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ll ri< Immunology Consultants Laboratory: Tenant Improvement Date 03.29.2019 61 Job# 180275.01 4KC447CFukk Location 7150 SW Sandburg St. U ENGINEERING AFbNN,N , Tigard, OR 97223 INTFRl( , l#INUSC>.Vk HMIS SCHEDULE: STORAGE Classification Physical Hazard 0 Chemical Quantity Case# Sub-chemical % Non- -n Hazardous* Flammable Liquid 'R 1A 1B 1C 0 Carbon Dioxide, Solid 10 kg or Dry Ice 124 38 9 X 0 ill Carbon Dioxide, Gas 4,500 cf 124-38-9 X M Nitrogen, Refrigerated 20 gal B77 Liquid 7727-37-9 X n Chloroform 50 gal 67-66-3 X 0 Ethyl Alcohol 200 Proof 5.28 gal '® GR ACS 64-17-5 5.28 Ethyl Alcohol, 5.28 gal c 0 Denatured 95% 64-17-5 ethanol 90 4.75 c3-< m 67 56 1 methanol 4 z O n 0-n im 141-78-6 ethyl acetate 4 0.21 0-4 1. 108-10-1 4-methylpentan-2-one 1 0.05 Z0 cFF. ITI Total (Gal) 0 10.29 D Total Allowable (Gal) 90 360 360 ON *Non-hazardous per OSSC 2014. . Carbon Dioxide, Solid or Dry Ice an Air Liquide company Section 1. Identification GHS product identifier : Carbon Dioxide, Solid or Dry Ice Chemical name : Carbon dioxide, solid Other means of : Dry ice; carbonic anhydride identification Product type : Solid. Product use : Synthetic/Analytical chemistry. Synonym : Dry ice; carbonic anhydride SDS# : 001091 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : Not classified. Classification of the : Not classified by Globally Harmonized System of Classification and Labeling (GHS). substance or mixture GHS label elements Signal word : Warning Hazard statements : May displace oxygen and cause rapid suffocation. May increase respiration and heart rate. May cause frostbite. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable. Hazards not otherwise : Contact with cryogenic liquid can cause frostbite and cryogenic burns. classified Section 3. Composition/information on ingredients Substance/mixture : Substance Chemical name : Carbon dioxide, solid Other means of : Dry ice; carbonic anhydride identification Product code : 001091 CAS number/other identifiers CAS number : 124-38-9 Ingredient name °la CAS number Carbon Dioxide 100 124-38-9 Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 1/10 Carbon Dioxide,Solid or Dry Ice Section 3. Composition/information on ingredients There are no additional ingredients present which,within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Pescriotion of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Skin contact ; Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Most important symptoms/effects. acute and delayed Potential acute health effects Eye contact : May cause eye irritation. Inhalation : May be harmful if inhaled. May cause respiratory irritation. Skin contact ; Harmful if absorbed through the skin. May cause skin irritation. Frostbite : Try to warm up the frozen tissues and seek medical attention. Ingestion : May be harmful if swallowed and enters airways. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders ; No action shall be taken involving any personal risk or without suitable training. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinauishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media Specific hazards arising : No specific fire or explosion hazard. from the chemical Hazardous thermal ; Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 2/10 Carbon Dioxide, Solid or Dry Ice Section 5. Fire-fighting measures Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective ; Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus(SCBA)with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage,take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers,waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment(see Section 8). Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from including any direct sunlight in a dry, cool and well-ventilated area,away from incompatible materials incompatibilities (see Section 10)and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 3/10 Carbon Dioxide,Solid or Dry Ice Section 8. Exposure controls/personal protection Ingredient name Exposure limits Carbon Dioxide ACGIH TLV(United States, 3/2017). STEL: 54000 mg/m3 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 9000 mg/m3 8 hours. TWA: 5000 ppm 8 hours. NIOSH REL(United States, 10/2016). STEL: 54000 mg/m3 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 9000 mg/m3 10 hours. TWA: 5000 ppm 10 hours. OSHA PEL(United States,6/2016). TWA: 9000 mg/m3 8 hours. TWA: 5000 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). STEL: 54000 mg/m3 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 18000 mg/m3 8 hours. TWA: 10000 ppm 8 hours. Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases,fume scrubbers,filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting,training, and other important aspects of use. Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 4/10 Carbon Dioxide,Solid or Dry Ice Section 9. Physical and chemical properties Aouearance Physical state : Solid. [WHITE SNOW-LIKE SOLID] Color : White. Odor : Not available. Odor threshold : Not available. pH : Not available. Melting point : Sublimation temperature:-78.5°C(-109.3 to °F) Boiling point : Not available. Critical temperature : 31°C(87.8°F) Flash point : Not available. Evaporation rate : Not available. Flammability(solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : Not available. Vapor density : Not available. Specific Volume(ft 311b) : 0.6579 Gas Density(Ib/ft 3) : 1.52 Relative density : Density Solid (Dry Ice)97.5189 lb./ft.3 at-109.3° F Solubility : Not available. Solubility in water : Not available. Partition coefficient: n- : Not available. octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. Flow time(ISO 2431) : Not available. Molecular weight : 44.01 g/mole Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Date of issue/Dale of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 5/10 Carbon Dioxide,Solid or Dry Ice Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity(single exposure) Not available. Specific target organ toxicity(repeated exposure) Not available. Aspiration hazard( Not available. Information on the likely : Not available. routes of exposure Potential acute health effects Eye contact May cause eye irritation. Inhalation : May be harmful if inhaled. May cause respiratory irritation. Skin contact Harmful if absorbed through the skin. May cause skin irritation. Ingestion : May be harmful if swallowed and enters airways. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 6/10 Carbon Dioxide,Solid or Dry Ice Section 11. Toxicological information Not available. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Bioaccumulative potential Not available. Mobility in soil Soil/water partition : Not available. coefficient(Koc) Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains and sewers. Section 14. Transport information Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 7/10 Carbon Dioxide,Solid or Drylce Section 14. Transport information DOT TDG Mexico IMDG IATA UN number UN1845 UN1845 UN1845 UN1845 UN1845 UN proper CARBON CARBON CARBON CARBON CARBON shipping name DIOXIDE, SOLID DIOXIDE, SOLID; DIOXIDE, SOLID DIOXIDE, SOLID DIOXIDE, SOLID OR DRY ICE OR DRY ICE OR DRY ICE (DRY ICE) Transport 9 9 9 9 9 hazard class(es) Packing group - - - - - Environmental No. No. No. No. No. hazards "Refer to CFR 49 (or authority having jurisdiction)to determine the information required for shipment of the product." Additional information DOT Classification : Limited quantity Yes. Quantity limitation Passenger aircraft/rail: 200 kg. Cargo aircraft: 200 kg. TDG Classification : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.43-2.45 (Class 9). Explosive Limit and Limited Quantity Index 5 Passenger Carrying Ship Index 200 Suecial provisions 18 IATA : Quantity limitation Passenger and Cargo Aircraft: 200 kg. Cargo Aircraft Only: 200 kg. Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according : Not available. to Annex II of MARPOL and the IBC Code Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted. Clean Air Act Section 112 : Not listed (b) Hazardous Air Pollutants(HAPs) Clean Air Act Section 602 : Not listed Class I Substances Clean Air Act Section 602 : Not listed Class II Substances DEA List I Chemicals : Not listed (Precursor Chemicals) DEA List II Chemicals : Not listed (Essential Chemicals) SARA 302/304 Composition/information on ingredients No products were found. Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 8/10 Carbon Dioxide,Solid or Dry Ice Section 15. Regulatory information SARA 304 RQ : Not applicable. SARA 311/31 Z Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance. State regulations Massachusetts : This material is listed. New York : This material is not listed. New Jersey : This material is listed. Pennsylvania : This material is listed. International regulations Chemical Weapon Convention List Schedules I. II & Ill Chemicals Not listed. Montreal Protocol (Annexes A. B. C. E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent(PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Inventory list Australia : This material is listed or exempted. Canada : This material is listed or exempted. China : This material is listed or exempted. Europe : This material is listed or exempted. Japan : Japan inventory(ENCS):This material is listed or exempted. Japan inventory(ISHL):This material is listed or exempted. Malaysia : Not determined. New Zealand : This material is listed or exempted. Philippines : This material is listed or exempted. Republic of Korea : This material is listed or exempted. Taiwan : This material is listed or exempted. Thailand : Not determined. Turkey : This material is listed or exempted. United States : This material is listed or exempted. Viet Nam : Not determined. Section 16. Other information Hazardous Material Information System (U.S.A.) / 3 Flammability 0 ' e 0 Caution: HMIS®ratings are based on a 0-4 rating scale,with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks.Although HMIS®ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200,the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®program. HMIS®is a registered trademark and service mark of the American Coatings Association, Inc. Date of issue/Date of revision : 11/10/2018 Date of previous issue :6/26/2018 Version :1 9/10 Carbon Dioxide,Solid or Dry Ice Section 16. Other information The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment(PPE)codes, consult the HMIS®Implementation Manual. National Fire Protection Association (U.S.A.1 Flammability Health 160 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright©1997, National Fire Protection Association, Quincy, MA 02269.This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright©2001, National Fire Protection Association, Quincy, MA 02269.This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,which would be used as a guideline only.Whether the chemicals are classified by NFPA or not,anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification Not classified. History Date of printing : 11/10/2018 Date of issue/Date of : 11/10/2018 revision Date of previous issue : 6/26/2018 Version : 1 Key to abbreviations : ATE =Acute Toxicity Estimate BCF = Bioconcentration Factor GHS= Globally Harmonized System of Classification and Labelling of Chemicals IATA= International Air Transport Association IBC= Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow= logarithm of the octanol/water partition coefficient MARPOL= International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations References : Not available. Notice to reader To the best of our knowledge,the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision :11/10/2018 Date of previous issue :6/26/2018 Version :1 10/10 Carbon Dioxide an Air Liquide company Section 1. Identification GHS product identifier : Carbon Dioxide Chemical name : Carbon dioxide, gas Other means of : Carbonic, Carbon Dioxide, Carbonic Anhydride, R744, Carbon Dioxide USP identification Product type : Gas. Product use : Synthetic/Analytical chemistry and Medical use. Synonym : Carbonic, Carbon Dioxide, Carbonic Anhydride, R744, Carbon Dioxide USP SDS# : 001013 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : GASES UNDER PRESSURE- Liquefied gas substance or mixture Simple asphyxiant. GHS label elements Hazard pictograms .• Signal word : Warning Hazard statements : Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. May increase respiration and heart rate. Precautionary statements General : Read and follow all Safety Data Sheets (SDS'S)before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Always keep container in upright position. Prevention : Use and store only outdoors or in a well ventilated place. Response : Not applicable. Storage : Protect from sunlight. Store in a well-ventilated place. Disposal : Not applicable. Hazards not otherwise : In addition to any other important health or physical hazards,this product may displace classified oxygen and cause rapid suffocation. May cause frostbite. • Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 1/11 Carbon Dioxide Section 3. Composition/information on ingredients Substance/mixture : Substance Chemical name : Carbon dioxide, gas Other means of : Carbonic, Carbon Dioxide, Carbonic Anhydride, R744, Carbon Dioxide USP identification Product code : 001013 CAS number/other identifiers CAS number : 124-38-9 Ingredient name % CAS number Carbon Dioxide 100 124-38-9 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which,within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : As this product is a gas, refer to the inhalation section. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Frostbite : Try to warm up the frozen tissues and seek medical attention. Ingestion : As this product is a gas, refer to the inhalation section. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version 7 0.03 2/11 Carbon Dioxide Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media Specific hazards arising : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and from the chemical the container may burst or explode. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus(SCBA)with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions. protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage,take note of any information in Section 8 on suitable and unsuitable materials. See also the information in"For non- emergency personnel". Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers,waterways, soil or air). Methods and materials for containment and cleaning uo Small spill : Immediately contact emergency personnel. Stop leak if without risk. Large spill : Immediately contact emergency personnel. Stop leak if without risk. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment(see Section 8). Contains gas under pressure. Avoid breathing gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Avoid contact with eyes, skin and clothing. Empty containers retain product residue and can be hazardous. Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 3/11 Carbon Dioxide Section 7. Handling and storage Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area. including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatibilities incompatible materials (see Section 10). Cylinders should be stored upright,with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52°C (125 °F). Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Carbon Dioxide ACGIH TLV(United States, 3/2017). Oxygen Depletion [Asphyxiant]. STEL: 54000 mg/m3 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 9000 mg/m3 8 hours. TWA: 5000 ppm 8 hours. NIOSH REL(United States, 10/2016). STEL: 54000 mg/m3 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 9000 mg/m3 10 hours. TWA: 5000 ppm 10 hours. OSHA PEL(United States, 6/2016). TWA: 9000 mg/m3 8 hours. TWA: 5000 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). STEL: 54000 mg/m3 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 18000 mg/m3 8 hours. TWA: 10000 ppm 8 hours. Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases,fume scrubbers,filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 4/11 Carbon Dioxide Section 8. Exposure controls/personal protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting,training, and other important aspects of use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : Gas. [Compressed gas.] Color : Colorless. Odor : Odorless. Odor threshold : Not available. pH : Not available. Melting point : Sublimation temperature: -79°C(-110.2 to°F) Boiling point : Not available. Critical temperature : 30.85°C (87.5°F) Flash point : [Product does not sustain combustion.] Evaporation rate : Not available. Flammability(solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : 830 (psig) Vapor density : 1.53 (Air= 1) Liquid Density@BP: Solid density= 97.5 lb/ft3 (1562 kg/m3) Specific Volume(ft 3/Ib) : 8.7719 Gas Density(lb/ft') : 0.114 Relative density : Not applicable. Solubility : Not available. Solubility in water : Not available. Partition coefficient: n- : 0.83 octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not applicable. Flow time (ISO 2431) : Not available. Molecular weight : 44.01 g/mole Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 5/11 Carbon Dioxide Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Incompatible materials : No specific data. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratoaenicity Not available. Specific target organ toxicity(single exposurel Not available. Specific target organ toxicity(repeated exposurel Not available. Aspiration hazard Not available. Information on the likely : Not available. routes of exposure Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 6/11 Carbon Dioxide Section 11. Toxicological information Ingestion : As this product is a gas, refer to the inhalation section. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Not available. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Bioaccumulative potential Product/ingredient name LogPow BCF Potential Carbon Dioxide 0.83 - low Mobility in soil Soil/water partition : Not available. coefficient (Koc) Other adverse effects : No known significant effects or critical hazards. Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 7/11 Carbon Dioxide Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Section 14. Transport information DOT TDG Mexico IMDG IATA UN number UN1013 UN1013 UN1013 UN1013 UN1013 UN proper CARBON CARBON CARBON CARBON CARBON shipping name DIOXIDE DIOXIDE DIOXIDE DIOXIDE DIOXIDE Transport 2.2 2.2 2.2 2.2 2.2 hazard class(es) Packing group - Environmental No. No. No. No. No. hazards "Refer to CFR 49 (or authority having jurisdiction)to determine the information required for shipment of the product." Additional information DOT Classification : Limited auantity Yes. Quantity limitation Passenger aircraft/rail: 75 kg. Cargo aircraft: 150 kg. TDG Classification : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). Explosive Limit and Limited Quantity Index 0.125 Passenger Carrvina Road or Rail Index 75 IATA : Quantity limitation Passenger and Cargo Aircraft: 75 kg. Cargo Aircraft Only: 150 kg. Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according : Not available. to Annex II of MARPOL and the IBC Code Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted. Clean Air Act Section 112 : Not listed (b) Hazardous Air Pollutants (HAPs) Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 8/11 Carbon Dioxide Section 15. Regulatory information Clean Air Act Section 602 : Not listed Class I Substances Clean Air Act Section 602 : Not listed Class II Substances DEA List I Chemicals : Not listed (Precursor Chemicals) DEA List II Chemicals : Not listed (Essential Chemicals) SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance. State regulations Massachusetts : This material is listed. New York : This material is not listed. New Jersey : This material is listed. Pennsylvania : This material is listed. International regulations Chemical Weapon Convention List Schedules I, II & Ill Chemicals Not listed. Montreal Protocol (Annexes A. B.C. El Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent(PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Inventory list Australia : This material is listed or exempted. Canada : This material is listed or exempted. China : This material is listed or exempted. Europe : This material is listed or exempted. Japan : Japan inventory(ENCS):This material is listed or exempted. Japan inventory(ISHL):This material is listed or exempted. Malaysia : Not determined. New Zealand : This material is listed or exempted. Philippines : This material is listed or exempted. 1 Republic of Korea : This material is listed or exempted. Taiwan : This material is listed or exempted. Thailand : Not determined. Turkey : This material is listed or exempted. United States : This material is listed or exempted. Viet Nam : Not determined. Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 9/11 Carbon Dioxide Section 16. Other information Hazardous Material Information System (U.S.A.) / 1 Flammability 0 Physic&hazards 3 Caution: HMIS®ratings are based on a 0-4 rating scale,with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks.Although HMIS®ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200,the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®program. HMIS®is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment(PPE)codes, consult the HMIS®Implementation Manual. National Fire Protection Association (U.S.A.1 Flammability Health Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright©1997, National Fire Protection Association, Quincy, MA 02269.This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright©2001, National Fire Protection Association, Quincy, MA 02269.This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,which would be used as a guideline only.Whether the chemicals are classified by NFPA or not,anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification GASES UNDER PRESSURE- Liquefied gas Expert judgment History Date of printing : 2/12/2018 Date of issue/Date of : 2/12/2018 revision Date of previous issue : 4/25/2017 Version : 0.03 Key to abbreviations : ATE=Acute Toxicity Estimate BCF= Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA= International Air Transport Association IBC= Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow=logarithm of the octanol/water partition coefficient MARPOL= International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol"= marine pollution) UN = United Nations References : Not available. Notice to reader Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 10/11 Carbon Dioxide Section 16. Other information To the best of our knowledge,the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision :2/12/2018 Date of previous issue :4/25/2017 Version :0.03 11/11 an Air Liquide company Nitrogen, Refrigerated Liquid Section 1. Identification GHS product identifier : Nitrogen, Refrigerated Liquid Chemical name : NITROGEN, REFRIGERATED LIQUID Other means of : LIN, Cryogenic Liquid Nitrogen, Liquid Nitrogen, Liquid Nitrogen NF, Liquid Nitrogen FG identification Product type : Liquefied gas Product use : Synthetic/Analytical chemistry. Synonym : LIN, Cryogenic Liquid Nitrogen, Liquid Nitrogen, Liquid Nitrogen NF, Liquid Nitrogen FG SDS# : 001188 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : GASES UNDER PRESSURE- Refrigerated liquefied gas substance or mixture GI-IS label elements Hazard pictograms • Signal word : Warning Hazard statements : Contains refrigerated gas; may cause cryogenic burns or injury. May cause frostbite. May displace oxygen and cause rapid suffocation. Precautionary statements General : Read and follow all Safety Data Sheets(SDS'S)before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Always keep container in upright position. Do not change or force fit connections. Avoid spills. Do not walk or roll equipment over spills. Prevention : Wear cold insulating gloves and face shield. Use and store only outdoors or in a well ventilated place. Response : Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention. Storage : Store in a well-ventilated place. Disposal : Not applicable. Hazards not otherwise : Liquid can cause burns similar to frostbite. classified Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 1/11 Nitrogen,Refrigerated Liquid Section 3. Composition/information on ingredients Substance/mixture : Substance Chemical name : NITROGEN, REFRIGERATED LIQUID Other means of : LIN, Cryogenic Liquid Nitrogen, Liquid Nitrogen, Liquid Nitrogen NF, Liquid Nitrogen FG identification Product code : 001188 CAS number/other identifiers CAS number : 7727-37-9 Ingredient name % CAS number NITROGEN, REFRIGERATED LIQUID 100 7727-37-9 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available,are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. In case of contact with liquid,warm frozen tissues slowly with lukewarm water and get medical attention. Do not rub affected area. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if adverse health effects persist or are severe. Ingestion of liquid can cause burns similar to frostbite. If frostbite occurs, get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,tie, belt or waistband. As this product rapidly becomes a gas when released, refer to the inhalation section. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Extremely cold material. Liquid can cause burns similar to frostbite. Inhalation : No known significant effects or critical hazards. Skin contact : Extremely cold material. Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. Frostbite : Try to warm up the frozen tissues and seek medical attention. Ingestion : Ingestion of liquid can cause burns similar to frostbite. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following:,frostbite Inhalation : No specific data. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 2/11 Nitrogen,Refrigerated Liquid Section 4. First aid measures Skin contact : Adverse symptoms may include the following:,frostbite Ingestion : Adverse symptoms may include the following:,frostbite Indication of immediate medical attention and special treatment needed. if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-alders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media Specific hazards arising : Contains gas under pressure. Contains refrigerated gas. In a fire or if heated, a from the chemical pressure increase will occur and the container may burst or explode. Hazardous thermal : Decomposition products may include the following materials: decomposition products nitrogen oxides Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus(SCBA)with a full face-piece operated in positive pressure mode. For incidents involving large quantities, thermally insulated undergarments and thick textile or leather gloves should be worn. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage,take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,soil or air). Methods and materials for containment and cleaning uo Small spill : Immediately contact emergency personnel. Stop leak if without risk. Large spill : Immediately contact emergency personnel. Stop leak if without risk. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 3/11 Nitrogen,Refrigerated Liquid Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment(see Section 8). Contains gas under pressure. Contains refrigerated gas. Do not get in eyes or on skin or clothing. Avoid breathing gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Never allow any unprotected part of the body to touch uninsulated pipes or vessels that contain cryogenic liquids. Prevent entrapment of liquid in closed systems or piping without pressure relief devices. Some materials may become brittle at low temperatures and will easily fracture. Empty containers retain product residue and can be hazardous. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area. including any Store in a dry, cool and well-ventilated area, away from incompatible materials(see incompatibilities Section 10). Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits NITROGEN, REFRIGERATED LIQUID None. Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. If contact with the liquid is possible, insulated gloves suitable for low temperatures should be worn. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 4/11 Nitrogen,Refrigerated Liquid Section 8. Exposure controls/personal protection Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting,training, and other important aspects of use. Thermal hazards : If there is a risk of contact with the liquid, all protective equipment worn should be suitable for use with extremely low temperature materials. Section 9. Physical and chemical properties Appearance Physical state : Liquid. [Cryogenic liquid] Color : Colorless. Odor : Odorless. Odor threshold : Not available. pH : Not available. Melting point : -210°C (-346°F) Boiling point : -195.8 °C Critical temperature : -146.95°C(-232.5°F) Flash point : Not applicable. Evaporation rate : Not available. Flammability(solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure : Not available. Vapor density : 0.967 (Air= 1) Liquid Density@BP: 50.46 Ibfft3(808.3 kg/m3) Specific Volume(ft'Ilb) : 13.8889 Gas Density(lb/ft') : 0.072 Relative density : Not available. Solubility : Not available. Solubility in water : 0.023 g/I Partition coefficient: n- : 0.67 octanol/water Auto-ignition temperature : Not available. Decomposition temperature : Not available. Viscosity : Not available. Flow time(ISO 2431) : Not available. Molecular weight : 28.01 g/mole Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : No specific data. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 5/11 Nitrogen,Refrigerated Liquid Section 10. Stability and reactivity Incompatible materials : No specific data. Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratoaenicity Not available. Specific target organ toxicity(single exi osurel Not available. Specific target organ toxicity (repeated exposure Not available. Aspiration hazard Not available. Information on the likely : Not available. routes of exposure Potential acute health effects Eye contact : Extremely cold material. Liquid can cause burns similar to frostbite. Inhalation : No known significant effects or critical hazards. Skin contact : Extremely cold material. Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. Ingestion : Ingestion of liquid can cause bums similar to frostbite. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following:,frostbite Inhalation : No specific data. Skin contact : Adverse symptoms may include the following:, frostbite Ingestion : Adverse symptoms may include the following:, frostbite Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 6/11 Nitrogen,Refrigerated Liquid Section 11 . Toxicological information Delayed and immediate effects and also chronic effects from short and Iona term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Not available. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Section 12. Ecological information Toxicity Not available. Persistence and degradability Not available. Bioaccumulative potential Product/ingredient name LogP„. BCF Potential NITROGEN, 0.67 - low REFRIGERATED LIQUID Mobility in soil Soil/water partition : Not available. coefficient(Koc) Other adverse effects : No known significant effects or critical hazards. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 7/11 Nitrogen,Refrigerated Liquid Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Section 14. Transport information DOT TOG Mexico IMDG IATA UN number UN1977 UN1977 UN1977 UN1977 UN1977 UN proper NITROGEN, NITROGEN, NITROGEN, NITROGEN, NITROGEN, shipping name REFRIGERATED REFRIGERATED REFRIGERATED REFRIGERATED REFRIGERATED LIQUID LIQUID LIQUID LIQUID LIQUID Transport 2.2 2.2 2.2 2.2 2.2 hazard class(es) 9 Packing group - - - - - Environmental No. No. No. No. No. hazards "Refer to CFR 49 (or authority having jurisdiction)to determine the information required for shipment of the product." Additional information DOT Classification : Limited quantity Yes. Quantity limitation Passenger aircraft/rail: 75 kg. Cargo aircraft: 150 kg. TOG Classification : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17(Class 2). Explosive Limit and Limited Quantity Index 0.125 Passenger Carrying Road or Rail Index 75 IATA : Passenger and Cargo AircraftQuantity limitation: 50 kg Cargo Aircraft OnlyQuantity limitation: 500 kg Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according : Not available. to Annex I1 of MARPOL and the IBC Code Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 8/11 Nitrogen,Refrigerated Liquid Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a)CDR Exempt/Partial exemption: This material is listed or exempted. Clean Air Act Section 112 : Not listed (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 : Not listed Class I Substances Clean Air Act Section 602 : Not listed Class II Substances DEA List I Chemicals : Not listed (Precursor Chemicals) DEA List II Chemicals : Not listed (Essential Chemicals) SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance. State regulations Massachusetts : This material is listed. New York : This material is riot listed. New Jersey : This material is listed. Pennsylvania : This material is listed. International regulations Chemical Weapon Convention List Schedules I, II &Ill Chemicals Not listed. Montreal Protocol (Annexes A. B.C. E1 Not listed. Stockholm Convention on Persistent Oroanic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent(PIC) Not listed. UNECE Aarhus Protocol on POPS and Heavy Metals Not listed. Inventory list Australia : This material is listed or exempted. Canada : This material is listed or exempted. China : This material is listed or exempted. Europe : This material is listed or exempted. Japan : Japan inventory(ENCS): Not determined. Japan inventory(ISHL): Not determined. Malaysia : Not determined. New Zealand : This material is listed or exempted. Philippines : This material is listed or exempted. Republic of Korea : This material is listed or exempted. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 9/11 Nitrogen,Refrigerated Liquid Section 15. Regulatory information Taiwan : Not determined. Thailand : Not determined. Turkey : Not determined. United States : This material is listed or exempted. Viet Nam : Not determined. Section 16. Other information Hazardous Material Information System (U.S.A.' / 3 Flammability 0 r,,,px77.1 max, 0 Caution: HMIS®ratings are based on a 0-4 rating scale,with 0 representing minimal hazards or risks,and 4 representing significant hazards or risks.Although HMIS®ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200,the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®program. HMIS®is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment(PPE)codes, consult the HMIS®Implementation Manual. National Fire Protection Association (U.S.A.) Flammability Health Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright©1997, National Fire Protection Association, Quincy, MA 02269.This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright©2001, National Fire Protection Association, Quincy, MA 02269.This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,which would be used as a guideline only.Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification GASES UNDER PRESSURE- Refrigerated liquefied gas Expert judgment History Date of printing : 7/16/2018 Date of issue/Date of : 7/16/2018 revision Date of previous issue : 1/30/2018 Version : 1 Key to abbreviations : ATE =Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA= International Air Transport Association IBC= Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow= logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) Date of issue/Date of revision :7/16/2018 Date of previous issue .1/30/2018 Version :1 10/11 Nitrogen,Refrigerated Liquid Section 16. Other information UN = United Nations References : Not available. Notice to reader To the best of our knowledge,the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision :7/16/2018 Date of previous issue :1/30/2018 Version :1 11/11 SAFETY DATA SHEET V ' R ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Chloroform MSDS Number : 000000011712 Product Use Description : Solvent Manufactured for VWR International LLC Radnor Corporate Center Building One Suite 200 100 Matsonford Road Radnor PA 19087 For more information call : (Monday-Friday,8.00am-5:00pm) 1-800-932-5000 In case of emergency call : (24 hours/day, 7 days/week) 1-800-424-9300(USA Only) For Transportation Emergencies: 1-800-424-9300 (CHEMTREC - Domestic) 1-613-996-6666 (CANUTEC- Canada) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form : liquid, clear Color : colourless Odor : sweet Page 1 / 16 SAFETY DATA SHEET VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Classification of the substance or mixture Classification of the substance : Acute toxicity, Category 4, Oral or mixture Skin irritation, Category 2 Eye irritation, Category 2A Carcinogenicity, Category 2 Reproductive toxicity, Category 2 Specific target organ toxicity-single exposure, Category 1, Liver, Kidney, Central nervous system Specific target organ toxicity- repeated exposure, Category 1 GHS Label elements, including precautionary statements Symbol(s) 'r . Signal word : Danger Hazard statements : Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Precautionary statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/eye protection/face protection. Response: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Page2/ 16 SAFETY DATA SHEET r VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 IF ON SKIN:Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed: Call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with local, state & federal regulations. Carcinogenicity NTP: Chloroform 67-66-3 Reasonably Anticipated to be a Human Carcinogen. !ARC: Chloroform 67-66-3 Group 2B: Possibly carcinogenic to humans ACGIH: Chloroform 67-66-3 A3: Confirmed animal carcinogen SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula : CHCI3 Chemical nature : Substance Chemical Name CAS-No. Concentration Chloroform 67-66-3 100.00 Page 3/ 16 SAFETY DATA SHEET VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 SECTION 4. FIRST AID MEASURES Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Use oxygen as required, provided a qualified operator is present. Call a physician. Skin contact : Wash off immediately with plenty of water for at least 15 minutes.Take off contaminated clothing and shoes immediately. Wash contaminated clothing before re-use. Call a physician. Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician. Ingestion : Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Call a physician. Notes to physician Treatment : Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Dry chemical Carbon dioxide (CO2) Foam Cool closed containers exposed to fire with water spray. Specific hazards during : The product is not flammable. firefighting Exposure to decomposition products may be a hazard to health. In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen chloride (NCI). Phosgene Chlorine (Cl2) Carbon monoxide Page4/ 16 SAFETY DATA SHEET VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Carbon dioxide (CO2) Special protective equipment : Wear self-contained breathing apparatus and protective suit. for firefighters Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wear personal protective equipment. Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Isolate the affected area. Confine entry into the affected area to those persons properly protected (see Section 8 of MSDS). Ensure adequate ventilation. Avoid accumulation of vapours in low areas. Remove all sources of ignition. Do not swallow. Avoid breathing vapours, mist or gas. Avoid contact with skin, eyes and clothing. Environmental precautions : Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Do not flush into surface water or sanitary sewer system. Do not allow run-off from fire fighting to enter drains or water courses. Methods for cleaning up : Ventilate the area. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Shovel into suitable container for disposal. Dispose of absorbed material in accordance with the regulations. Page 5/ 16 SAFETY DATA SHEET U r VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 SECTION 7. HANDLING AND STORAGE Handling Handling : Wear personal protective equipment. Use only in well-ventilated areas. Keep container tightly closed. Do not smoke. Do not swallow. Avoid breathing vapours, mist or gas. Avoid contact with skin, eyes and clothing. Advice on protection against : The product is not flammable. fire and explosion Normal measures for preventive fire protection. Keep product and empty container away from heat and sources of ignition. Fire or intense heat may cause violent rupture of packages. Container hazardous when empty. Storage Requirements for storage : Keep containers tightly closed in a dry, cool and well-ventilated areas and containers place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep away from heat and sources of ignition. Keep away from direct sunlight. Protect from physical damage. Store away from incompatible substances. Container hazardous when empty. Do not pressurize, cut,weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective measures : Ensure that eyewash stations and safety showers are close to the workstation location. Page 6/16 SAFETY DATA SHEET VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Engineering measures : Use with local exhaust ventilation. Prevent vapour buildup by providing adequate ventilation during and after use. Eye protection : Do not wear contact lenses. Wear as appropriate: Safety glasses with side-shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes Hand protection : Solvent-resistant gloves Gloves must be inspected prior to use. Replace when worn. Skin and body protection : Wear as appropriate: Solvent-resistant apron Solvent-resistant gloves If splashes are likely to occur, wear: Protective suit Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator. For rescue and maintenance work in storage tanks use self-contained breathing apparatus. Use NIOSH approved respiratory protection. Hygiene measures : When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Keep working clothes separately. Remove and wash contaminated clothing before re-use. Do not swallow. Avoid breathing vapours, mist or gas. Avoid contact with skin, eyes and clothing. This material has an established AIHA ERPG exposure limit. The current list of ERPG exposure limits can be found at http://www.aiha.org/insideaiha/GuidelineDevelopment/ERPG/D ocuments/2011 erpgweelhandbook_table-only.pdf. Exposure Guidelines Components CAS-No. Value Control Upda Basis Page 7/ 16 SAFETY DATA SHEET � Y p t r Ja 9 VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 parameters to Chloroform 67-66-3 TWA : (10 ppm) 2008 ACGIH US. ACGIH time Threshold Limit weighted Values average Chloroform 67-66-3 STEL : 9.78 mg/m3 2005 NIOSH/GUIDE:US. Short (2 ppm) NIOSH: Pocket term Guide to Chemical exposure Hazards limit Chloroform 67-66-3 Ceiling : 240 mg/m3 02 OSHA_TRANS:US. Ceiling (50 ppm) 2006 OSHA Table Z-1 Limit Limits for Air Value: Contaminants (29 CFR 1910.1000) Chloroform 67-66-3 TWA : 9.78 mg/m3 1989 Z1A:US. OSHA time (2 ppm) Table Z-1-A (29 weighted CFR 1910.1000) average SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid, clear Color : colourless Odor : sweet pH : Note: Not applicable Melting point/freezing point : -64 °C Boiling point/boiling range : 62 °C Page 8/ 16 SAFETY DATA SHEET t VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Flash point : Note: does not flash Evaporation rate : 0.6 Method: Compared to Ether (anhydrous). Lower explosion limit : Note: Not applicable Upper explosion limit : Note: Not applicable Vapor pressure : 212 hPa at 20 °C(68 °F) Vapor density : 4.12 Note: (Air= 1.0) • Density : 1.49 g/cm3 at 20 °C Water solubility : 8 g/I at 20 °C Ignition temperature : > 1,000 °C Molecular weight : 119.37 g/mol SECTION 10. STABILITY AND REACTIVITY Chemical stability : Stable under recommended storage conditions. Page 9/ 16 SAFETY DATA SHEET " VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Possibility of hazardous : Hazardous polymerisation does not occur. reactions Conditions to avoid : Heat, flames and sparks. Protect from heat/overheating. Keep away from direct sunlight. Incompatible materials to : Metals avoid Aluminium Magnesium Strong bases Strong oxidizing agents May attack many plastics, rubbers and coatings. Hazardous decomposition : Gaseous hydrogen chloride (NCI). products Phosgene Chlorine (Cl2) Carbon monoxide Carbon dioxide (CO2) SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50: 908 mg/kg Species: Rat Acute inhalation toxicity : LC50: 47.7 mg/I Exposure time: 4 h Species: Rat Acute dermal toxicity : LD50: 20 g/kg Species: Rabbit Skin irritation : Species: Rabbit Result: Mild skin irritation Exposure time: 24 h Page 10/ 16 SAFETY DATA SHEET BDH VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Eye irritation : Species: Rabbit Result: Moderate eye irritation Exposure time: 24 h Repeated dose toxicity : Species: Rat Application Route: Inhalation Note: (50 ppm;7 hours/day, 5 days/week for 6 months) Causes damage to the following organs: liver, kidneys. : Species: Rat, male Application Route: Oral gavage bioassay Note: Carcinogenicity (70 g/kg for 78 weeks) Kidney tumors : Species: Mouse, both male and female Application Route: Oral gavage bioassay Note: Carcinogenicity (127 g/kg for 92 weeks) Liver tumors : Species: Rat, male Application Route: Drinking Water Study Note: Carcinogenicity (160 mg/kg/d for 104 days) Kidney tumors : Species: Rat Application Route: Inhalation Note: Embryotoxicity at maternally toxic concentrations. Species: Rat Application Route: Inhalation Note: Teratogenicity at maternally toxic concentrations. Further information : Note: Contains material which may cause cancer based on animal data. SECTION 12. ECOLOGICAL INFORMATION Page 11 / 16 SAFETY DATA SHEET • VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Ecotoxicity effects Toxicity to fish : static test LC50: 43.8 mg/I Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) : static test LC50: 100 mg/I Exposure time: 96 h Species: Lepomis macrochirus (Bluegill sunfish) Toxicity to daphnia and other : static test aquatic invertebrates LC50: 28.9 mg/I Exposure time: 48 h Species: Daphnia magna (Water flea) Toxicity to algae : LCO: 185 mg/I Species: Microcystis aeruginosa (blue alge) : LCO: 1,110 mg/I Species: Scenedesmus quadricauda (Green algae) Toxicity to bacteria : LCO: 125 mg/I Species: Pseudomonas putida Further information on ecology SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods : Dispose of contents/container in accordance with local, state, and federal regulations. Contaminated packaging Empty remaining contents.Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 12/ 16 SAFETY DATA SHEET VWR NLYT I ° L Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 SECTION 14. TRANSPORT INFORMATION DOT UN/ID No. : UN 1888 Proper shipping name : CHLOROFORM Class 6.1 Packing group III Hazard Labels 6.1 IATA UN/ID No. : UN 1888 Description of the goods : CHLOROFORM Class : 6.1 Packaging group : III Hazard Labels : 6.1 Packing instruction (cargo : 680 aircraft) Packing instruction : 680 (passenger aircraft) Packing instruction : Y680 (passenger aircraft) IMDG UN/ID No. : UN 1888 Description of the goods : CHLOROFORM Class : 6.1 Packaging group : III Hazard Labels : 6.1 EmS Number : F-A, S-A Marine pollutant : no SECTION 15. REGULATORY INFORMATION Inventories US. Toxic Substances : On TSCA Inventory Control Act Australia. Industrial : On the inventory, or in compliance with the inventory Chemical (Notification and Assessment) Act Page 13/16 SAFETY DATA SHEET I VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 Canada. Canadian : All components of this product are on the Canadian DSL. Environmental Protection Act (CEPA). Domestic Substances List (DSL) Japan. Kashin-Hou Law List : On the inventory, or in compliance with the inventory Korea. Toxic Chemical : On the inventory, or in compliance with the inventory Control Law (TCCL) List Philippines. The Toxic : On the inventory, or in compliance with the inventory Substances and Hazardous and Nuclear Waste Control Act China. Inventory of Existing : On the inventory, or in compliance with the inventory Chemical Substances New Zealand. Inventory of : On the inventory, or in compliance with the inventory Chemicals (NZIoC), as published by ERMA New Zealand National regulatory information • US. EPA CERCLA : The following component(s) of this product is/are subject to Hazardous Substances (40 release reporting under 40 CFR 302 when release exceeds the CFR 302) Reportable Quantity (RQ): Reportable quantity: 10 lbs : Chloroform 67-66-3 SARA 302 Components : The following components are subject to reporting levels established by SARA Title III, Section 302: : Chloroform 67-66-3 SARA 313 Components : The following components are subject to reporting levels established by SARA Title III, Section 313: Page 14/ 16 SAFETY DATA SHEET WR A � . Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 : Chloroform 67-66-3 SARA 311/312 Hazards : Acute Health Hazard Chronic Health Hazard CERCLA Reportable : 10 lbs Quantity California Prop. 65 : WARNING!This product contains a chemical known to the State of California to cause cancer. Chloroform 67-66-3 : WARNING:This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Chloroform 67-66-3 Massachusetts RTK : Chloroform 67-66-3 New Jersey RTK : Chloroform 67-66-3 Pennsylvania RTK : Chloroform 67-66-3 WHMIS Classification : D1 B: Toxic Material Causing Immediate and Serious Toxic Effects D2A: Very Toxic Material Causing Other Toxic Effects D2B: Toxic Material Causing Other Toxic Effects This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. Page 15/ 16 SAFETY DATA SHEET VWR ANALYTICAL Chloroform BDH1109 Version 1.4 Revision Date 03/25/2015 Print Date 05/08/2015 SECTION 16. OTHER INFORMATION HMIS III NFPA Health hazard : 2* 2 Flammability : 0 0 Physical Hazard : 0 Instability 0 - Chronic health hazard Hazard rating and rating systems (e.g. HMIS®III, NFPA):This information is intended solely for the use of individuals trained in the particular system. Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties. Changes since the last version are highlighted in the margin. This version replaces all previous versions. Previous Issue Date 06/19/2012 Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group Page16/ 16 SAFETY DATA SHEET 'ril according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Revision Date 04/30/2014 Version 1.1 SECTION 1.Identification Product identifier Product number EX0276 Product name Ethyl Alcohol 200 Proof GR ACS Synonyms EtOH CAS-No. 64-17-5 Relevant identified uses of the substance or mixture and uses advised against Identified uses Reagent for analysis Details of the supplier of the safety data sheet Company EMD Millipore Corporation i 290 Concord Road, Billerica, MA 01821, United States of America I General Inquiries: +1-978-715-4321 Monday to Friday, 9:00 AM to 4:00 PM Eastern Time (GMT-5) Emergency telephone 800-424-9300 CHEMTREC (USA) +1-703-527-3887 CHEMTREC (International) 24 Hours/day; 7 Days/week SECTION 2. Hazards identification GHS Classification Flammable liquid, Category 2, H225 For the full text of the H-Statements mentioned in this Section, see Section 16. GHS-Labeling Hazard pictograms Signal Word Danger Hazard Statements H225 Highly flammable liquid and vapor. Precautionary Statements Page 1 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P403 + P235 Store in a well-ventilated place. Keep cool. OSHA Hazards This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This information is based on 29 CFR 1910.1200 criteria prior to adoption of the GHS and may deviate from the GHS information. Other hazards None known. SECTION 3. Composition/information on ingredients Formula C2H5OH C2H6O (Hill) Synonyms EtOH Molar mass 46.07 g/mol Hazardous ingredients Chemical Name(Concentration) CAS-No. ethanol(>=90 % - <= 100 %) 64-17-5 Exact percentages are being withheld as a trade secret. SECTION 4. First aid measures Description of first-aid measures Inhalation After inhalation: fresh air. Skin contact After skin contact: wash off with plenty of water. Remove contaminated clothing. Eye contact After eye contact: rinse out with plenty of water with the eyelid held wide open. Call in ophthalmologist if necessary. Ingestion After swallowing: immediately make victim drink water(two glasses at most). Consult doctor in the event of any complaints. Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed irritant effects, respiratory paralysis, Dizziness, narcosis, inebriation, euphoria, Nausea, Vomiting Indication of any immediate medical attention and special treatment needed No information available. Page 2 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS SECTION 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Carbon dioxide (CO2), Foam, Dry powder, Water Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. Special hazards arising from the substance or mixture Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at ambient temperatures. Pay attention to flashback. Development of hazardous combustion gases or vapors possible in the event of fire. Advice for firefighters Special protective equipment for fire-fighters In the event of fire, wear self-contained breathing apparatus. Further information Prevent fire extinguishing water from contaminating surface water or the ground water system. Remove container from danger zone and cool with water. SECTION 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid substance contact. Do not breathe vapors, aerosols. Keep away from heat and sources of ignition. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. Environmental precautions Do not empty into drains. Risk of explosion. Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. SECTION 7. Handling and storage Precautions for safe handling Observe label precautions. Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge. Conditions for safe storage, including any incompatibilities Page 3 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Store at room temperature. SECTION 8. Exposure controls/personal protection Exposure limit(s) Ingredients Basis Value Threshold Remarks limits ethanol 64-17-5 ACGIH Short Term Exposure 1,000 ppm Limit(STEL): NIOSH/GUIDE Recommended 1,000 ppm exposure limit(REL): 1,900 mg/m' OSHA_TRANS PEL: 1,000 ppm 1,900 mg/rn' Z1A Time Weighted Average 1,000 ppm (TWA): 1,900 mg/m' Engineering measures Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. Individual protection measures Protective clothing should be selected specifically for the workplace, depending on concentration and quantity of the hazardous substances handled. The chemical resistance of the protective equipment should be inquired at the respective supplier. Hygiene measures Change contaminated clothing. Application of skin- protective barrier cream recommended. Wash hands after working with substance. Eye/face protection Safety glasses Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Other protective equipment: Flame retardant antistatic protective clothing Respiratory protection required when vapors/aerosols are generated. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. SECTION 9. Physical and chemical properties Physical state liquid Page 4 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS Color colorless Odor alcohol-like Odor Threshold 0.1 -5058.5 ppm pH 7.0 at 10 g/I 68 °F (20 °C) Melting point -114.5 °C Boiling point/boiling range 172.9 °F (78.3 °C) at 1,013 hPa Flash point 54 °F (12 °C) Method: c.c. Evaporation rate No information available. Flammability (solid, gas) No information available. Lower explosion limit 3.5 %(V) Upper explosion limit 15 %(V) Vapor pressure 59 hPa at 68 °F (20 °C) Relative vapor density 1.6 Density 0.790 - 0.793 g/cm' at 68 °F (20 °C) Relative density No information available. Water solubility at 68 °F (20 °C) completely miscible Partition coefficient: n- log Pow: -0.31 octanol/water (experimental) (Lit.) Bioaccumulation is not expected. Autoignition temperature No information available. Decomposition temperature Distillable in an undecomposed state at normal pressure. Viscosity, dynamic 1.2 mPa.s at 68 °F (20 °C) Explosive properties Not classified as explosive. Page 5 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS Oxidizing properties none Ignition temperature 797 °F (425 °C) Method: DIN 51794 Conductivity < 1 pS/cm SECTION 10. Stability and reactivity Reactivity Vapors may form explosive mixture with air. Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . Possibility of hazardous reactions Risk of explosion/exothermic reaction with: hydrogen peroxide, perchlorates, perchloric acid, Nitric acid, mercury(II) nitrate, permanganic acid, Nitriles, peroxi compounds, Strong oxidizing agents, nitrosyl compounds, Peroxides, sodium, Potassium, halogen oxides, calcium hypochlorite, nitrogen dioxide, metallic oxides, uranium hexafluoride, iodides, Chlorine, Alkali metals, Alkaline earth metals, alkali oxides, Ethylene oxide silver, with, Nitric acid silver compounds, with, Ammonia potassium permanganate, with, conc. sulfuric acid Risk of ignition or formation of inflammable gases or vapors with: halogen-halogen compounds, chromium(VI) oxide, chromyl chloride, Fluorine, hydrides, Oxides of phosphorus, platinum Nitric acid, with, potassium permanganate Conditions to avoid Warming. Incompatible materials rubber, various plastics Hazardous decomposition products no information available SECTION 11. Toxicological information Information on toxicological effects Likely route of exposure Inhalation, Eye contact, Skin contact Target Organs Eyes Skin Respiratory system Central nervous system Liver Page 6 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS Blood reproductive system Acute oral toxicity LD50 rat: 6,200 mg/kg (IUCLID) Symptoms: Nausea, Vomiting Acute inhalation toxicity LC50 rat: 95.6 mg/I; 4 h (RTECS) Symptoms: slight mucosal irritations absorption Skin irritation rabbit Result: No irritation OECD Test Guideline 404 Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Sensitization Sensitization test(Magnusson and Kligman): Result: negative (IUCLID) Genotoxicity in vitro Ames test Salmonella typhimurium Result: negative (National Toxicology Program) Carcinogenicity Carcinogen classifications of IARC, NTP, California proposition 65 for Ethanol CAS 64-17-5 apply to beverage use only. This product is NOT intended for this use. Specific target organ systemic toxicity-single exposure The substance or mixture is not classified as specific target organ toxicant, single exposure. Specific target organ systemic toxicity-repeated exposure The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration hazard Regarding the available data the classification criteria are not fulfilled. Carcinogenicity IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen Page 7 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS by NTP. ACGIH No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Further information Systemic effects: euphoria After absorption of large quantities: Dizziness, inebriation, narcosis, respiratory paralysis Handle in accordance with good industrial hygiene and safety practice. SECTION 12. Ecological information Ecotoxicity Toxicity to fish LC50 Leuciscus idus (Golden orfe): 8,140 mg/I; 48 h (IUCLID) Toxicity to daphnia and other aquatic invertebrates EC5 E.sulcatum: 65 mg/I; 72 h (Lit.) EC50 Daphnia magna (Water flea): 9,268- 14,221 mg/I; 48 h (IUCLID) Toxicity to algae IC5 Scenedesmus quadricauda (Green algae): 5,000 mg/I; 7 d (Lit.) Toxicity to bacteria EC5 Pseudomonas putida: 6,500 mg/I; 16 h (IUCLID) Persistence and degradability Biodegradability 94 % OECD Test Guideline 301 E Readily biodegradable. Biochemical Oxygen Demand(BOD) 930- 1,670 mg/g (5 d) (Lit.) Theoretical oxygen demand(ThOD) 2,100 mg/g (Lit.) Ratio COD/ThBOD 90 % (Lit.) Bioaccumulative potential Partition coefficient:n-octanol/water log Pow: -0.31 (experimental) (Lit.) Bioaccumulation is not expected. Mobility in soil No information available. Page 8 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS Additional ecological information No interference with wastewater treatment plants are to be expected when used properly. Discharge into the environment must be avoided. SECTION 13. Disposal considerations The information presented only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. SECTION 14. Transport information Land transport(DOT) UN number UN 1170 Proper shipping name ETHANOL Class 3 Packing group II Environmentally hazardous -- Air transport(IATA) UN number UN 1170 Proper shipping name ETHANOL Class 3 Packing group II Environmentally hazardous -- Special precautions for user no Sea transport(IMDG) UN number UN 1170 Proper shipping name ETHANOL Class 3 Packing group II Environmentally hazardous -- Special precautions for user yes EmS F-E S-D SECTION 15. Regulatory information United States of America OSHA Hazards Flammable Liquid Target organ effects Eye irritant This information is based on 29 CFR 1910.1200 criteria prior to adoption of the GHS, and may deviate from the GHS information on the label and in section 2. Page 9 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS SARA 311/312 Hazards Fire Hazard Chronic Health Hazard SARA 313 SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 302 SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. DEA List I Not listed DEA List II Not listed US State Regulations Massachusetts Right To Know Ingredients ethanol Pennsylvania Right To Know Ingredients ethanol New Jersey Right To Know Ingredients ethanol California Prop 65 Components This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. Notification status TSCA: All components of the product are listed in the TSCA-inventory. DSL: All components of this product are on the Canadian DSL. SECTION 16. Other information Training advice Provide adequate information, instruction and training for operators. Page 10 of 11 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0276 Version 1.1 Product name Ethyl Alcohol 200 Proof GR ACS Full text of H-Statements referred to under sections 2 and 3. H225 Highly flammable liquid and vapor. Key or legend to abbreviations and acronyms used in the safety data sheet Used abbreviations and acronyms can be looked up at www.wikipedia.org. Revision Date 04/30/2014 The information contained herein is based on the present state of our knowledge.It characterizes the product with regard to appropriate safety precautions. It does not represent a warranty of any product properties and we assume no liability for any loss or injury which may result from the use of this information. Users should conduct their own investigations to determine the suitability of the information. All rights reserved.Millipore and the M"Mark are registered trademarks of Merck KGaA,Darmstadt, Germany. Page 11 of 11 !.. SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Revision Date 05/01/2014 Version 1.1 SECTION 1.Identification Product identifier Product number EX0280 Product name Ethyl Alcohol, Denatured 95% Relevant identified uses of the substance or mixture and uses advised against Identified uses Reagent for analysis Details of the supplier of the safety data sheet Company EMD Millipore Corporation 1290 Concord Road, Billerica, MA 01821, United States of America I General Inquiries: +1-978-715-4321 Monday to Friday, 9:00 AM to 4:00 PM Eastern Time (GMT-5) Emergency telephone 800-424-9300 CHEMTREC (USA) +1-703-527-3887 CHEMTREC (International) 24 Hours/day; 7 Days/week SECTION 2. Hazards identification GHS Classification Flammable liquid, Category 2, H225 Specific target organ systemic toxicity-single exposure, Category 2, Eyes, H371 For the full text of the H-Statements mentioned in this Section, see Section 16. GHS-Labeling Hazard pictograms . • Signal Word Danger Hazard Statements H225 Highly flammable liquid and vapor. H371 May cause damage to organs (Eyes). Precautionary Statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Page 1 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% P240 Ground/bond container and receiving equipment. P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. OSHA Hazards This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This information is based on 29 CFR 1910.1200 criteria prior to adoption of the GHS and may deviate from the GHS information. Other hazards None known. SECTION 3. Composition/information on ingredients Chemical nature Mixture of inorganic and organic compounds Hazardous ingredients Chemical Name (Concentration) CAS-No. ethanol(>=70 % - <90 %) 64-17-5 Exact percentages are being withheld as a trade secret. methanol(>= 1 % - <5%) 67-56-1 Exact percentages are being withheld as a trade secret. ethyl acetate(>= 1 % - <5 %) 141-78-6 Exact percentages are being withheld as a trade secret. 4-methylpentan-2-one(>=0.1 % - < 1 %) 108-10-1 Exact percentages are being withheld as a trade secret. SECTION 4. First aid measures Description of first-aid measures Inhalation After inhalation: fresh air. Consult a physician. Skin contact After skin contact: wash off with plenty of water. Remove contaminated clothing. Consult a physician. Eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Ingestion After swallowing: immediately make victim drink water(two glasses at most). Consult a physician. Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed Page 2 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% irritant effects, respiratory paralysis, Dizziness, narcosis, inebriation, euphoria, Nausea, Vomiting, Drowsiness, agitation, spasms, blindness, Headache, Coma, Impairment of vision Indication of any immediate medical attention and special treatment needed Mention methanol. SECTION 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Water, Foam, Carbon dioxide (CO2), Dry powder Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. Special hazards arising from the substance or mixture Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at ambient temperatures. Pay attention to flashback. Development of hazardous combustion gases or vapors possible in the event of fire. Advice for firefighters Special protective equipment for fire-fighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. Further information Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid substance contact. Do not breathe vapors, aerosols. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. Environmental precautions Do not let product enter drains. Risk of explosion. Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. SECTION 7. Handling and storage Precautions for safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapors/aerosols. Page 3 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% Observe label precautions. Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Store at room temperature. SECTION 8. Exposure controls/personal protection Exposure limit(s) Ingredients Basis Value Threshold Remarks limits ethanol 64-17-5 ACGIH Short Term Exposure 1,000 ppm Limit(STEL): NIOSH/GUIDE Recommended 1,000 ppm exposure limit(REL): 1,900 mg/m' OSHA_TRANS PEL: 1,000 ppm 1,900 mg/m' Z1A Time Weighted Average 1,000 ppm (TWA): 1,900 mg/m' methanol 67-56-1 ACGIH Time Weighted Average 200 ppm (TWA): Short Term Exposure 250 ppm Limit(STEL): Skin designation: Can be absorbed through the skin. NIOSH/GUIDE Recommended 200 ppm exposure limit(REL): 260 mg/m' Skin designation: Can be absorbed through the skin. Short Term Exposure 250 ppm Limit(STEL): 325 mg/m' OSHA_TRANS PEL: 200 ppm 260 mg/m' Z1A Time Weighted Average 200 ppm (TWA): 260 mg/m' Skin designation (Final Can be absorbed through the skin. Rule Limit applies): Short Term Exposure 250 ppm Limit(STEL): 325 mg/m' ethyl acetate 141-78-6 Page 4 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% ACGIH Time Weighted Average 400 ppm (TWA): NIOSH/GUIDE Recommended 400 ppm exposure limit(REL): 1,400 mg/m' OSHA_TRANS PEL: 400 ppm 1,400 mg/m' Z1A Time Weighted Average 400 ppm (TWA): 1,400 mg/m' 4-methyipentan-2-one 108-10-1 ACGIH Time Weighted Average 20 ppm (TWA): Short Term Exposure 75 ppm Limit(STEL): NIOSH/GUIDE Recommended 50 ppm exposure limit(REL): 205 mg/m' Short Term Exposure 75 ppm Limit(STEL): 300 mg/m' OSHA_TRANS PEL: 100 ppm 410 mg/m' Z1A Time Weighted Average 50 ppm (TWA): 205 mg/m' Short Term Exposure 75 ppm Limit(STEL): 300 mg/m' Engineering measures Technical measures and appropriate working operations should be given priority over the use of personal protective equipment. Individual protection measures Protective clothing should be selected specifically for the workplace, depending on concentration and quantity of the hazardous substances handled.The chemical resistance of the protective equipment should be inquired at the respective supplier. Hygiene measures Change contaminated clothing. Application of skin- protective barrier cream recommended. Wash hands after working with substance. Eye/face protection Safety glasses Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Other protective equipment. Flame retardant antistatic protective clothing Respiratory protection required when vapors/aerosols are generated. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Page 5of16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% SECTION 9. Physical and chemical properties Physical state liquid Color colorless Odor No strong odor known. Odor Threshold No information available. pH No information available. Melting point No information available. Boiling point No information available. Flash point 57.0 °F (13.9 °C) Evaporation rate No information available. Flammability(solid, gas) No information available. Lower explosion limit No information available. Upper explosion limit No information available. Vapor pressure No information available. Relative vapor density No information available. Density No information available. Relative density No information available. Water solubility No information available. Partition coefficient: n- No information available. octanol/water Autoignition temperature No information available. Decomposition temperature No information available. Viscosity, dynamic No information available. Explosive properties Not classified as explosive. Oxidizing properties none Page 6 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% SECTION 10. Stability and reactivity Reactivity Vapors may form explosive mixture with air. Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . Possibility of hazardous reactions Risk of explosion/exothermic reaction with: hydrogen peroxide, perchlorates, perchloric acid, Nitric acid, mercury(II) nitrate, permanganic acid, Nitriles, peroxi compounds, Oxidizing agents, nitrosyl compounds, Peroxides, sodium, Potassium, halogen oxides, calcium hypochlorite, nitrogen dioxide, metallic oxides, uranium hexafluoride, iodides, Chlorine, Alkali metals, Alkaline earth metals, alkali oxides, Ethylene oxide, salts of oxyhalogenic acids, chromium(VI) oxide, nitrogen oxides, nonmetallic oxides, chromosulfuric acid, chlorates, hydrides, zinc diethyl, halogens, magnesium, acid halides, Acid anhydrides, Reducing agents, acids silver, with, Nitric acid silver compounds, with, Ammonia potassium permanganate, with, conc. sulfuric acid Risk of ignition or formation of inflammable gases or vapors with: halogen-halogen compounds, chromyl chloride, Fluorine, Oxides of phosphorus, platinum Nitric acid, with, potassium permanganate Conditions to avoid Warming. Incompatible materials rubber, various plastics, oils, magnesium, zinc alloys Hazardous decomposition products no information available SECTION 11. Toxicological information Information on toxicological effects Likely route of exposure Eye contact, Skin contact Target Organs Eyes Skin Respiratory system Central nervous system Liver Blood reproductive system gastrointestinal tract Page 7 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% Acute oral toxicity Acute toxicity estimate: > 2,000 mg/kg Calculation method absorption Symptoms: Nausea, Vomiting Acute inhalation toxicity Acute toxicity estimate: > 20 mg/I; 4 h Calculation method absorption Symptoms: Irritation symptoms in the respiratory tract. Acute dermal toxicity Acute toxicity estimate : > 2,000 mg/kg Calculation method absorption Skin irritation Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Eye irritation Irritations of mucous membranes Carcinogenicity Carcinogen classifications of IARC, NTP, California proposition 65 for Ethanol CAS 64-17-5 apply to beverage use only. This product is NOT intended for this use. Specific target organ systemic toxicity-single exposure Target Organs: Eyes Mixture may cause damage to organs. Specific target organ systemic toxicity-repeated exposure The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration hazard Regarding the available data the classification criteria are not fulfilled. Carcinogenicity IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH Confirmed animal carcinogen with unknown relevance to Page 8of16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% humans. 4-methylpentan-2-one 108-10-1 Further information Systemic effects: euphoria, Dizziness, inebriation, agitation, spasms, Drowsiness, Headache, acidosis, drop in blood pressure, narcosis, Impairment of vision, blindness, respiratory paralysis, Coma Symptoms may be delayed. Damage to: Liver, Kidney, Cardiac, Irreversible damage of the optical nerve. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. Ingredients ethanol Acute oral toxicity LD50 rat: 6,200 mg/kg(IUCLID) Acute inhalation toxicity LC50 rat:95.6 mg/I;4 h(RTECS) Skin irritation rabbit Result: No irritation OECD Test Guideline 404 Sensitization Sensitization test(Magnusson and Kligman): Result: negative (IUCLID) Germ cell mutagenicity Genotoxicity in vitro Ames test Salmonella typhimurium Result:negative (National Toxicology Program) methanol Acute oral toxicity LDLO human: 143 mg/kg(RTECS) LD50 rat: 5,628 mg/kg(IUCLID) Acute inhalation toxicity LC50 rat:85.26 mg/I;4 h(IUCLID) Acute dermal toxicity L050 rabbit:ca. 17,100 mg/kg(External MSDS) Sensitization Sensitization test:guinea pig Result:negative (IUCLID) Germ cell mutagenicity Page 9 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% Genotoxicityin vivo Mutagenicity(mammal cell test):micronucleus. Result:negative (IUCLID) Genotoxicity in vitro Ames test Result:negative (IUCLID) ethyl acetate Acute oral toxicity LD50 rat: 5,620 mg/kg(RTECS) Acute inhalation toxicity LC50 rat:5.86 mg/I;8 h(Lit.) Acute dermal toxicity LD50 rabbit: >18,000 mg/kg(External MSDS) Skin irritation rabbit Result: No skin irritation (IUCLID) Eye imitation rabbit Result:slight irritation OECD Test Guideline 405 Sensitization Maximization Test(GPMT)guinea pig Result:negative Method:OECD Test Guideline 406 Germ cell mutagenicity Genotoxicity in vitro Ames test Salmonella typhimurium Result:negative Method:OECD Test Guideline 471 Mutagenicity(mammal cell test):chromosome aberration. Result:negative (National Toxicology Program) 4-methylpentan-2-one Acute oral toxicity LD50 rat: 2,080 mg/kg(RTECS) Acute inhalation toxicity LC50 rat:8.3-16.6 mg/I;4 h(External MSDS) Acute dermal toxicity LD50 rabbit: > 16,000 mg/kg(IUCLID) Sensitization Sensitization test(Magnusson and Kligman): Result: negative Method:OECD Test Guideline 406 Page 10 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% Germ cell mutagenicity Genotoxicity in vivo Mutagenicity(mammal cell test):micronucleus. Result:negative (IUCLID) Genotoxicity in vitro Ames test Result:negative (IUCLID) SECTION 12. Ecological information Ecotoxicity No information available. Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility in soil No information available. Ingredients ethanol Toxicity to fish LC50 Leuciscus idus(Golden orre):8,140 mg/I;48 h(IUCLID) Toxicity to daphnia and other aquatic invertebrates EC5 E.sulcatum:65 mg/I;72 h(Lit) EC50 Daphnia magna(Water flea):9,268-14,221 mg/I;48 h(IUCLID) Toxicity to algae IC5 Scenedesmus quadricauda(Green algae):5,000 mg/I;7 d(Lit.) Toxicity to bacteria EC5 Pseudomonas putida:6,500 mg/I; 16 h(IUCLID) Biodegradability 94% OECD Test Guideline 301E Readily biodegradable. Biochemical Oxygen Demand(BOD) 930-1,670 mg/g (5 d) (Lit.) Theoretical oxygen demand(ThOD) 2,100 mg/g (Lit.) Ratio COD/ThBOD 90% (Lit.) Page 11 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% Substance does not meets the criteria for PBT or vPvB according to Regulation(EC)No 1907/2006,Annex XIII. methanol Toxicity to fish LC50 Lepomis macrochirus(Bluegill sunfish): 15,400 mg/I;96 h(in soft water)(ECOTOX Database) Toxicity to daphnia and other aquatic invertebrates EC5 E.sulcatum:> 10,000 mg/I;72 h(Lit.) EC50 Daphnia magna(Water flea):> 10,000 mg/I;48 h(IUCLID) Toxicity to algae EC50 Pseudokirchneriella subcapitata(green algae):ca. 22,000 mg/I;96 h(External MSDS) IC5 Scenedesmus quadricauda(Green algae): 8,000 mg/I; 8 d(IUCLID) Toxicity to bacteria EC5 Pseudomonas fluorescens:6,600 mg/I; 16 h(IUCLID) Toxicity to fish(Chronic toxicity) NOEC Oryzias latipes(Orange-red killifish):7,900 mg/I;200 h (External MSDS) Biodegradability 99%;30d OECD Test Guideline 301D Readily biodegradable. Biochemical Oxygen Demand(BOO) 600- 1,120 mg/g (5 d) (IUCLID) Chemical Oxygen Demand(COD) 1,420 mg/g (IUCLID) Theoretical oxygen demand(ThOD) 1,500 mg/g (Lit.) Ratio BOD/ThBOD BOD5 76% Closed Bottle test Substance does not meets the criteria for PBT or vPvB according to Regulation(EC)No 1907/2006,Annex XIII. Stability in water 2.2 yr reaction with hydroxyl radicals(IUCLID) ethyl acetate Toxicity to fish LC50 Pimephales promelas(fathead minnow):230 mg/I;96 h(IUCLID) Toxicity to daphnia and other aquatic invertebrates EC50 Daphnia magna(Water flea): 717 mg/I;48 h(IUCLID) Page 12 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% Toxicity to algae IC50 Desmodesmus subspicatus(green algae):3,300 mg/I;48 h(IUCLID) Toxicity to bacteria EC10 Pseudomonas putida:2,900 mg/I; 16 h(IUCLID) Biodegradability 100%;28 d OECD Test Guideline 301D Readily biodegradable. Theoretical oxygen demand(ThOD) 1,820 mg/g (Lit.) Substance does not meets the criteria for PBT or vPvB according to Regulation(EC)No 1907/2006,Annex XIII. 4-methy/pentan 2-one Toxicity to fish LC50 Pimephales promelas(fathead minnow):505-540 mg/I;96 h(IUCLID) Toxicity to daphnia and other aquatic invertebrates EC5 E.sulcatum:447 mg/I;72 h(maximum permissible toxic concentration)(Lit.) EC50 Daphnia magna(Water flea): 170 mg/I;48 h(IUCLID) Toxicity to algae IC5 Scenedesmus quadricauda(Green algae):725 mg/I;7 d(maximum permissible toxic concentration)(Lit.) IC50 Pseudokirchneriella subcapitata(green algae):400 mg/I;96 h(IUCLID) Toxicity to bacteria EC50 Photobacterium phosphoreum:80 mg/I;5 min(maximum permissible toxic concentration)(Lit.) EC5 Pseudomonas putida:275 mg/I; 16 h(maximum permissible toxic concentration)(Lit.) Biodegradability 99%;7d OECD Test Guideline 301E Readily biodegradable. Theoretical oxygen demand(mOD) 2,720 mg/g (Lit.) Ratio COD/ThBOD 79% (Lit.) Substance does not meets the criteria for PBT or vPvB according to Regulation(EC)No 1907/2006,Annex XIII. Page 13 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% SECTION 13. Disposal considerations The information presented only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. SECTION 14. Transport information Land transport(DOT) UN number UN 1170 Proper shipping name ETHANOL Class 3 Packing group II Environmentally hazardous -- Air transport (IATA) UN number UN 1170 Proper shipping name ETHANOL Class 3 Packing group II Environmentally hazardous -- Special precautions for user no Sea transport (IMDG) UN number UN 1170 Proper shipping name ETHANOL Class 3 Packing group II Environmentally hazardous -- Special precautions for user yes EmS F-E S-D SECTION 15. Regulatory information United States of America OSHA Hazards Flammable Liquid Target organ effects Toxic by inhalation. Toxic by ingestion Toxic by skin absorption Eye irritant This information is based on 29 CFR 1910.1200 criteria prior to adoption of the GHS, and may deviate from the GHS information on the label and in section 2. Page 14 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% SARA 311/312 Hazards Fire Hazard Acute Health Hazard Chronic Health Hazard SARA 313 The following components are subject to reporting levels established by SARA Title III, Section 313: Ingredients methanol 67-56-1 4 % SARA 302 SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. Clean Water Act, Section 311, Table 117.3. DEA List I Not listed DEA List II Listed Ingredients 4-methylpentan-2-one 108-10-1 US State Regulations Massachusetts Right To Know Ingredients ethanol methanol ethyl acetate Pennsylvania Right To Know Ingredients ethanol water methanol ethyl acetate New Jersey Right To Know Ingredients ethanol water methanol ethyl acetate California Prop 65 Components WARNING: This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. Ingredients Page 15 of 16 SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 1910.1200) Product number EX0280 Version 1.1 Product name Ethyl Alcohol, Denatured 95% methanol Notification status TSCA: All components of the product are listed in the TSCA-inventory. DSL: All components of this product are on the Canadian DSL. SECTION 16. Other information Training advice Provide adequate information, instruction and training for operators. Full text of H-Statements referred to under sections 2 and 3. H225 Highly flammable liquid and vapor. H371 May cause damage to organs. Key or legend to abbreviations and acronyms used in the safety data sheet Used abbreviations and acronyms can be looked up at www.wikipedia.org. Revision Date 05/01/2014 The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to appropriate safety precautions. It does not represent a warranty of any product properties and we assume no liability for any loss or injury which may result from the use of this information. Users should conduct their own investigations to determine the suitability of the information. All rights reserved.Millipore and the"M"Mark are registered trademarks of Merck KGaA,Darmstadt, Germany. Page 16 of 16