2 (time horizon 100 years)) Ozone Depletion Potential: ODP approx. 0.02 (Ozone depletion potential; ODP; (R -11 = 1)) Data for Ethane, 1,1- difluoro- (75 -37 -6) Photodegradation: Degradation by radicals OH Half -life direct photolysis: approximately 1.04 y Global Warming Potential: GWP = 140 (CO2) Ecotoxicolocly No data are available. Data for Methane, chlorodifluoro- (75 -45-6) Aquatic toxicity data: Practically nontoxic. Fish 24 h Toxicity threshold = 180 mg /I Microorganisms: Slightly toxic. under anaerobic conditions / Bacteria 24 h Toxicity threshold > 400 mg /I 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3163 Proper shipping name : Liquefied gas, n.o.s. Technical name : (Chlorodifluoromethane, Chlorotetrafluoroethane) Class : 2.2 Marine pollutant : no Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 10 / 13 Material Safety Data Sheet ARemn Refrigerant 401A International Maritime Dangerous Goods Code (IMDG) UN Number : 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. Technical name : (CHLORODIFLUOROMETHANE, CHLOROTETRAFLUOROETHANE) Class : 2.2 Marine pollutant : no 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Conforms to Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Conforms to published by ERMA New Zealand United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 11 / 13 Material Safety Data Sheet Ar -<emn Refrigerant 401A SARA Title III — Section 313 Toxic Chemicals: Chemical Name CAS -No. De minimis Reportable concentration threshold: Methane, chlorodifluoro- 75 -45-6 1.0 % 10000 Ibs (Otherwise used (non - manufacturing /processing)) 25000 Ibs (Manufacturing and processing) Ethane, 2- chloro- 1,1,1,2- 2837 -89 -0 1.0 % 10000 Ibs (Otherwise tetrafluoro- used (non - manufacturing /processing)) 25000 Ibs (Manufacturing and processing) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1 % is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations New Jersey Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 Ethane, 1,1- difluoro- 75 -37 -6 Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 12 / 13 Material Safety Data Sheet AR1 -<e fl Refrigerant 401A Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 Pennsylvania Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 Ethane, 1,1- difluoro- 75 -37 -6 Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 Pennsylvania Right to Know — Environmentally Hazardous Substance(s) Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Latest Revision(s): Revised Section(s): Initial entry Reference number: 000000057064 Date of Revision: 11/04/2010 Date Printed: 11/04/2010 Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. Product code: 04607 Version 1.0 Issued on: 11/04/2010 Page: 13 / 13 Material Safety Data Sheet A RKemA Refrigerant 401b 1. PRODUCT AND COMPANY IDENTIFICATION Company Arkema I nc. 2000 R CE �/ TED 2000 Marrket Street 1 jJ Philadelphia, Pennsylvania 19103 Fluorochemicals FEB 15 2011 Customer Service Telephone Number: (800) 245 -5858 CITY OF TIGARD (Monday through Friday, 8:30 AM to 5:30 PM EST) BUILDING DIVISION Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: Refrigerant 401b Synonyms: Not available Molecular formula: CHCIF2 /CH3CHF2 /CHCIFCF3 Chemical family: Hydrofluorocarbon, Hydrochlorofluorocarbon Product use: Refrigerant 2. HAZARDS IDENTIFICATION Emergency Overview Color: Clear - colourless Physical state: gaseous Form: Liquefied gas Odor: Ether -like (slightly) WARNING! HIGH PRESSURE GAS. LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND 1S HEAVIER THAN AIR. CAUSES EYE AND RESPIRATORY TRACT IRRITATION. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 1 / 13 • Material Safety Data Sheet ARKemR Refrigerant 401b Signs and symptoms of acute exposure: Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Irritating to eyes and respiratory system. Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (extent of injury depends on severity of exposure). Skin: Contact with liquid or refrigerated gas can cause cold bums and frostbite. Inhalation: Practically nontoxic. (based on animal studies) Eyes: Contact with liquid or refrigerated gas can cause cold burns and frostbite. (mist or aerosol) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Wt/Wt OSHA Hazardous Methane, chlorodifluoro- 75 -45 -6 61 % Y Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 28 % Y Ethane, 1,1- difluoro- 75 -37 -6 11 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Notes to physician: Do not give drugs from adrenaline- ephedrine group. Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 2 / 13 Material Safety Data Sheet °*g") A Rt -Ce Refrigerant 401b 5. FIRE - FIGHTING MEASURES Flash point not applicable Auto - ignition temperature: 1,265 °F (685 °C) Lower flammable limit (LFL): None. Upper flammable limit (UFL): None. Extinguishing media (suitable): Use extinguishing media appropriate to surrounding fire conditions. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self - contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Further firefighting advice: Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. When burned, the following hazardous products of combustion can occur: hydrofluoric acid hydrochloric acid Carbon oxides Carbonyl halides 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Eliminate all ignition sources. Evacuate area of all unnecessary personnel. Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Prevent further leakage or spillage if you can do so without risk. Keep upwind. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Avoid dispersal of leaked material. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 3 / 13 Material Safety Data Sheet t ' ARKemn Refrigerant 401b 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing gas. Avoid contact with eyes. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Use a backflow preventative device in piping. Wash thoroughly after handling. Close valve after each use and when empty. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Store separate from: Alkaline earth metals Finely divided metals (aluminium, magnesium, zinc...) Strong oxidizing agents Alkali metals Strong bases 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Methane, chlorodifluoro- (75 -45 -6) US. ACGIH Threshold Limit Values Time Weighted Average (TWA): 1,000 ppm Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- (2837 -89 -0) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 4 / 13 Material Safety Data Sheet R Kemn Refrigerant 401b Remarks: Listed Ethane, 1,1-difluoro- (75-37-6) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (2,700 mg /m3) Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below airborne exposure limits (if applicable see above),If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Monitor carbon monoxide and oxygen levels in tanks and enclosed spaces. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components. Full facepiece equipment is recommended and, if used, replaces need for face shield and /or chemical goggles. Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self- contained breathing apparatus or positive - pressure airline with auxiliary self - contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Where there is potential for eye contact, wear chemical goggles and have eye flushing equipment immediately available. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Clear - colourless Physical state: gaseous Form: Liquefied gas Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 5 / 13 Material Safety Data Sheet ARKE?C Refrigerant 401b Odor: Ether -like (slightly) pH: Not applicable Density: 1.193 g /cm3 (77 °F (25 °C)) Vapor pressure: 57,858.653 mmHg (77 °F (25 °C)) Vapor density: 3.2 kg /m3 (77 °F (25 °C)) (Air = 1.0) Boiling point/boiling -30.3 °F ( -34.6 °C) range: Solubility in water: 0.1 g/I 77 °F (25 °C) % Volatiles: 100 % 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Alkaline earth metals Finely divided metals (aluminium, magnesium, zinc...) Strong oxidizing agents Alkali metals Strong bases Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : hydrofluoric acid hydrochloric acid Carbon oxides Carbonyl halides 11. TOXICOLOGICAL INFORMATION Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approx. 780 mg /I (220000 ppm). Skin Irritation: Moderately irritating. (rabbit) (Rapid evaporation of the liquid may cause frostbite.) Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 6 / 13 Material Safety Data Sheet ARKemn Refrigerant 401b Eye Irritation: Slightly irritating. (rabbit) (30 s) (gas spray) Sensitization: Causes cardiac sensitization. (dog, rat, mouse, rabbit and monkey) irregular heart beat, rapid heart beat, in some cases, sudden death Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat, rabbit, mouse / affected organ(s): liver, lung, central nervous system / (Repeated exposure at high concentrations) Chronic oral administration to rat / No adverse effects reported. Carcinogenicity Chronic inhalation administration to mouse / No increase in tumor incidence was reported. Chronic inhalation administration to female rat / No increase in tumor incidence was reported. Chronic inhalation administration to male rat / affected organ(s): salivary gland / Increased incidence of tumors was reported. (The observed tumors do not appear to be relevant for men.) Genotoxicity Assessment in Vitro: Genetic changes were observed in laboratory tests using: bacteria No genetic changes were observed in laboratory tests using: animal cells, yeast Genotoxicitv Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals, rodent Developmental toxicity Exposure during pregnancy. inhalation (rat) / Birth defects were observed. (eye) Exposure during pregnancy. inhalation (rabbit) / No birth defects were observed. Reproductive effects Reproduction test. inhalation (rat and mouse) / No toxicity to reproduction / (males) Human experience Inhalation: Lung: Asphyxia, suffocation. Heart: Palpitation. (based on reports of occupational exposure to workers) Human experience Skin contact: Skin: irritation, redness, swelling. (repeated or prolonged exposure) Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 7 / 13 Material Safety Data Sheet ARt -CemA Refrigerant 401b Data for Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- (2837 -89 -0) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 between 1,280 - 1,670 mg /I (between 230000 - 300000 ppm). Signs /effects reported after acute exposure. (dog, mouse) signs: anesthetic effects Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Inhalation administration to rat and mouse / affected organ(s): central nervous system / signs: blood chemistry changes Carcinogenicity Chronic inhalation administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (at doses that produce effects in mothers) Data for Ethane, 1,1- difluoro- (75 -37 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LCO = 861 mg /I (319000 ppm). Practically nontoxic. (rat) 4 h ALC = 1,034 mg /I (383000 ppm). Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress - induced heart effects. rapid heart beat, irregular heart beat, in some cases, sudden death Repeated dose toxicity Repeated inhalation administration to rat / affected organ(s): respiratory tract / signs: irritation / (Repeated exposure at high concentrations) Carcinogenicity Chronic inhalation administration to rat / No increase in tumor incidence was reported. Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 8 / 13 Material Safety Data Sheet A�tt -�C�mA Refrigerant 401b Genotoxicity Assessment in Vitro: No genetic changes were observed in a laboratory test using: bacteria Genetic changes were observed in a laboratory test using: human cells Genotoxicity Assessment in Vivo: No genetic changes were observed in a laboratory test using: rodent, mouse Developmental toxicity Exposure during pregnancy. inhalation (rat) / No birth defects were observed. Human experience Inhalation: Throat: Frostbite, damage. (effects associated with substance abuse) Heart: Cardiac arrhythmias, death. (effects associated with substance abuse) 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Biodegradation: Not readily biodegradable. Octanol Water Partition Coefficient: log Pow = 1.08 (Practically no potential to bioaccumulate.) Photodegradation: Half -life direct photolysis: = 8.4 y Mobility and Distribution in the Environment: Moderate adsorption / Log Koc = 1.8 Global Warming Potential: GWP = 0.33 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0.055 Data for Ethane, 2- chloro - 1,1,1,2 - tetrafluoro- (2837 -89 -0) Biodegradation: Not readily biodegradable. (28 d) biodegradation 2 - 5 % Slight potential to bioaccumulate. Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 9 / 13 Material Safety Data Sheet ARKemA Refrigerant 401b Octanol Water Partition Coefficient: log Pow = 1.9 - 2.0 Global Warming Potential: GWP 470 (Global warming potential with respect to CO2 (time horizon 100 years)) Ozone Depletion Potential: ODP approx. 0.02 (Ozone depletion potential; ODP; (R -11 = 1)) Data for Ethane, 1,1- difluoro- (75 -37 -6) Photodegradation: Degradation by radicals OH Half -life direct photolysis: approximately 1.04 y Global Warming Potential: GWP = 140 (CO2) Ecotoxicology Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75-45-6) Aquatic toxicity data: Practically nontoxic. Fish 24 h Toxicity threshold = 180 mg /I Microorganisms: Slightly toxic. under anaerobic conditions / Bacteria 24 h Toxicity threshold > 400 mg /I 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3163 Proper shipping name : Liquefied gas, n.o.s. Technical name : (Chlorodifluoromethane, Chlorotetrafluoroethane) Class : 2.2 Marine pollutant : no Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 10 / 13 Material Safety Data Sheet w i- emA Refrigerant 401b International Maritime Dangerous Goods Code (IMDG) UN Number : 3163 Proper shipping name . LIQUEFIED GAS, N.O.S. Technical name : (CHLORODIFLUOROMETHANE, CHLOROTETRAFLUOROETHANE) Class : 2.2 Marine pollutant : no 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Conforms to Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Conforms to published by ERMA New Zealand United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 11 / 13 Material Safety Data Sheet ARt (2mA Refrigerant 401b SARA Title III — Section 313 Toxic Chemicals: Chemical Name CAS -No. De minimis Reportable concentration threshold: Methane, chlorodifluoro- 75 -45-6 1.0 % 10000 Ibs (Otherwise used (non- manufacturing/processing)) 25000 Ibs (Manufacturing and processing) Ethane, 2- chloro- 1,1,1,2- 2837 -89 -0 1.0 % 10000 Ibs (Otherwise tetrafluoro- used (non - manufacturing /processing)) 25000 Ibs (Manufacturing and processing) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations New Jersey Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 Ethane, 1,1- difluoro- 75 -37 -6 Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 12 / 13 Material Safety Data Sheet ARKEMPI Refrigerant 401b Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 Pennsylvania Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45-6 Ethane, 1,1- difluoro- 75 -37-6 Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 Pennsylvania Right to Know — Environmentally Hazardous Substance(s) Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Latest Revision(s): Revised Section(s): Initial entry Reference number: 000000057065 Date of Revision: 11/18/2010 Date Printed: 11/18/2010 Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. Product code: 04608 Version 1.0 Issued on: 11/18/2010 Page: 13 / 13 Material Safety Data Sheet ARKe FORANE ®404A 1. PRODUCT AND COMPANY IDENTIFICATION Company Arkema Inc. 2000 Market Street RECEIVED Philadelphia, Pennsylvania 19103 Fluorochemicals FEB 15 ?ell Customer Service Telephone Number: (800) 245 -5858 CITY OF TIGARD (Monday through Friday, 8:30 AM to 5:30 PM EST) UI.DING DIVISION Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: FORANE ® 404A Synonyms: R -404A, HFC 404A, FORANE FX 70 Molecular formula: CHF2CF3 /CH3CF3 /CH2FCF3 Chemical family: Hydrofluorocarbon Molecular weight: 97.6 g /mol Product use: Refrigerant 2. HAZARDS IDENTIFICATION Emergency Overview Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like CAUTION! HIGH PRESSURE GAS. LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Signs and symptoms of acute exposure: Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 1 / 13 Material Safety Data Sheet ARKE=f n FORANE ®404A Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (severity of effects depends on extent of exposure). Inhalation: Practically nontoxic. (based on components) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Wt/Wt OSHA Hazardous Ethane, 1,1,1 - trifluoro- 420 -46 -2 52 % Y Ethane, pentafluoro- 354 -33 -6 44 % Y Ethane, 1,1,1,2 - tetrafluoro- 811 -97 -2 4 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: Immediately flush eye(s) with plenty of water. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Notes to physician: Do not give drugs from adrenaline- ephedrine group. 5. FIRE - FIGHTING MEASURES Flash point Not applicable Auto - ignition temperature: Not determined Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 2 / 13 Material Safety Data Sheet ARKemn FORANE ®404A Lower flammable limit (LFL): None. Upper flammable limit (UFL): None. Extinguishing media (suitable): Use extinguishing measures to suit surroundings. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self- contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Further firefighting advice: Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. When burned, the following hazardous products of combustion can occur: Hydrogen fluoride 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Keep upwind. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Stop the leak if you can do so without risk. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing gas. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Use a backflow preventative device in piping. Wash thoroughly after handling. Close valve after each use and when empty. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 3 / 13 Material Safety Data Sheet 4 AR FORANE ®404A Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Keep away from oxidising agents and strongly acid or alkaline materials. Temperature tolerance — Do not store above: 118 °F (48 °C) 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Ethane, 1,1,1-trifluoro- (420-46-2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (3,400 mg /m3) Remarks: Listed Ethane, pentafluoro- (354 -33 -6) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,900 mg /m3) Remarks: Listed Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,240 mg /m3) Remarks: Listed Ethane, 1,1,1 - trifluoro- (420 -46 -2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (3,400 mg /m3) Remarks: Listed Ethane, pentafluoro- (354 -33 -6) US. Workplace Environmental Exposure Level (WEEL) Guides Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 4 / 13 Material Safety Data Sheet ARK emra FORANE ®404A Time Weighted Average (TWA): 1,000 ppm (4,900 mg /m3) Remarks: Listed Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,240 mg /m3) Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if necessary to control exposure levels below airborne exposure limits (see above). If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components (full facepiece recommended). Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self - contained breathing apparatus or positive - pressure airline with auxiliary self - contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Use good industrial practice to avoid eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Clear - colourless Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 5 / 13 Material Safety Data Sheet ARKemn FORANE ®404A Physical state: gas Form: Liquefied gas Odor: Slightly ether -like pH: not applicable Density: not determined Specific Gravity (Relative 1.05 (77 °F( 25 °C)) density): Vapor pressure: 8,445 mmHg (70.0 °F (21.1 °C)) Vapor density: 3.39 kg /m3 Boiling point/boiling -54.0 °F (-47.8 °C) range: Freezing point: not determined Melting point: not determined Solubility in water: negligible % Volatiles: 100 % Molecular weight: 97.6 g /mol 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Strong oxidizing agents Strong acids Alkaline materials Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : Hydrogen fluoride Carbon monoxide Carbon dioxide (CO2) Carbonyl halides Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 6 / 13 Material Safety Data Sheet If IARKemA FORANE ®404A 11. TOXICOLOGICAL INFORMATION Data on this material and /or its components are summarized below. Data for Ethane, 1,1,1 - trifluoro- (420 -46 -2) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 > 540,000 ppm. Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Repeated inhalation administration to rat and guinea pig / affected organ(s): lung / signs: irritation, bronchitis, pneumonia Chronic oral administration to rat / No adverse effects reported. Carcinogenicity Chronic oral administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: animal cells Both positive and negative responses for genetic changes were observed in laboratory tests using: bacteria Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. Data for Ethane, pentafluoro- (354 -33-6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 > 3,900 mg /I (> 800000 ppm). Sensitization: Causes cardiac sensitization. inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 7 / 13 Material Safety Data Sheet "°"") I -cemA FORANE ®404A Subchronic inhalation administration to rat / No adverse systemic effects reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. Data for Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approximately 2,360 mg /I (— 567000 ppm). Practically nontoxic. (rat) 0.5 h LC50 approximately 3,122 mg /I (— 750000 ppm). Signs /effects reported after acute exposure. (mouse, dog, cat, monkey) signs: anesthetic effects Skin Irritation: Slightly irritating. (rabbit) (24 h) Eye Irritation: Slightly irritating. (rabbit) Sensitization: Causes cardiac sensitization. inhalation. (dog) Stress - induced heart effects. irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat / No adverse systemic effects reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (delays in development, at doses that produce effects in mothers) Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 8 / 13 Material Safety Data Sheet ARKE?f - 7 n FORANE ®404A 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data on this material and /or its components are summarized below. Data for Ethane, pentafluoro- (354 -33 -6) Biodegradation: Not readily biodegradable. (Closed Bottle test, 28 d) biodegradation 5 % Octanol Water Partition Coefficient: log Pow = 1.48 Global Warming Potential: GWP 0.84 (Halocarbon global warming potential; HGWP; (R -11 = 1)) Ozone Depletion Potential: ODP < 0.001 (Ozone depletion potential; ODP; (R -11 = 1)) Data for Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) Biodegradation: Not readily biodegradable. (28 d) biodegradation 3 % Bioaccumulation: Practically no potential to bioaccumulate. Octanol Water Partition Coefficient: log Pow = 1.06 Photodegradation: Degradation in the atmosphere Half -life direct photolysis: = 9.6 - 16.7 y (in atmosphere) Global Warming Potential: GWP = 0.3 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0 Ecotoxicology Data on this material and /or its components are summarized below. Data for Ethane, 1,1,1 - trifluoro- (420 -46 -2) Aquatic toxicity data: No more than slightly toxic. Oncorhynchus mykiss (rainbow trout) 96 h LC50 > 40 mg /I Aquatic invertebrates: Practically nontoxic. Daphnia magna (Water flea) 48 h LC50 = 300 mg /I Data for Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 9 / 13 Material Safety Data Sheet A RKEMR FORANE ®404A Aquatic toxicity data: Practically nontoxic. Oncorhynchus mykiss (rainbow trout) 96 h LC50 = 450 mg /I Aquatic invertebrates: Practically nontoxic. Daphnia magna (Water flea) 48 h EC50 = 930 mg /I Microorganisms: Practically nontoxic. Bacteria 16 h EC10 > 730 mg /I 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3337 Proper shipping name : Refrigerant gas R 404A Class : 2.2 Marine pollutant : no International Maritime Dangerous Goods Code (IMDG) UN Number : 3337 Proper shipping name : REFRIGERANT GAS R 404A Class : 2.2 Marine pollutant : no 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 10 / 13 Material Safety Data Sheet ARKemA FORANE ®404A Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Conforms to Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Conforms to published by ERMA New Zealand United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard SARA Title III — Section 313 Toxic Chemicals: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. Toxic Substances Control Act — Section 12(b): Chemical Name CAS -No. Ethane, 1,1,1,2 - tetrafluoro- 811 -97 -2 OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 11 / 13 Material Safety Data Sheet ARKE'!'7 n FORANE ®404A IARC: No component of this product present at levels greater than or equal to 0.1 % is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations Massachusetts Right to Know Chemical Name CAS -No. Hydrochloric acid 7647 -01 -0 Massachusetts Right to Know — Extraordinarily Hazardous Substance(s) Chemical Name CAS -No. Hydrochloric acid 7647 -01 -0 New Jersey Right to Know Chemical Name CAS -No. Ethane, 1,1,1 - trifluoro- 420 -46 -2 Pennsylvania Right to Know Chemical Name CAS -No. Ethane, 1,1,1,2- tetrafluoro- 811 -97 -2 Ethane, pentafluoro- 354 -33 -6 Ethane, 1,1,1- trifluoro- 420 -46 -2 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Latest Revision(s): Revised Section(s): Initial entry Reference number: 000000057859 Date of Revision: 01/15/2009 Date Printed: 01/15/2009 FORANE ® is a registered trademark of Arkema Inc. Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 12 / 13 Material Safety Data Sheet raRKemn FORANE ®404A Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. Product code: 04389 Version 1.0 Issued on: 01/15/2009 Page: 13 / 13 Material Safety Data Sheet nRKe FORANE ® 407C 1. PRODUCT AND COMPANY IDENTIFICATION Company RECEIVED Arkema Inc. 2000 Market Street Philadelphia, Pennsylvania 19103 FEB 1 5 2011 Fluorochemicals CITY OFTIGARD BUILDING DIVISION Customer Service Telephone Number: (800) 245 -5858 (Monday through Friday, 8:30 AM to 5:30 PM EST) Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: FORANE ® 407C Synonyms: R -407C, HFC 407C Molecular formula: CH2F2 /CHF2CF3 /CF3CH2F Chemical family: Hydrofluorocarbon Molecular weight: 86.2 g /mol Product use: Refrigerant 2. HAZARDS IDENTIFICATION Emergency Overview Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like CAUTION! HIGH PRESSURE GAS. LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 1 / 12 Material Safety Data Sheet A RKe mn FORANE ®407C Signs and symptoms of acute exposure: Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (severity of effects depends on extent of exposure). Skin: Slightly irritating. (based on components) Inhalation: Practically nontoxic. (based on components) Eyes: Slightly irritating. (based on components) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Wt/Wt OSHA Hazardous Ethane, 1,1,1,2- tetrafluoro- 811 -97 -2 52 % Y Ethane, pentafluoro- 354 -33 -6 25 % Y Methane, difluoro- 75 -10 -5 23 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: Immediately flush eye(s) with plenty of water. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Notes to physician: Do not give drugs from adrenaline- ephedrine group. Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 2 / 12 °" Material Safety Data Sheet " I-temn FORANE ® 407C 5. FIRE - FIGHTING MEASURES Flash point Not applicable Auto - ignition temperature: not determined Lower flammable limit (LFL): None. Upper flammable limit (UFL): None. Extinguishing media (suitable): Use extinguishing measures to suit surroundings. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self- contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Further firefighting advice: Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. When burned, the following hazardous products of combustion can occur: Hydrogen fluoride 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Keep upwind. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Stop the leak if you can do so without risk. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 3 / 12 Material Safety Data Sheet nRKemr� FORANE ® 407C 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing gas. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Use a backflow preventative device in piping. Wash thoroughly after handling. Close valve after each use and when empty. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Keep away from oxidising agents and strongly acid or alkaline materials. Temperature tolerance — Do not store above: 118 °F (48 °C) 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Ethane, 1,1,1,2- tetrafluoro- (811 -97 -2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,240 mg /m3) Remarks: Listed Ethane, pentafluoro- (354 -33 -6) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,900 mg /m3) Remarks: Listed Methane, difluoro- (75 -10 -5) US. Workplace Environmental Exposure Level (WEEL) Guides Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 4 / 12 Material Safety Data Sheet AR emn FORANE ®407C Time Weighted Average (TWA): 1,000 ppm (2,200 mg /m3) Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if necessary to control exposure levels below airborne exposure limits (see above). If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components (full facepiece recommended). Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self - contained breathing apparatus or positive - pressure airline with auxiliary self- contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Use good industrial practice to avoid eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like pH: not applicable Density: not determined Specific Gravity (Relative 1.14 (77 °F( 25 °C)) density): Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 5 / 12 Material Safety Data Sheet ARKhmA FORANE ® 407C Vapor pressure: 7,839 mmHg (70.0 °F (21.1 °C)) Vapor density: 2.99 kg /m3 Boiling point/boiling -44.1 °F ( -42.3 °C) range: Freezing point: not determined Melting point: not determined Solubility in water: negligible % Volatiles: 100 % Molecular weight: 86.2 g /mol 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Strong oxidizing agents Strong acids Alkaline materials Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : Hydrogen fluoride Carbon monoxide Carbon dioxide (CO2) Carbonyl halides 11. TOXICOLOGICAL INFORMATION Data on this material and /or its components are summarized below. Data for Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approximately 2,360 mg /I (— 567000 ppm). Practically nontoxic. (rat) 0.5 h LC50 approximately 3,122 mg /I (— 750000 ppm). Signs /effects reported after acute exposure. (mouse, dog, cat, monkey) signs: anesthetic effects Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 6 / 12 Material Safety Data Sheet ARKE?MA FORANE ® 407C Skin Irritation: Slightly irritating. (rabbit) (24 h) Eye Irritation: Slightly irritating. (rabbit) Sensitization: Causes cardiac sensitization. inhalation. (dog) Stress - induced heart effects. irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat / No adverse systemic effects reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (delays in development, at doses that produce effects in mothers) Data for Ethane, pentafluoro- (354 -33 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 > 3,900 mg /I (> 800000 ppm). Sensitization: Causes cardiac sensitization. inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Subchronic inhalation administration to rat / No adverse systemic effects reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 7 / 12 Material Safety Data Sheet ARKemn FORANE ® 407C Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. Data for Methane, difluoro- (75 -10 -5) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 > 520000 ppm. signs: anesthetic effects, central nervous system depression Sensitization: Causes cardiac sensitization. inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Repeated inhalation administration to rat / no adverse effects Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (at doses that produce effects in mothers) 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data on this material and /or its components are summarized below. Data for Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) Biodegradation: Not readily biodegradable. (28 d) biodegradation 3 % Bioaccumulation: Practically no potential to bioaccumulate. Octanol Water Partition Coefficient: log Pow = 1.06 Photodegradation: Degradation in the atmosphere Half -life direct photolysis: = 9.6 - 16.7 y (in atmosphere) Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 8 / 12 Material Safety Data Sheet ARKemn FORANE ® 407C Global Warming Potential: GWP = 0.3 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0 Data for Ethane, pentafluoro- (354 -33 -6) Biodegradation: Not readily biodegradable. (Closed Bottle test, 28 d) biodegradation 5 Octanol Water Partition Coefficient: log Pow = 1.48 Global Warming Potential: GWP 0.84 ( Halocarbon global warming potential; HGWP; (R -11 = 1)) Ozone Depletion Potential: ODP < 0.001 (Ozone depletion potential; ODP; (R -11 = 1)) Data for Methane, difluoro- (75 -10-5) Biodegradation: Not biodegradable. (28 d) biodegradation 5 % / Closed Bottle test Slight potential to bioaccumulate. Octanol Water Partition Coefficient: log Pow = 0.21 Global Warming Potential: GWP = 543 (CO2) Ozone Depletion Potential: ODP = 0 (Ozone depletion potential; ODP; (R -11 = 1)) Ecotoxicoloqy Data on this material and /or its components are summarized below. Data for Ethane, 1,1,1,2 - tetrafluoro- (811 -97 -2) Aquatic toxicity data: Practically nontoxic. Oncorhynchus mykiss (rainbow trout) 96 h LC50 = 450 mg /I Aquatic invertebrates: Practically nontoxic. Daphnia magna (Water flea) 48 h EC50 = 930 mg /I Microorganisms: Practically nontoxic. Bacteria 16 h EC10 > 730 mg /I Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 9 / 12 Material Safety Data Sheet nRI-<e inn FORANE ® 407C 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3340 Proper shipping name : Refrigerant gas R 407C Class : 2.2 Marine pollutant : no International Maritime Dangerous Goods Code (IMDG) UN Number : 3340 Proper shipping name : REFRIGERANT GAS R 407C Class : 2.2 Marine pollutant : no 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Does not conform Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 10 / 12 Material Safety Data Sheet nRKemA FORANE ® 407C China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Does not conform published by ERMA New Zealand United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard SARA Title III — Section 313 Toxic Chemicals: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. Toxic Substances Control Act — Section 12(b): Chemical Name CAS -No. Ethane, 1,1,1,2 - tetrafluoro- 811 -97 -2 OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. IARC: No component of this product present at levels greater than or equal to 0.1 % is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations Massachusetts Right to Know No components are subject to the Massachusetts Right to Know Act. Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 11 / 12 Material Safety Data Sheet ARk mn FORANE ® 407C New Jersey Right to Know Chemical Name CAS -No. Methane, difluoro- 75 -10 -5 Pennsylvania Right to Know Chemical Name CAS -No. Ethane, 1,1,1,2 - tetrafluoro- 811 -97 -2 Ethane, pentafluoro- 354 -33 -6 Methane, difluoro- 75 -10 -5 Pennsylvania Right to Know — Environmentally Hazardous Substance(s) Chemical Name CAS -No. Methane, difluoro- 75 -10 -5 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Latest Revision(s): Revised Section(s): Initial entry Reference number: 000000057860 Date of Revision: 01/15/2009 Date Printed: 01/15/2009 FORANE ® is a registered trademark of Arkema Inc. Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. Product code: 04070 Version 1.0 Issued on: 01/15/2009 Page: 12 / 12 Material Safety Data Sheet ARKemra FORANE 408A 1. PRODUCT AND COMPANY IDENTIFICATION Company fa l rnin Arkema Inc. yk ° Y 2000 Market Street / am. Philadelphia, Pennsylvania 19103 FEB 1 5 2011 Fluorochemicals Customer Service Telephone Number: (800) 245 -5858 1 O (Monday through Friday, 8:30 AM to 5:30 PM EST) BUILDING DIVISION! Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: FORANE 408A Synonyms: R -408A, HFC 408A, FORANE FX 10 Molecular formula: Not available Chemical family: Hydrochlorofluorocarbon Molecular weight: 87.01 g /mol Product use: Low temperature refrigerant, Air conditioning 2. HAZARDS IDENTIFICATION Emergency Overview Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like CAUTION! HIGH PRESSURE GAS. LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. MAY CAUSE SKIN IRRITATION. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 1 / 13 Material Safety Data Sheet _. ARKemn FORANE 408A Signs and symptoms of acute exposure: May cause skin irritation. Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (severity of effects depends on extent of exposure). Skin: Moderately irritating. (based on components) Inhalation: Practically nontoxic. (based on components) Eyes: Slightly irritating. (based on components) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. WtlWt OSHA Hazardous Methane, chlorodifluoro- 75 -45 -6 >= 30 - < 60 % Y Ethane, 1,1,1- trifluoro- 420 -46 -2 >= 30 - < 60 % Y Ethane, pentafluoro- 354 -33 -6 >= 5 - < 10 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Remove contaminated clothing and shoes. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: Immediately flush eye(s) with plenty of water. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Notes to physician: Do not give drugs from adrenaline- ephedrine group. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 2 / 13 Material Safety Data Sheet ARKemn FORANE 408A 5. FIRE - FIGHTING MEASURES Flash point Not applicableNot applicable Auto- ignition temperature: not determinednot determined Lower flammable limit (LFL): None.None. Upper flammable limit (UFL): None.None. Extinguishing media (suitable): Use extinguishing measures to suit surroundings. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self- contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Further firefighting advice: Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. When burned, the following hazardous products of combustion can occur: Hydrogen fluoride hydrogen chloride 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Keep upwind. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Stop the leak if you can do so without risk. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 3 / 13 Material Safety Data Sheet ARKE?ITIA FORANE 408A 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing gas. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Use a backflow preventative device in piping. Wash thoroughly after handling. Close valve after each use and when empty. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Keep away from oxidising agents and strongly acid or alkaline materials. Temperature tolerance — Do not store above: 118 °F (48 °C) 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Methane, chlorodifluoro- (75 -45 -6) US. ACGIH Threshold Limit Values Time Weighted Average (TWA): 1,000 ppm Ethane, 1,1,1 - trifluoro- (420 -46 -2) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (3,400 mg /m3) Remarks: Listed Ethane, pentafluoro- (354 -33 -6) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,900 mg /m3) Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 4 / 13 Material Safety Data Sheet nnkemn FORANE 408A Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if necessary to control exposure levels below airborne exposure limits (see above). If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components (full facepiece recommended). Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self- contained breathing apparatus or positive - pressure airline with auxiliary self- contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Use good industrial practice to avoid eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like pH: not applicable Density: not determined Specific Gravity (Relative 1.06 (77 °F( 25 ° C)) density): Vapor pressure: 7,834 mmHg (70.0 °F (21.1 °C)) Vapor density: 3.02 kg /m3 Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 5 / 13 Material Safety Data Sheet ARKemn FORANE 408A Boiling point/boiling -46.3 °F (-43.5 °C) range: Freezing point: not determined Melting point: not determined Solubility in water: Slightly soluble % Volatiles: 100 % Molecular weight: 87.01 g /mol 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Strong oxidizing agents Strong acids Alkaline materials Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : Halogen acids (HCI and HF) Carbon monoxide Carbon dioxide (CO2) Carbonyl halides 11. TOXICOLOGICAL INFORMATION Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approx. 780 mg /I (220000 ppm). Skin Irritation: Moderately irritating. (rabbit) (Rapid evaporation of the liquid may cause frostbite.) Eye Irritation: Slightly irritating. (rabbit) (30 s) (gas spray) Sensitization: Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 6 / 13 Material Safety Data Sheet ARKemra FORANE 408A Causes cardiac sensitization. (dog, rat, mouse, rabbit and monkey) irregular heart beat, rapid heart beat, in some cases, sudden death Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat, rabbit, mouse / affected organ(s): liver, lung, central nervous system / (Repeated exposure at high concentrations) Chronic oral administration to rat / No adverse effects reported. Carcinogenicity Chronic inhalation administration to mouse / No increase in tumor incidence was reported. Chronic inhalation administration to female rat / No increase in tumor incidence was reported. Chronic inhalation administration to male rat / affected organ(s): salivary gland / Increased incidence of tumors was reported. (The observed tumors do not appear to be relevant for men.) Genotoxicity Assessment in Vitro: Genetic changes were observed in laboratory tests using: bacteria No genetic changes were observed in laboratory tests using: animal cells, yeast Genotoxicitv Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals, rodent Developmental toxicity Exposure during pregnancy. inhalation (rat) / Birth defects were observed. (eye) Exposure during pregnancy. inhalation (rabbit) / No birth defects were observed. Reproductive effects Reproduction test. inhalation (rat and mouse) / No toxicity to reproduction / (males) Human experience Inhalation: Lung: Asphyxia, suffocation. Heart: Palpitation. (based on reports of occupational exposure to workers) Human experience Skin contact: Skin: irritation, redness, swelling. (repeated or prolonged exposure) Data for Ethane, 1,1,1 - trifluoro- (420 -46 -2) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 > 540,000 ppm. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 7 / 13 Material Safety Data Sheet ARKemR FORANE 408A Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Repeated inhalation administration to rat and guinea pig / affected organ(s): lung / signs: irritation, bronchitis, pneumonia Chronic oral administration to rat / No adverse effects reported. Carcinogenicity Chronic oral administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: animal cells Both positive and negative responses for genetic changes were observed in laboratory tests using: bacteria Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. Data for Ethane, pentafluoro- (354 -33 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 > 3,900 mg /I (> 800000 ppm). Sensitization: Causes cardiac sensitization. inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Subchronic inhalation administration to rat / No adverse systemic effects reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 8 / 13 Material Safety Data Sheet ArRI —<e - lA FORANE 408A Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro (75 - 45 - 6) Biodegradation: Not readily biodegradable. (28 d) biodegradation 0 % Octanol Water Partition Coefficient: log Pow = 1.08 (Practically no potential to bioaccumulate.) Photodegradation: Half -life direct photolysis: = 8.4 y Mobility and Distribution in the Environment: Moderate adsorption / Log Koc = 1.8 Global Warming Potential: GWP = 0.33 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0.055 Data for Ethane, pentafluoro- (354 -33 -6) Biodegradation: Not readily biodegradable. (Closed Bottle test, 28 d) biodegradation 5 % Octanol Water Partition Coefficient: log Pow = 1.48 Global Warming Potential: GWP 0.84 (Halocarbon global warming potential; HGWP; (R -11 = 1)) Ozone Depletion Potential: ODP < 0.001 (Ozone depletion potential; ODP; (R -11 = 1)) Ecotoxicology Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Aquatic toxicity data: Practically nontoxic. Fish 24 h Toxicity threshold = 180 mg /I Microorganisms: Slightly toxic. under anaerobic conditions / Bacteria 24 h Toxicity threshold > 400 mg /I Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 9 / 13 Material Safety Data Sheet ARKemA FORANE 408A Data for Ethane, 1,1,1 - trifluoro- (420 -46 -2) Aquatic toxicity data: No more than slightly toxic. Oncorhynchus mykiss (rainbow trout) 96 h LC50 > 40 mg /I Aquatic invertebrates: Practically nontoxic. Daphnia magna (Water flea) 48 h LC50 = 300 mg /I 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3163 Proper shipping name : Liquefied gas, n.o.s. Technical name : (Chlorodifluoromethane, 1,1,1 Trifluoroethane) Class : 2.2 Marine pollutant : no International Maritime Dangerous Goods Code (IMDG) UN Number : 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. Technical name : (CHLORODIFLUOROMETHANE, 1.1.1 - TRIFLUOROETHANE) Class : 2.2 Marine pollutant : no 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 10 / 13 Material Safety Data Sheet . ARKemn FORANE 408A Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Does not conform Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Does not conform published by ERMA New Zealand United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard SARA Title III — Section 313 Toxic Chemicals: Chemical Name CAS -No. De minimis Reportable threshold: concentration Methane, chlorodifluoro- 75 -45 -6 1.0 % 10000 Ibs (Otherwise used (non - manufacturing /processing)) 25000 lbs (Manufacturing and processing) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 11 / 13 Material Safety Data Sheet nRKe FORANE 408A IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1 % is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations Massachusetts Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 New Jersey Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45-6 Ethane, 1,1,1 - trifluoro- 420 -46 -2 Pennsylvania Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 Ethane, pentafluoro- 354 -33 -6 Ethane, 1,1,1 - trifluoro- 420 -46 -2 Pennsylvania Right to Know — Environmentally Hazardous Substance(s) Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45-6 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Latest Revision(s): Revised Section(s): initial entry Reference number: 000000057861 Date of Revision: 01/15/2009 Date Printed: 01/15/2009 FORANE ® is a registered trademark of Arkema Inc. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 12 / 13 Material Safety Data Sheet AFZKemA FORANE 408A Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. Product code: 04004 Version 1.0 Issued on: 01/15/2009 Page: 13 / 13 Material Safety Data Sheet ARKemA FORANE ® 409A 1. PRODUCT AND COMPANY IDENTIFICATION Company Arkema Inc. Market Philadelphia, RECEIVED Philadelphiaphia, Pennsylvania 19103 Fluorochemicals FEB 15 2011 Customer Service Telephone Number: (800) 245 -5858 CITY OFTIGARD (Monday through Friday, 8:30 AM to 5:30 PM EST UILDING DIVISION Emergency Information Transportation: CHEMTREC: (800) 424 -9300 (24 hrs., 7 days a week) Medical: Rocky Mountain Poison Center: (303) 623 -5716 (24 hrs., 7 days a week) Product Information Product name: FORANE ® 409A Synonyms: R -409A, HCFC 409A, FORANE FX 56 Molecular formula: CHCIF2 /CHCLFCF3 /CH3CCIF2 Chemical family: Hydrochlorofluorocarbon Molecular weight: 97.43 g /mol Product use: Refrigerant 2. HAZARDS IDENTIFICATION Emergency Overview Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like CAUTION! HIGH PRESSURE GAS. LIQUID AND GAS UNDER PRESSURE. OVERHEATING OR OVERPRESSURIZING MAY CAUSE GAS RELEASE OR VIOLENT CYLINDER BURSTING. MAY DECOMPOSE ON CONTACT WITH FLAMES OR EXTREMELY HOT METAL SURFACES TO PRODUCE TOXIC AND CORROSIVE PRODUCTS. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING AND IS HEAVIER THAN AIR. MAY CAUSE SKIN IRRITATION. MAY CAUSE FROSTBITE. MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINESS, LOSS OF CONSCIOUSNESS. MAY CAUSE EFFECTS ON: HEART Potential Health Effects Primary routes of exposure: Inhalation and skin contact. Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 1 / 14 Material Safety Data Sheet RRHemn FORANE ® 409A Signs and symptoms of acute exposure: May cause skin irritation. Liquid: Rapid evaporation of the liquid may cause frostbite. Vapor: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Central nervous system effects: headache, nausea, dizziness, drowsiness, loss of consciousness. Stress induced heart effects: irregular heart beat, rapid heart beat, (severity of effects depends on extent of exposure). Skin: Moderately irritating. (based on components) Inhalation: Practically nontoxic. (based on components) Eyes: Slightly irritating. (based on components) Medical conditions aggravated by overexposure: Heart disease or compromised heart function. 3. COMPOSITION /INFORMATION ON INGREDIENTS Chemical Name CAS -No. Wt/Wt OSHA Hazardous Methane, chlorodifluoro- 75 -45 -6 60 % Y Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 25 % Y Ethane, 1- chloro -1,1- difluoro- 75 -68 -3 15 % Y Ethane, 1- chloro- 1,1,2,2 - tetrafluoro- 354 -25 -6 < 5 % Y The substance(s) marked with a "Y" in the Hazard column above, are those identified as hazardous chemicals under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is classified as hazardous under Federal OSHA regulation. 4. FIRST AID MEASURES Inhalation: If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Skin: If on skin, flush exposed skin with lukewarm water (not hot), or use other means to warm skin slowly. Remove contaminated clothing and shoes. Get medical attention if frostbitten by liquid or if irritation occurs. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eyes: Immediately flush eye(s) with plenty of water. Ingestion: Ingestion is not applicable - product is a gas at ambient temperatures. Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 2 / 14 Material Safety Data Sheet A RKemn FORANE ® 409A Notes to physician: Do not give drugs from adrenaline- ephedrine group. 5. FIRE MEASURES Flash point Not applicable Auto - ignition temperature: not determined Lower flammable limit (LEL): None. Upper flammable limit (UFL): None. Extinguishing media (suitable): Use extinguishing measures to suit surroundings. Protective equipment: Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear (full Bunker Gear) and self- contained breathing apparatus (pressure demand / NIOSH approved or equivalent). Fire fighting equipment should be thoroughly decontaminated after use. Further firefighting advice: Keep containers cool by spraying with water if exposed to fire. Water mist should be used to reduce vapor concentrations in air. Fire and explosion hazards: May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. Liquid and gas under pressure, overheating or overpressurizing may cause gas release and /or violent cylinder bursting. Container may explode if heated due to resulting pressure rise. Some mixtures of HCFCs and /or HFCs, and air or oxygen may be combustible if pressurized and exposed to extreme heat or flame. When burned, the following hazardous products of combustion can occur: Hydrogen fluoride hydrogen chloride 6. ACCIDENTAL RELEASE MEASURES In case of spill or leak: Use Halogen leak detector or other suitable means to locate leaks or check atmosphere. Keep upwind. Evacuate enclosed spaces and disperse gas with floor -level forced -air ventilation. Stop the leak if you can do so without risk. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 3 / 14 Material Safety Data Sheet nni -<e 1A FORANE ® 409A 7. HANDLING AND STORAGE Handling General information on handling: Avoid breathing gas. Keep container closed. Use only with adequate ventilation. Do not enter confined spaces unless adequately ventilated. Use equipment rated for cylinder pressure. Use a backflow preventative device in piping. Wash thoroughly after handling. Close valve after each use and when empty. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Storage General information on storage conditions: Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity. Storage stability — Remarks: Do not apply direct flame to cylinder. Do not store cylinder in direct sun or expose it to heat above 120 F (48.9 C.). Do not drop or refill this cylinder. Storage incompatibility — General: Keep away from oxidising agents and strongly acid or alkaline materials. Temperature tolerance — Do not store above: 118 °F (48 °C) 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Airborne Exposure Guidelines: Methane, chlorodifluoro- (75 -45 -6) US. ACGIH Threshold Limit Values Time Weighted Average (TWA): 1,000 ppm Ethane, 2- chloro- 1,1,1,2- tetrafluoro- (2837 -89 -0) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm Remarks: Listed Ethane, 1- chloro -1,1- difluoro- (75 -68 -3) US. Workplace Environmental Exposure Level (WEEL) Guides Time Weighted Average (TWA): 1,000 ppm (4,100 mg /m3) Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 4 / 14 Material Safety Data Sheet ARKe FORANE ® 409A Remarks: Listed Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions. Engineering controls: Investigate engineering techniques to reduce exposures below airborne exposure limits. Provide ventilation if necessary to control exposure levels below airborne exposure limits (see above). If practical, use local mechanical exhaust ventilation at sources of air contamination such as open process equipment. Respiratory protection: Avoid breathing gas. Where airborne exposure is likely or airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection equipment appropriate to the material and /or its components (full facepiece recommended). Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an approved full face positive - pressure, self- contained breathing apparatus or positive - pressure airline with auxiliary self - contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134. Skin protection: Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact. Consult glove manufacturer to determine appropriate type glove material for given application. Rinse immediately if skin is contaminated. Wash contaminated clothing and clean protective equipment before reuse. Wash thoroughly after handling. Eye protection: Use good industrial practice to avoid eye contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Clear - colourless Physical state: gas Form: Liquefied gas Odor: Slightly ether -like pH: not applicable Density: not determined Specific Gravity (Relative 1.21 (77 °F( 25 °C)) density): Vapor pressure: 5,388 mmHg (70.0 °F (21.1 °C)) Vapor density: 3.38 kg /m3 Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 5 / 14 Material Safety Data Sheet ARKemA FORANE ® 409A Boiling point/boiling -24 °F ( -31 °C) range: Freezing point: not determined Melting point: not determined Solubility in water: negligible % Volatiles: 100 % Molecular weight: 97.43 g /mol 10. STABILITY AND REACTIVITY Stability: This material is chemically stable under normal and anticipated storage, handling and processing conditions. Materials to avoid: Strong oxidizing agents Strong acids Alkaline materials Conditions / hazards to avoid: Heat. Hazardous decomposition products: Thermal decomposition giving toxic and corrosive products : Halogen acids (HCI and HF) Carbon monoxide Carbon dioxide (CO2) Carbonyl halides 11. TOXICOLOGICAL INFORMATION Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 approx. 780 mg /I (220000 ppm). Skin Irritation: Moderately irritating. (rabbit) (Rapid evaporation of the liquid may cause frostbite.) Eye Irritation: Slightly irritating. (rabbit) (30 s) (gas spray) Sensitization: Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 6 / 14 Material Safety Data Sheet nnIemr FORANE ® 409A Causes cardiac sensitization. (dog, rat, mouse, rabbit and monkey) irregular heart beat, rapid heart beat, in some cases, sudden death Skin Sensitization: Repeated skin exposure. (guinea pig) No skin allergy was observed. Repeated dose toxicity Repeated inhalation administration to rat, rabbit, mouse / affected organ(s): liver, lung, central nervous system / (Repeated exposure at high concentrations) Chronic oral administration to rat / No adverse effects reported. Carcinogenicity Chronic inhalation administration to mouse / No increase in tumor incidence was reported. Chronic inhalation administration to female rat / No increase in tumor incidence was reported. Chronic inhalation administration to male rat / affected organ(s): salivary gland / Increased incidence of tumors was reported. (The observed tumors do not appear to be relevant for men.) Genotoxicity Assessment in Vitro: Genetic changes were observed in laboratory tests using: bacteria No genetic changes were observed in laboratory tests using: animal cells, yeast Genotoxicitv Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals, rodent Developmental toxicity Exposure during pregnancy. inhalation (rat) / Birth defects were observed. (eye) Exposure during pregnancy. inhalation (rabbit) / No birth defects were observed. Reproductive effects Reproduction test. inhalation (rat and mouse) / No toxicity to reproduction / (males) Human experience Inhalation: Lung: Asphyxia, suffocation. Heart: Palpitation. (based on reports of occupational exposure to workers) Human experience Skin contact: Skin: irritation, redness, swelling. (repeated or prolonged exposure) Data for Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- (2837 -89 -0) Acute toxicity Inhalation: Practically nontoxic. (rat) 4 h LC50 between 1,280 - 1,670 mg /I (between 230000 - 300000 ppm). Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 7 / 14 Material Safety Data Sheet ARKe MR FORANE ®409A Signs /effects reported after acute exposure. (dog, mouse) signs: anesthetic effects Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Repeated dose toxicity Inhalation administration to rat and mouse / affected organ(s): central nervous system / signs: blood chemistry changes Carcinogenicity Chronic inhalation administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: No genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat and rabbit) / No birth defects were observed. (at doses that produce effects in mothers) Data for Ethane, 1- chloro -1,1- difluoro- (75 -68 -3) Acute toxicity Inhalation: Practically nontoxic. (rat) 6 h LC50 > 400,000 ppm. signs: respiratory irritation Eye Irritation: Slightly irritating. (rabbit) (liquid) Sensitization: Causes cardiac sensitization. Inhalation. (dog) Stress induced heart effects: irregular heart beat, rapid heart beat, in some cases, sudden death (Reaction may occur in response to stress (natural adrenaline release) or administration of epinephrine.) Carcinogenicity Chronic inhalation administration to rat / No increase in tumor incidence was reported. Genotoxicity Assessment in Vitro: Both positive and negative responses for genetic changes were observed in laboratory tests using: bacteria, animal cells Genotoxicity Assessment in Vivo: Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 8 / 14 Material Safety Data Sheet F I ARKemn FORANE ® 409A No genetic changes were observed in laboratory tests using: animals Developmental toxicity Exposure during pregnancy. inhalation (rat) / No birth defects were observed. Reproductive effects Repeated administration. Inhalation (rat, dog) / Did not cause damage to the reproductive organs. Exposure prior to mating. Inhalation (mouse) / No toxicity to reproduction / (males) 12. ECOLOGICAL INFORMATION Chemical Fate and Pathway Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Biodegradation: Not readily biodegradable. (28 d) biodegradation 0 % Octanol Water Partition Coefficient: log Pow = 1.08 (Practically no potential to bioaccumulate.) Photodegradation: Half -life direct photolysis: = 8.4 y Mobility and Distribution in the Environment: Moderate adsorption / Log Koc = 1.8 Global Warming Potential: GWP = 0.33 (Halocarbon global warming potential.) Ozone Depletion Potential: ODP = 0.055 Data for Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- (2837 -89 -0) Biodegradation: Not readily biodegradable. (28 d) biodegradation 2 - 5 % Slight potential to bioaccumulate. Octanol Water Partition Coefficient: log Pow = 1.9 - 2.0 Global Warming Potential: GWP 470 Literary reference (CO2) Ozone Depletion Potential: ODP approx. 0.02 (Ozone depletion potential; ODP; (R -11 = 1)) ODP 0.04 (Ozone depletion potential; ODP; (R -11 = 1)) Data for Ethane, 1- chloro -1,1- difluoro- (75 -68 -3) Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 9 / 14 Material Safety Data Sheet A RKEmn FORANE ® 409A Biodegradation: Not readily biodegradable. (20 d) biodegradation 5 % Practically no potential to bioaccumulate. Octanol Water Partition Coefficient: log Pow = 1.64 - 2.05 Photodegradation: Half -life direct photolysis: = 12.8 y Global Warming Potential: GWP = 0.42 (Halocarbon global warming potential.) GWP = 1,800 (CO2) Ozone Depletion Potential: ODP = 0.065 Ecotoxicology Data on this material and /or its components are summarized below. Data for Methane, chlorodifluoro- (75 -45 -6) Aquatic toxicity data: Practically nontoxic. Fish 24 h Toxicity threshold = 180 mg /I Microorganisms: Slightly toxic. under anaerobic conditions / Bacteria 24 h Toxicity threshold > 400 mg /I Data for Ethane, 1- chloro -1,1- difluoro- (75 -68 -3) Aquatic toxicity data: Practically nontoxic. Poecilia retiaculata (guppy) 96 h LC50 = 220 mg /I Aquatic invertebrates: Practically nontoxic. Daphnia magna (Water flea) 48 h EC50 >= 160 mg /I Practically nontoxic. Daphnia magna (Water flea) 48 h EC50 > 190 mg /I 13. DISPOSAL CONSIDERATIONS Waste disposal: Do not vent the container contents, or product residuals, to the atmosphere. Recover and reclaim unused contents or residuals as appropriate. Recovered /reclaimed product can be returned to an approved certified reclaimer or back to the seller depending on the material. Completely emptied disposable containers can be disposed of as recyclable steel. Returnable cylinders must be returned to seller. Dispose of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and /or hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or otherwise altering this material may make this waste management information incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or otherwise different from federal laws and regulations. Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 10 / 14 Material Safety Data Sheet / 46.°" ) RI4eMPI FORANE ® 409A 14. TRANSPORT INFORMATION US Department of Transportation (DOT) UN Number : 3163 Proper shipping name : Liquefied gas, n.o.s. Technical name : (Chlorodifluoromethane, ) Class : 2.2 Marine pollutant : no International Maritime Dangerous Goods Code (IMDG) UN Number : 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. Technical name : (CHLORODIFLUOROMETHANE, 1- CHLORO -1,1- DIFLUOROETHANE) Class : 2.2 Marine pollutant : no 15. REGULATORY INFORMATION Chemical Inventory Status EU. EINECS EINECS Conforms to US. Toxic Substances Control Act TSCA The components of this product are all on the TSCA Inventory. Australia. Industrial Chemical (Notification and AICS Conforms to Assessment) Act Canada. Canadian Environmental Protection Act DSL All components of this product are on the (CEPA). Domestic Substances List (DSL). (Can. Gaz. Canadian DSL list. Part II, Vol. 133) Japan. Kashin -Hou Law List ENCS (JP) Does not conform Korea. Toxic Chemical Control Law (TCCL) List KECI (KR) Conforms to Philippines. The Toxic Substances and Hazardous PICCS (PH) Conforms to and Nuclear Waste Control Act China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to China. Inventory of Existing Chemical Substances IECSC (CN) Conforms to New Zealand. Inventory of Chemicals (NZIoC), as NZIOC Does not conform published by ERMA New Zealand Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 11 / 14 Material Safety Data Sheet ARKemn FORANE ® 409A United States — Federal Regulations SARA Title III — Section 302 Extremely Hazardous Chemicals: The components in this product are either not SARA Section 302 regulated or regulated but present in negligible concentrations. SARA Title III - Section 311/312 Hazard Categories: Acute Health Hazard, Sudden Release of Pressure Hazard SARA Title III — Section 313 Toxic Chemicals: Chemical Name CAS -No. De minimis Reportable threshold: concentration Methane, chlorodifluoro- 75 -45 -6 1.0 % 10000 lbs (Otherwise used (non- manufacturing/processing)) 25000 lbs (Manufacturing and processing) Ethane, 1- chloro -1,1- difluoro- 75 -68 -3 1.0 % 10000 lbs (Otherwise used (non- manufacturing/processing)) 25000 lbs (Manufacturing and processing) Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 1.0 % 10000 lbs (Otherwise used (non- manufacturing/processing)) 25000 lbs (Manufacturing and processing) Ethane, 1- chloro- 1,1,2,2 - tetrafluoro- 354 -25 -6 1.0 % 10000 lbs (Otherwise used (non- manufacturing/processing)) 25000 lbs (Manufacturing and processing) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable Quantity (RQ): The components in this product are either not CERCLA regulated, regulated but present in negligible concentrations, or regulated with no assigned reportable quantity. OSHA Regulated Carcinogens (NTP, IARC, OSHA Listed): NTP: No component of this product present at levels greater than or equal to 0.1 % is identified as a known or anticipated carcinogen by NTP. Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 12 / 14 Material Safety Data Sheet :.RRKemn FORANE ® 409A IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. United States — State Regulations Massachusetts Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 Ethane, 1- chloro -1,1- difluoro- 75 -68 -3 Methane, chlorodifluoro- 75 -45 -6 Ethane, 1- chloro -1,1- difluoro- 75 -68 -3 New Jersey Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45-6 Ethane, 1- chloro -1,1- difluoro- 75 -68 -3 Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 Ethane, 1- chloro- 1,1,2,2- tetrafluoro- 354 -25 -6 Pennsylvania Right to Know Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45-6 Ethane, 1- chloro -1,1- difluoro- 75 -68 -3 Ethane, 2- chloro- 1,1,1,2 - tetrafluoro- 2837 -89 -0 Pennsylvania Right to Know — Environmentally Hazardous Substance(s) Chemical Name CAS -No. Methane, chlorodifluoro- 75 -45 -6 California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive defects. 16. OTHER INFORMATION Latest Revision(s): Revised Section(s): Initial entry Reference number: 000000057863 Date of Revision: 01/15/2009 Date Printed: 01/15/2009 Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 13 / 14 Material Safety Data Sheet r. A RK emn FORANE ® 409A FORANE ® is a registered trademark of Arkema Inc. Arkema Inc. believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of Arkema Inc., Arkema Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. • Product code: 04010 Version 1.0 Issued on: 01/15/2009 Page: 14 / 14